Ontology type: schema:ScholarlyArticle
2009-04
AUTHORSKazushige Yokoyama, Jeffrey R. Swana, Tonya M. Gilbert, Duo D. Chen, Liwen Chen, Paul Kogan
ABSTRACTVarious sizes of gold nano colloidal particles ranging from 5 nm to 100 nm of size were encapsulated in a silica based sol–gel, and these surfaces were exposed to a pH 1 acid solution. This enabled us to observe the process of solvent intrusion and interaction with gold colloids by the absorption spectrum as a function of time. The rate was analyzed by a single exponential analytical function, and the maximum rate was found for gold colloid of 15 nm size. The least acid interaction and colour change was observed for the size of 60 nm. It was speculated that the surface of these gold colloids were homogeneously covered by the sodium tetra-borate buffer which insulated silica gel layer, thus avoiding direct contact of the acid with the surface of the gold colloid. This study confirmed that the nano scale dopant size affects the rate of solvent penetration into a sol–gel cavity. More... »
PAGES48-57
http://scigraph.springernature.com/pub.10.1007/s10971-009-1904-7
DOIhttp://dx.doi.org/10.1007/s10971-009-1904-7
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1010297065
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Physical Chemistry (incl. Structural)",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Chemical Sciences",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "SUNY Geneseo",
"id": "https://www.grid.ac/institutes/grid.264269.d",
"name": [
"Department of Chemistry, State University of New York, 14454, Geneseo, NY, USA"
],
"type": "Organization"
},
"familyName": "Yokoyama",
"givenName": "Kazushige",
"id": "sg:person.01341666755.99",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01341666755.99"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Worcester Polytechnic Institute",
"id": "https://www.grid.ac/institutes/grid.268323.e",
"name": [
"Department of Chemistry, State University of New York, 14454, Geneseo, NY, USA",
"Worcester Polytech Institute, 100 Institute Road, 01609, Worcester, MA, USA"
],
"type": "Organization"
},
"familyName": "Swana",
"givenName": "Jeffrey R.",
"id": "sg:person.013376054035.04",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013376054035.04"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "SUNY Geneseo",
"id": "https://www.grid.ac/institutes/grid.264269.d",
"name": [
"Department of Chemistry, State University of New York, 14454, Geneseo, NY, USA"
],
"type": "Organization"
},
"familyName": "Gilbert",
"givenName": "Tonya M.",
"type": "Person"
},
{
"affiliation": {
"alternateName": "SUNY Geneseo",
"id": "https://www.grid.ac/institutes/grid.264269.d",
"name": [
"Department of Chemistry, State University of New York, 14454, Geneseo, NY, USA"
],
"type": "Organization"
},
"familyName": "Chen",
"givenName": "Duo D.",
"type": "Person"
},
{
"affiliation": {
"alternateName": "SUNY Geneseo",
"id": "https://www.grid.ac/institutes/grid.264269.d",
"name": [
"Department of Chemistry, State University of New York, 14454, Geneseo, NY, USA"
],
"type": "Organization"
},
"familyName": "Chen",
"givenName": "Liwen",
"type": "Person"
},
{
"affiliation": {
"alternateName": "SUNY Geneseo",
"id": "https://www.grid.ac/institutes/grid.264269.d",
"name": [
"Department of Chemistry, State University of New York, 14454, Geneseo, NY, USA",
"Down State Health Sciences Center, State University of New York, 11203, Brooklyn, NY, USA"
],
"type": "Organization"
},
"familyName": "Kogan",
"givenName": "Paul",
"type": "Person"
}
],
"citation": [
{
"id": "https://doi.org/10.1002/adma.19930050603",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1000488169"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1088/0957-4484/18/10/105101",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1005719425"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/225420a0",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1008580609",
"https://doi.org/10.1038/225420a0"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/s10971-007-1566-2",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1008685318",
"https://doi.org/10.1007/s10971-007-1566-2"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/s10971-007-1566-2",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1008685318",
"https://doi.org/10.1007/s10971-007-1566-2"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/382609a0",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1013811778",
"https://doi.org/10.1038/382609a0"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1073/pnas.91.4.1229",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1014829679"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1073/pnas.151125698",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1017765347"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/adma.19930050604",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1027506186"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/382607a0",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1030717946",
"https://doi.org/10.1038/382607a0"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1073/pnas.98.4.1577",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1032768763"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1088/0957-4484/19/37/375101",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1038143363"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1039/an9931800385",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1039295218"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1126/science.289.5485.1757",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1040063812"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1073/pnas.91.13.5740",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1041174406"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/cr030698+",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1042893548"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/cr030698+",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1042893548"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf00486300",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1052364135",
"https://doi.org/10.1007/bf00486300"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf00486300",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1052364135",
"https://doi.org/10.1007/bf00486300"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ac000567y",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1054969051"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ac000567y",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1054969051"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/cm00043a028",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055407324"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/j100113a028",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055653474"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ja012215u",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055783856"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ja012215u",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055783856"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/la036183v",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1056146552"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/la036183v",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1056146552"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1063/1.1753572",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1057814103"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1063/1.1795652",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1057822754"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physrev.124.1866",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1060424664"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physrev.124.1866",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1060424664"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physrevb.47.8565",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1060566746"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physrevb.47.8565",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1060566746"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physrevlett.68.3555",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1060804788"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physrevlett.68.3555",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1060804788"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physrevlett.88.105505",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1060824579"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physrevlett.88.105505",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1060824579"
],
"type": "CreativeWork"
}
],
"datePublished": "2009-04",
"datePublishedReg": "2009-04-01",
"description": "Various sizes of gold nano colloidal particles ranging from 5 nm to 100 nm of size were encapsulated in a silica based sol\u2013gel, and these surfaces were exposed to a pH 1 acid solution. This enabled us to observe the process of solvent intrusion and interaction with gold colloids by the absorption spectrum as a function of time. The rate was analyzed by a single exponential analytical function, and the maximum rate was found for gold colloid of 15 nm size. The least acid interaction and colour change was observed for the size of 60 nm. It was speculated that the surface of these gold colloids were homogeneously covered by the sodium tetra-borate buffer which insulated silica gel layer, thus avoiding direct contact of the acid with the surface of the gold colloid. This study confirmed that the nano scale dopant size affects the rate of solvent penetration into a sol\u2013gel cavity.",
"genre": "research_article",
"id": "sg:pub.10.1007/s10971-009-1904-7",
"inLanguage": [
"en"
],
"isAccessibleForFree": false,
"isFundedItemOf": [
{
"id": "sg:grant.3057679",
"type": "MonetaryGrant"
}
],
"isPartOf": [
{
"id": "sg:journal.1048337",
"issn": [
"0928-0707",
"1573-4846"
],
"name": "Journal of Sol-Gel Science and Technology",
"type": "Periodical"
},
{
"issueNumber": "1",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "50"
}
],
"name": "The nanoscale description of acid penetration to the gold colloids encapsulated in silica sol\u2013gel matrix",
"pagination": "48-57",
"productId": [
{
"name": "readcube_id",
"type": "PropertyValue",
"value": [
"310e67a6bf32c7e87d2a3b0d23e8905b37627e1a2d558c887add8eb966cce32d"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1007/s10971-009-1904-7"
]
},
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1010297065"
]
}
],
"sameAs": [
"https://doi.org/10.1007/s10971-009-1904-7",
"https://app.dimensions.ai/details/publication/pub.1010297065"
],
"sdDataset": "articles",
"sdDatePublished": "2019-04-10T20:46",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8684_00000510.jsonl",
"type": "ScholarlyArticle",
"url": "http://link.springer.com/10.1007%2Fs10971-009-1904-7"
}
]Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10971-009-1904-7'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10971-009-1904-7'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10971-009-1904-7'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10971-009-1904-7'
This table displays all metadata directly associated to this object as RDF triples.
185 TRIPLES
21 PREDICATES
54 URIs
19 LITERALS
7 BLANK NODES