On the effect of montmorillonite in the curing reaction of epoxy nanocomposites View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2007-01

AUTHORS

F. Román, S. Montserrat, J. M. Hutchinson

ABSTRACT

The procedure for the fabrication of epoxy-based polymer layered silicate nanocomposites is important in respect of the nanostructure that is developed. To further our understanding of this, the influence of an organically modified clay (montmorillonite, MMT) on the curing kinetics of an epoxy resin has been studied by differential scanning calorimetry. Clay loadings of 10 and 20 mass% are used, and isothermal as well as dynamic cures have been investigated. For both cure schedules the effect of the MMT is to advance the reaction. Kinetic analysis yields values for the activation energy, but shows that the reaction cannot be described simply by the usual autocatalytic equation. The glass transition of the cured nanocomposites is lower than that for the cured neat resin, a result that is attributed to homopolymerisation taking place in addition to the epoxy–amine reaction. More... »

PAGES

113-118

References to SciGraph publications

  • 2005. Epoxy Layered Silicate Nanocomposites in INORGANIC POLYMERIC NANOCOMPOSITES AND MEMBRANES
  • 2004-10. Cure behavior of epoxy resin/MMT/DETA nanocomposite in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s10973-006-7830-9

    DOI

    http://dx.doi.org/10.1007/s10973-006-7830-9

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1022446912


    Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
    Incoming Citations Browse incoming citations for this publication using opencitations.net

    JSON-LD is the canonical representation for SciGraph data.

    TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

    [
      {
        "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
        "about": [
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0912", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Materials Engineering", 
            "type": "DefinedTerm"
          }, 
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Engineering", 
            "type": "DefinedTerm"
          }
        ], 
        "author": [
          {
            "affiliation": {
              "alternateName": "Universitat Polit\u00e8cnica de Catalunya", 
              "id": "https://www.grid.ac/institutes/grid.6835.8", 
              "name": [
                "Departament de M\u00e0quines\ni Motors T\u00e8rmics, ETSEIAT, Universitat Polit\u00e8cnica\nde Catalunya, 08222, Terrassa, Spain"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Rom\u00e1n", 
            "givenName": "F.", 
            "id": "sg:person.012635427171.37", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012635427171.37"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Universitat Polit\u00e8cnica de Catalunya", 
              "id": "https://www.grid.ac/institutes/grid.6835.8", 
              "name": [
                "Departament de M\u00e0quines\ni Motors T\u00e8rmics, ETSEIAT, Universitat Polit\u00e8cnica\nde Catalunya, 08222, Terrassa, Spain"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Montserrat", 
            "givenName": "S.", 
            "id": "sg:person.013200533475.62", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013200533475.62"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Universitat Polit\u00e8cnica de Catalunya", 
              "id": "https://www.grid.ac/institutes/grid.6835.8", 
              "name": [
                "Departament de M\u00e0quines\ni Motors T\u00e8rmics, ETSEIAT, Universitat Polit\u00e8cnica\nde Catalunya, 08222, Terrassa, Spain"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Hutchinson", 
            "givenName": "J. M.", 
            "id": "sg:person.014125766777.76", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014125766777.76"
            ], 
            "type": "Person"
          }
        ], 
        "citation": [
          {
            "id": "sg:pub.10.1023/b:jtan.0000042159.78698.0c", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1004731128", 
              "https://doi.org/10.1023/b:jtan.0000042159.78698.0c"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/b107204", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1007994979", 
              "https://doi.org/10.1007/b107204"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0040-6031(92)85118-f", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1008269354"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0040-6031(93)80273-d", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1014855763"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/s0927-796x(00)00012-7", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1017989816"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1002/pen.20468", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1024324967"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1002/pen.20468", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1024324967"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1557/jmr.2001.0255", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1026849645"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.progpolymsci.2003.08.002", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1031408371"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.progpolymsci.2003.08.002", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1031408371"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1002/pen.760140312", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1036409037"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0022-3697(95)00388-6", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1041148320"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1002/app.1961.070051313", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1043561812"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ma00011a012", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1056172815"
            ], 
            "type": "CreativeWork"
          }
        ], 
        "datePublished": "2007-01", 
        "datePublishedReg": "2007-01-01", 
        "description": "The procedure for the fabrication of epoxy-based polymer layered silicate nanocomposites is important in respect of the nanostructure that is developed. To further our understanding of this, the influence of an organically modified clay (montmorillonite, MMT) on the curing kinetics of an epoxy resin has been studied by differential scanning calorimetry. Clay loadings of 10 and 20 mass% are used, and isothermal as well as dynamic cures have been investigated. For both cure schedules the effect of the MMT is to advance the reaction. Kinetic analysis yields values for the activation energy, but shows that the reaction cannot be described simply by the usual autocatalytic equation. The glass transition of the cured nanocomposites is lower than that for the cured neat resin, a result that is attributed to homopolymerisation taking place in addition to the epoxy\u2013amine reaction.", 
        "genre": "research_article", 
        "id": "sg:pub.10.1007/s10973-006-7830-9", 
        "inLanguage": [
          "en"
        ], 
        "isAccessibleForFree": false, 
        "isPartOf": [
          {
            "id": "sg:journal.1294862", 
            "issn": [
              "1388-6150", 
              "1572-8943"
            ], 
            "name": "Journal of Thermal Analysis and Calorimetry", 
            "type": "Periodical"
          }, 
          {
            "issueNumber": "1", 
            "type": "PublicationIssue"
          }, 
          {
            "type": "PublicationVolume", 
            "volumeNumber": "87"
          }
        ], 
        "name": "On the effect of montmorillonite in the curing reaction of epoxy nanocomposites", 
        "pagination": "113-118", 
        "productId": [
          {
            "name": "readcube_id", 
            "type": "PropertyValue", 
            "value": [
              "6af0fafb891b0e1c1981c52c27735a52771efe5175a02a8b05f4ccd82a876cd2"
            ]
          }, 
          {
            "name": "doi", 
            "type": "PropertyValue", 
            "value": [
              "10.1007/s10973-006-7830-9"
            ]
          }, 
          {
            "name": "dimensions_id", 
            "type": "PropertyValue", 
            "value": [
              "pub.1022446912"
            ]
          }
        ], 
        "sameAs": [
          "https://doi.org/10.1007/s10973-006-7830-9", 
          "https://app.dimensions.ai/details/publication/pub.1022446912"
        ], 
        "sdDataset": "articles", 
        "sdDatePublished": "2019-04-10T21:37", 
        "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
        "sdPublisher": {
          "name": "Springer Nature - SN SciGraph project", 
          "type": "Organization"
        }, 
        "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8687_00000512.jsonl", 
        "type": "ScholarlyArticle", 
        "url": "http://link.springer.com/10.1007%2Fs10973-006-7830-9"
      }
    ]
     

    Download the RDF metadata as:  json-ld nt turtle xml License info

    HOW TO GET THIS DATA PROGRAMMATICALLY:

    JSON-LD is a popular format for linked data which is fully compatible with JSON.

    curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10973-006-7830-9'

    N-Triples is a line-based linked data format ideal for batch operations.

    curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10973-006-7830-9'

    Turtle is a human-readable linked data format.

    curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10973-006-7830-9'

    RDF/XML is a standard XML format for linked data.

    curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10973-006-7830-9'


     

    This table displays all metadata directly associated to this object as RDF triples.

    113 TRIPLES      21 PREDICATES      39 URIs      19 LITERALS      7 BLANK NODES

    Subject Predicate Object
    1 sg:pub.10.1007/s10973-006-7830-9 schema:about anzsrc-for:09
    2 anzsrc-for:0912
    3 schema:author Nc99a4dd7b8144dc3a85f7ba3a05626c2
    4 schema:citation sg:pub.10.1007/b107204
    5 sg:pub.10.1023/b:jtan.0000042159.78698.0c
    6 https://doi.org/10.1002/app.1961.070051313
    7 https://doi.org/10.1002/pen.20468
    8 https://doi.org/10.1002/pen.760140312
    9 https://doi.org/10.1016/0022-3697(95)00388-6
    10 https://doi.org/10.1016/0040-6031(92)85118-f
    11 https://doi.org/10.1016/0040-6031(93)80273-d
    12 https://doi.org/10.1016/j.progpolymsci.2003.08.002
    13 https://doi.org/10.1016/s0927-796x(00)00012-7
    14 https://doi.org/10.1021/ma00011a012
    15 https://doi.org/10.1557/jmr.2001.0255
    16 schema:datePublished 2007-01
    17 schema:datePublishedReg 2007-01-01
    18 schema:description The procedure for the fabrication of epoxy-based polymer layered silicate nanocomposites is important in respect of the nanostructure that is developed. To further our understanding of this, the influence of an organically modified clay (montmorillonite, MMT) on the curing kinetics of an epoxy resin has been studied by differential scanning calorimetry. Clay loadings of 10 and 20 mass% are used, and isothermal as well as dynamic cures have been investigated. For both cure schedules the effect of the MMT is to advance the reaction. Kinetic analysis yields values for the activation energy, but shows that the reaction cannot be described simply by the usual autocatalytic equation. The glass transition of the cured nanocomposites is lower than that for the cured neat resin, a result that is attributed to homopolymerisation taking place in addition to the epoxy–amine reaction.
    19 schema:genre research_article
    20 schema:inLanguage en
    21 schema:isAccessibleForFree false
    22 schema:isPartOf N41370617929f4d3eac281065fb00515a
    23 N97248e5caca948eca7177d2c4aa138d9
    24 sg:journal.1294862
    25 schema:name On the effect of montmorillonite in the curing reaction of epoxy nanocomposites
    26 schema:pagination 113-118
    27 schema:productId N3c8b216029e04da3a1e32b18fd1ef502
    28 N93a5f8e1625840969c7d07304b11e545
    29 Nd9280528b3084e45b49811fa8242c084
    30 schema:sameAs https://app.dimensions.ai/details/publication/pub.1022446912
    31 https://doi.org/10.1007/s10973-006-7830-9
    32 schema:sdDatePublished 2019-04-10T21:37
    33 schema:sdLicense https://scigraph.springernature.com/explorer/license/
    34 schema:sdPublisher N6c24c162fa614c9a9b90880351fc1253
    35 schema:url http://link.springer.com/10.1007%2Fs10973-006-7830-9
    36 sgo:license sg:explorer/license/
    37 sgo:sdDataset articles
    38 rdf:type schema:ScholarlyArticle
    39 N2ed05ce3d5ac4872b77436c0ea5ca963 rdf:first sg:person.014125766777.76
    40 rdf:rest rdf:nil
    41 N3c8b216029e04da3a1e32b18fd1ef502 schema:name readcube_id
    42 schema:value 6af0fafb891b0e1c1981c52c27735a52771efe5175a02a8b05f4ccd82a876cd2
    43 rdf:type schema:PropertyValue
    44 N41370617929f4d3eac281065fb00515a schema:volumeNumber 87
    45 rdf:type schema:PublicationVolume
    46 N42a5b7b876ae44d38456f2001a626d0d rdf:first sg:person.013200533475.62
    47 rdf:rest N2ed05ce3d5ac4872b77436c0ea5ca963
    48 N6c24c162fa614c9a9b90880351fc1253 schema:name Springer Nature - SN SciGraph project
    49 rdf:type schema:Organization
    50 N93a5f8e1625840969c7d07304b11e545 schema:name dimensions_id
    51 schema:value pub.1022446912
    52 rdf:type schema:PropertyValue
    53 N97248e5caca948eca7177d2c4aa138d9 schema:issueNumber 1
    54 rdf:type schema:PublicationIssue
    55 Nc99a4dd7b8144dc3a85f7ba3a05626c2 rdf:first sg:person.012635427171.37
    56 rdf:rest N42a5b7b876ae44d38456f2001a626d0d
    57 Nd9280528b3084e45b49811fa8242c084 schema:name doi
    58 schema:value 10.1007/s10973-006-7830-9
    59 rdf:type schema:PropertyValue
    60 anzsrc-for:09 schema:inDefinedTermSet anzsrc-for:
    61 schema:name Engineering
    62 rdf:type schema:DefinedTerm
    63 anzsrc-for:0912 schema:inDefinedTermSet anzsrc-for:
    64 schema:name Materials Engineering
    65 rdf:type schema:DefinedTerm
    66 sg:journal.1294862 schema:issn 1388-6150
    67 1572-8943
    68 schema:name Journal of Thermal Analysis and Calorimetry
    69 rdf:type schema:Periodical
    70 sg:person.012635427171.37 schema:affiliation https://www.grid.ac/institutes/grid.6835.8
    71 schema:familyName Román
    72 schema:givenName F.
    73 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012635427171.37
    74 rdf:type schema:Person
    75 sg:person.013200533475.62 schema:affiliation https://www.grid.ac/institutes/grid.6835.8
    76 schema:familyName Montserrat
    77 schema:givenName S.
    78 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013200533475.62
    79 rdf:type schema:Person
    80 sg:person.014125766777.76 schema:affiliation https://www.grid.ac/institutes/grid.6835.8
    81 schema:familyName Hutchinson
    82 schema:givenName J. M.
    83 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014125766777.76
    84 rdf:type schema:Person
    85 sg:pub.10.1007/b107204 schema:sameAs https://app.dimensions.ai/details/publication/pub.1007994979
    86 https://doi.org/10.1007/b107204
    87 rdf:type schema:CreativeWork
    88 sg:pub.10.1023/b:jtan.0000042159.78698.0c schema:sameAs https://app.dimensions.ai/details/publication/pub.1004731128
    89 https://doi.org/10.1023/b:jtan.0000042159.78698.0c
    90 rdf:type schema:CreativeWork
    91 https://doi.org/10.1002/app.1961.070051313 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043561812
    92 rdf:type schema:CreativeWork
    93 https://doi.org/10.1002/pen.20468 schema:sameAs https://app.dimensions.ai/details/publication/pub.1024324967
    94 rdf:type schema:CreativeWork
    95 https://doi.org/10.1002/pen.760140312 schema:sameAs https://app.dimensions.ai/details/publication/pub.1036409037
    96 rdf:type schema:CreativeWork
    97 https://doi.org/10.1016/0022-3697(95)00388-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041148320
    98 rdf:type schema:CreativeWork
    99 https://doi.org/10.1016/0040-6031(92)85118-f schema:sameAs https://app.dimensions.ai/details/publication/pub.1008269354
    100 rdf:type schema:CreativeWork
    101 https://doi.org/10.1016/0040-6031(93)80273-d schema:sameAs https://app.dimensions.ai/details/publication/pub.1014855763
    102 rdf:type schema:CreativeWork
    103 https://doi.org/10.1016/j.progpolymsci.2003.08.002 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031408371
    104 rdf:type schema:CreativeWork
    105 https://doi.org/10.1016/s0927-796x(00)00012-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1017989816
    106 rdf:type schema:CreativeWork
    107 https://doi.org/10.1021/ma00011a012 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056172815
    108 rdf:type schema:CreativeWork
    109 https://doi.org/10.1557/jmr.2001.0255 schema:sameAs https://app.dimensions.ai/details/publication/pub.1026849645
    110 rdf:type schema:CreativeWork
    111 https://www.grid.ac/institutes/grid.6835.8 schema:alternateName Universitat Politècnica de Catalunya
    112 schema:name Departament de Màquines i Motors Tèrmics, ETSEIAT, Universitat Politècnica de Catalunya, 08222, Terrassa, Spain
    113 rdf:type schema:Organization
     




    Preview window. Press ESC to close (or click here)


    ...