Isothermal cure characterization of dicyclopentadiene View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2007-08

AUTHORS

X. Liu, X. Sheng, J. K. Lee, M. R. Kessler

ABSTRACT

Conversion (α) and the glass transition temperature (Tg) were investigated during the isothermal cure of endo-dicyclopentadiene (DCPD) with a Grubbs catalyst for different temperatures using differential scanning calorimetry. Conversion vs. In (time) data at an arbitrary reference temperature were superposed by horizontal shift and the shift factors were used to calculate an Arrhenius activation energy. Glass transition temperature vs. conversion data fell on a single curve independent of cure temperature, implying that reaction of the norbornene and cyclopentene ring of DCPD proceeds in a sequential fashion. Implications of the isothermal reaction kinetics for self-healing composites are discussed. More... »

PAGES

453-457

References to SciGraph publications

  • 2004-03. Microcapsule induced toughening in a self-healing polymer composite in JOURNAL OF MATERIALS SCIENCE
  • 2001-02. Autonomic healing of polymer composites in NATURE
  • 2006-01. Thermocatalytic removal of carbonaceous materials in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 2002-12. Fracture testing of a self-healing polymer composite in EXPERIMENTAL MECHANICS
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s10973-006-8467-4

    DOI

    http://dx.doi.org/10.1007/s10973-006-8467-4

    DIMENSIONS

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