Mechanical properties and morphology of epoxy/poly(vinyl acetate)/poly(4-vinyl phenol) brominated system View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2007-01

AUTHORS

Margarita G. Prolongo, C. Arribas, Catalina Salom, Rosa M. Masegosa

ABSTRACT

Diglycidyl ether of bisfenol-A (DGEBA)/poly(vinyl acetate) (PVAc)/poly(4-vinyl phenol) brominated (PVPhBr) ternary blends cured with 4,4’-diaminodiphenylmethane (DDM) were investigated by differential scanning calorimetry (DSC), dynamic mechanical thermal analysis (DMTA) and scanning electron microscopy (SEM). Homogeneous (DGEBA+DDM)/PVPhBr networks with a unique Tg are generated. Ternary blends (DGEBA+DDM)/PVAc/PVPhBr are initially miscible and phase separate upon curing arising two Tgs that correspond to a PVAc-rich phase and to epoxy network phase. Increasing the PVPhBr content the Tgof the PVAc phase move to higher temperatures as a consequence of the PVAc-PVPhBr interactions. Different morphologies are generated as a function of the blend composition. More... »

PAGES

33-39

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10973-006-7800-2

DOI

http://dx.doi.org/10.1007/s10973-006-7800-2

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1033480631


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