Sol-assisted spray-drying synthesis of porous Li3V2(PO4)3/C microspheres as high-activity cathode materials for lithium-ion batteries View Full Text


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Article Info

DATE

2018-05

AUTHORS

Xiaoyu Liu, Xuejiao Feng, Xiaoning Xu, Fei Wang, Yanming Wang

ABSTRACT

Herein, porous Li3V2(PO4)3/C microspheres made of nanoparticles are obtained by a combination of sol spray-drying and subsequent-sintering process. Beta-cyclodextrin serves as a special chelating agent and carbon source to obtain carbon-coated Li3V2(PO4)3 grains with the size of ca. 30–50 nm. The unique porous structure and continuous carbon skeleton facilitate the fast transport of lithium ion and electron. The Li3V2(PO4)3/C microspheres offer an outstanding electrochemical performance, which present a discharge capacity of 122 mAh g−1 at 2 C with capacity retention of 96% at the end of 1000 cycles and a high-rate capacity of 113 mAh g−1 at 20 C in the voltage window of 3.0–4.3 V. Moreover, the Li3V2(PO4)3/C microspheres also give considerable cycling stability and high-rate reversible capacity at a higher end-of-charge voltage of 4.8 V. More... »

PAGES

343-350

References to SciGraph publications

  • 2016-12. In situ synthesis of biocarbon coated Li3V2(PO4)3 cathode material using lotus leaf as carbon source in JOURNAL OF MATERIALS SCIENCE: MATERIALS IN ELECTRONICS
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