A study on curing kinetic of bisphenol-F using benzyl dimethyl amine by isothermal DSC View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2005-09

AUTHORS

F. Shokrolahi, M. Sadi, P. Shokrolahi

ABSTRACT

The effect of the concentration of benzyl dimethyl amine as a catalyst on the cure reaction of bisphenol-F based epoxy resin(BPF)/nadic methyl ahydride(NMA) system was studied by differential scanning calorimetery using an isothermal approach over the temperature range 115-145°C. Kinetic parameters of the curing reaction including the reaction order, activation energy and kinetic rate constants were investigated. The results were dependent on the cure temperature and catalyst concentration and proceeded through an autocatalytic kinetic mechanism. The curing kinetic constants and the cure activation energies were obtained by the Arrhenius kinetic model. The suggested kinetic model with a diffusion term was successfully used to describe and predict the cure kinetic of BPF resin compositions as a function of the catalyst content and temperature. More... »

PAGES

151-156

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10973-005-0856-6

DOI

http://dx.doi.org/10.1007/s10973-005-0856-6

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1015438769


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0912", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Materials Engineering", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Engineering", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Iran Polymer and Petrochemical Institute", 
          "id": "https://www.grid.ac/institutes/grid.419412.b", 
          "name": [
            "Iran Polymer and Petrochemical Institute, P.O. Box 14965/159, Tehran, Iran"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Shokrolahi", 
        "givenName": "F.", 
        "id": "sg:person.07441260166.45", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07441260166.45"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Amirkabir University of Technology", 
          "id": "https://www.grid.ac/institutes/grid.411368.9", 
          "name": [
            "Amir Kabir University of Technology, Faculty of Chemical Engineering, P.O. Box 15875-4413 Tehran, Iran"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Sadi", 
        "givenName": "M.", 
        "id": "sg:person.014710670241.42", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014710670241.42"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Iran Polymer and Petrochemical Institute", 
          "id": "https://www.grid.ac/institutes/grid.419412.b", 
          "name": [
            "Iran Polymer and Petrochemical Institute, P.O. Box 14965/159, Tehran, Iran"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Shokrolahi", 
        "givenName": "P.", 
        "type": "Person"
      }
    ], 
    "datePublished": "2005-09", 
    "datePublishedReg": "2005-09-01", 
    "description": "The effect of the concentration of benzyl dimethyl amine as a catalyst on the cure reaction of bisphenol-F based epoxy resin(BPF)/nadic methyl ahydride(NMA) system was studied by differential scanning calorimetery using an isothermal approach over the temperature range 115-145\u00b0C. Kinetic parameters of the curing reaction including the reaction order, activation energy and kinetic rate constants were investigated. The results were dependent on the cure temperature and catalyst concentration and proceeded through an autocatalytic kinetic mechanism. The curing kinetic constants and the cure activation energies were obtained by the Arrhenius kinetic model. The suggested kinetic model with a diffusion term was successfully used to describe and predict the cure kinetic of BPF resin compositions as a function of the catalyst content and temperature.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s10973-005-0856-6", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1294862", 
        "issn": [
          "1388-6150", 
          "1572-8943"
        ], 
        "name": "Journal of Thermal Analysis and Calorimetry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "1", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "82"
      }
    ], 
    "name": "A study on curing kinetic of bisphenol-F using benzyl dimethyl amine by isothermal DSC", 
    "pagination": "151-156", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "498f2a821152665662b4b69c3a44d4a3d062cda01575b3c94ff1539b9188e7bc"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s10973-005-0856-6"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1015438769"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s10973-005-0856-6", 
      "https://app.dimensions.ai/details/publication/pub.1015438769"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T02:00", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8700_00000511.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007%2Fs10973-005-0856-6"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10973-005-0856-6'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10973-005-0856-6'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10973-005-0856-6'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10973-005-0856-6'


 

This table displays all metadata directly associated to this object as RDF triples.

77 TRIPLES      20 PREDICATES      27 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s10973-005-0856-6 schema:about anzsrc-for:09
2 anzsrc-for:0912
3 schema:author Nd179f6d1147246a7862029cbe50cd087
4 schema:datePublished 2005-09
5 schema:datePublishedReg 2005-09-01
6 schema:description The effect of the concentration of benzyl dimethyl amine as a catalyst on the cure reaction of bisphenol-F based epoxy resin(BPF)/nadic methyl ahydride(NMA) system was studied by differential scanning calorimetery using an isothermal approach over the temperature range 115-145°C. Kinetic parameters of the curing reaction including the reaction order, activation energy and kinetic rate constants were investigated. The results were dependent on the cure temperature and catalyst concentration and proceeded through an autocatalytic kinetic mechanism. The curing kinetic constants and the cure activation energies were obtained by the Arrhenius kinetic model. The suggested kinetic model with a diffusion term was successfully used to describe and predict the cure kinetic of BPF resin compositions as a function of the catalyst content and temperature.
7 schema:genre research_article
8 schema:inLanguage en
9 schema:isAccessibleForFree false
10 schema:isPartOf N0a29ad6ef76e4a46a7ccbe51cd4fc971
11 N85ec924bd2374830bd54809dac0ecdec
12 sg:journal.1294862
13 schema:name A study on curing kinetic of bisphenol-F using benzyl dimethyl amine by isothermal DSC
14 schema:pagination 151-156
15 schema:productId N2079ebded0b24ba1a205d2adf5ca9c8f
16 N225916abb00940529e8d10c6ee1a7906
17 N2ef0ab8c541d4d8a907096ea94f62f5d
18 schema:sameAs https://app.dimensions.ai/details/publication/pub.1015438769
19 https://doi.org/10.1007/s10973-005-0856-6
20 schema:sdDatePublished 2019-04-11T02:00
21 schema:sdLicense https://scigraph.springernature.com/explorer/license/
22 schema:sdPublisher Na8cb7bcbad8f4b638d3cac142bc5a106
23 schema:url http://link.springer.com/10.1007%2Fs10973-005-0856-6
24 sgo:license sg:explorer/license/
25 sgo:sdDataset articles
26 rdf:type schema:ScholarlyArticle
27 N0a29ad6ef76e4a46a7ccbe51cd4fc971 schema:issueNumber 1
28 rdf:type schema:PublicationIssue
29 N0c467437a309420dab5e17f8387b3f95 rdf:first sg:person.014710670241.42
30 rdf:rest N541b7898b1ec4fde97b6439baf107a2e
31 N2079ebded0b24ba1a205d2adf5ca9c8f schema:name dimensions_id
32 schema:value pub.1015438769
33 rdf:type schema:PropertyValue
34 N20f205754c7d4adca2f36b9e3badc7ee schema:affiliation https://www.grid.ac/institutes/grid.419412.b
35 schema:familyName Shokrolahi
36 schema:givenName P.
37 rdf:type schema:Person
38 N225916abb00940529e8d10c6ee1a7906 schema:name readcube_id
39 schema:value 498f2a821152665662b4b69c3a44d4a3d062cda01575b3c94ff1539b9188e7bc
40 rdf:type schema:PropertyValue
41 N2ef0ab8c541d4d8a907096ea94f62f5d schema:name doi
42 schema:value 10.1007/s10973-005-0856-6
43 rdf:type schema:PropertyValue
44 N541b7898b1ec4fde97b6439baf107a2e rdf:first N20f205754c7d4adca2f36b9e3badc7ee
45 rdf:rest rdf:nil
46 N85ec924bd2374830bd54809dac0ecdec schema:volumeNumber 82
47 rdf:type schema:PublicationVolume
48 Na8cb7bcbad8f4b638d3cac142bc5a106 schema:name Springer Nature - SN SciGraph project
49 rdf:type schema:Organization
50 Nd179f6d1147246a7862029cbe50cd087 rdf:first sg:person.07441260166.45
51 rdf:rest N0c467437a309420dab5e17f8387b3f95
52 anzsrc-for:09 schema:inDefinedTermSet anzsrc-for:
53 schema:name Engineering
54 rdf:type schema:DefinedTerm
55 anzsrc-for:0912 schema:inDefinedTermSet anzsrc-for:
56 schema:name Materials Engineering
57 rdf:type schema:DefinedTerm
58 sg:journal.1294862 schema:issn 1388-6150
59 1572-8943
60 schema:name Journal of Thermal Analysis and Calorimetry
61 rdf:type schema:Periodical
62 sg:person.014710670241.42 schema:affiliation https://www.grid.ac/institutes/grid.411368.9
63 schema:familyName Sadi
64 schema:givenName M.
65 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014710670241.42
66 rdf:type schema:Person
67 sg:person.07441260166.45 schema:affiliation https://www.grid.ac/institutes/grid.419412.b
68 schema:familyName Shokrolahi
69 schema:givenName F.
70 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07441260166.45
71 rdf:type schema:Person
72 https://www.grid.ac/institutes/grid.411368.9 schema:alternateName Amirkabir University of Technology
73 schema:name Amir Kabir University of Technology, Faculty of Chemical Engineering, P.O. Box 15875-4413 Tehran, Iran
74 rdf:type schema:Organization
75 https://www.grid.ac/institutes/grid.419412.b schema:alternateName Iran Polymer and Petrochemical Institute
76 schema:name Iran Polymer and Petrochemical Institute, P.O. Box 14965/159, Tehran, Iran
77 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...