Ontology type: schema:ScholarlyArticle
2006-12
AUTHORSC. Arribas, Rosa M. Masegosa, C. Salom, E. Arévalo, S. G. Prolongo, Margarita G. Prolongo
ABSTRACTDiglycidyl ether of bisfenol-A (DGEBA)/polybenzyl methacrylate (PBzMA) blends cured with 4,4’-diaminodiphenylmethane (DDM) were studied. Miscibility, phase separation, cure kinetics and morphology were investigated through differential scanning calorimetry (DSC) and scanning electron microscopy (SEM). Non-reactive DGEBA/PBzMA blends are miscible over the whole composition range. The addition of PBzMA to the reactive (DGEBA+DDM) mixture slows down the curing rate, although the reaction mechanism remains autocatalytic. On curing, initially miscible (DGEBA+DDM)/PBzMA blends phase separate, arising two glass transition temperatures that correspond to a PBzMA-rich phase and to epoxy network. Cured epoxy/PBzMA blends present different morphologies as a function of the PBzMA content. More... »
PAGES693-698
http://scigraph.springernature.com/pub.10.1007/s10973-006-7895-5
DOIhttp://dx.doi.org/10.1007/s10973-006-7895-5
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