Ontology type: schema:ScholarlyArticle
2007-01
AUTHORSSilvia G. Prolongo, G. Prolongo
ABSTRACTPoly(4-vinylphenol) (PVPh) was used as thermoplastic modifier of epoxy resins. Binary epoxy/PVPh mixtures with high thermoplastic content rise high glass transition temperatures (Tg) after heating, due to the epoxy-phenol reaction. Blends with low PVPh percentages reach high Tg if 2-methylimidazole is added, which catalyses epoxy homopolymerisation and epoxy-phenol reaction. The cured blends do not present phase separation although the network structure depends on the epoxy/phenol ratio. At low PVPh percentage the main crosslinking reaction is epoxy-epoxy but, when the thermoplastic content increases, the epoxy-phenol reaction prevails, causing an important Tg increase and becoming less brittle. More... »
PAGES259-268
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DOIhttp://dx.doi.org/10.1007/s10973-006-7803-z
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