The photodynamics of the [Ru(bpy)3]2+ ion dopant in a solvent exposed silica sol–gel thin film View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2007-08

AUTHORS

Kazushige Yokoyama, Bradley E. Johnson, Jonathan W. Bourne

ABSTRACT

The [Ru(bpy)3]2+ ion was encapsulated in a silica based sol–gel thin film, and the luminescence decay time constant of the photo-excited 3MLCT (metal-ligand-charge-transfer) was examined when this thin film was immersed in water, methanol, ethanol, 2-propanol, and glycerol. The luminescence decays of the films in the methanol, 2-propanol, and glycerol were better explained by a KWW model, while the luminescence decay of film immersed in water and ethanol were both well explained by a single exponential decay. Intriguingly, the dynamics of the dopants immersed in water, ethanol as well as in sol–gel bulk deviated from a single exponential fit and began to better explained by the the KWW model as temperature increased. The energy gap, ΔE(sol–gel film) and ΔE(solution), between the lowest 3MLCT state and atom localized 3dd state for dopants under the presence of all solvents tested in this study were extracted from the temperature dependence study of the luminescence decay time constant. Generally, the ΔE(sol–gel film) values of ethanol and water were reduced from ΔE(solution), and ΔE(sol–gel film) value in all solvents matched the value of ΔE for sol–gel bulk. The effect on the dynamics in solvent over three weeks was investigated, and the films immersed in water presented the most remarkable monotonic increase in relaxation rates finally approaching the asymptotic value observed in the water solution. This phenomenon was considered to correspond to a trapping environment change due to a hydrophilic interaction through sequential intrusion of water or ethanol solvent into sol–gel pores. More... »

PAGES

259-268

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10971-007-1566-2

DOI

http://dx.doi.org/10.1007/s10971-007-1566-2

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1008685318


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "SUNY Geneseo", 
          "id": "https://www.grid.ac/institutes/grid.264269.d", 
          "name": [
            "Department of Chemistry, State University of New York at Geneseo, 14454, Geneseo, NY, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Yokoyama", 
        "givenName": "Kazushige", 
        "id": "sg:person.01341666755.99", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01341666755.99"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Rochester", 
          "id": "https://www.grid.ac/institutes/grid.16416.34", 
          "name": [
            "Medical Center, University of Rochester, 14627, Rochester, NY, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Johnson", 
        "givenName": "Bradley E.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Cornell University", 
          "id": "https://www.grid.ac/institutes/grid.5386.8", 
          "name": [
            "Weill Medical College, Cornell University, 10021, New York, NY, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Bourne", 
        "givenName": "Jonathan W.", 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1002/adma.19930050603", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1000488169"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/1521-4095(20020318)14:6<433::aid-adma433>3.0.co;2-w", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002400282"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/225420a0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1008580609", 
          "https://doi.org/10.1038/225420a0"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1073/pnas.91.4.1229", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1014829679"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1073/pnas.151125698", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1017765347"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adma.19930050604", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027506186"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0022-3093(98)00842-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027857379"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0009-2614(99)01130-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1028458764"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1073/pnas.98.4.1577", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032768763"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0010-8545(88)80032-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039134373"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/an9931800385", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039295218"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja0270524", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039971168"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja0270524", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039971168"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1073/pnas.91.13.5740", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041174406"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/(sici)1099-1492(199802)11:1<19::aid-nbm499>3.0.co;2-o", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1044595659"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b302119j", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1051497822"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja012721j", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1051869268"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja012721j", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1051869268"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00486300", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1052364135", 
          "https://doi.org/10.1007/bf00486300"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00486300", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1052364135", 
          "https://doi.org/10.1007/bf00486300"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cm00043a028", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055407324"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cm049250v", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055411043"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cm049250v", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055411043"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cm050658h", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055411482"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cm050658h", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055411482"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cm970186+", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055418556"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cm970186+", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055418556"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cm970270p", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055418603"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cm970270p", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055418603"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cm9802806", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055419122"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cm9802806", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055419122"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic00192a009", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055546637"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/j100017a006", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055649261"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/j100040a024", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055650466"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/j100113a028", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055653474"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/j100364a039", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055667030"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja00071a049", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055704244"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja00097a064", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055706682"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja00437a020", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055732427"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja984163n", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055871226"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp0458957", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056057122"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp0458957", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056057122"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp970004z", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056123965"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp970004z", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056123965"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/la00019a063", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056137566"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/la00059a074", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056139954"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.477374", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1058066029"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.47.8565", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060566746"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.47.8565", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060566746"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevlett.68.3555", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060804788"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevlett.68.3555", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060804788"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevlett.88.105505", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060824579"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevlett.88.105505", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060824579"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1557/jmr.1998.0452", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1067901153"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2007-08", 
    "datePublishedReg": "2007-08-01", 
    "description": "The [Ru(bpy)3]2+ ion was encapsulated in a silica based sol\u2013gel thin film, and the luminescence decay time constant of the photo-excited 3MLCT (metal-ligand-charge-transfer) was examined when this thin film was immersed in water, methanol, ethanol, 2-propanol, and glycerol. The luminescence decays of the films in the methanol, 2-propanol, and glycerol were better explained by a KWW model, while the luminescence decay of film immersed in water and ethanol were both well explained by a single exponential decay. Intriguingly, the dynamics of the dopants immersed in water, ethanol as well as in sol\u2013gel bulk deviated from a single exponential fit and began to better explained by the the KWW model as temperature increased. The energy gap, \u0394E(sol\u2013gel film) and \u0394E(solution), between the lowest 3MLCT state and atom localized 3dd state for dopants under the presence of all solvents tested in this study were extracted from the temperature dependence study of the luminescence decay time constant. Generally, the \u0394E(sol\u2013gel film) values of ethanol and water were reduced from \u0394E(solution), and \u0394E(sol\u2013gel film) value in all solvents matched the value of \u0394E for sol\u2013gel bulk. The effect on the dynamics in solvent over three weeks was investigated, and the films immersed in water presented the most remarkable monotonic increase in relaxation rates finally approaching the asymptotic value observed in the water solution. This phenomenon was considered to correspond to a trapping environment change due to a hydrophilic interaction through sequential intrusion of water or ethanol solvent into sol\u2013gel pores.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s10971-007-1566-2", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isFundedItemOf": [
      {
        "id": "sg:grant.3012279", 
        "type": "MonetaryGrant"
      }
    ], 
    "isPartOf": [
      {
        "id": "sg:journal.1048337", 
        "issn": [
          "0928-0707", 
          "1573-4846"
        ], 
        "name": "Journal of Sol-Gel Science and Technology", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "2", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "43"
      }
    ], 
    "name": "The photodynamics of the [Ru(bpy)3]2+ ion dopant in a solvent exposed silica sol\u2013gel thin film", 
    "pagination": "259-268", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "2960fc0ca807c22e790540626f4484f579c5bb9db0d59ae7d691f14c3edc688d"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s10971-007-1566-2"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1008685318"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s10971-007-1566-2", 
      "https://app.dimensions.ai/details/publication/pub.1008685318"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T12:56", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000365_0000000365/records_71673_00000000.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007%2Fs10971-007-1566-2"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10971-007-1566-2'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10971-007-1566-2'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10971-007-1566-2'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10971-007-1566-2'


 

This table displays all metadata directly associated to this object as RDF triples.

206 TRIPLES      21 PREDICATES      68 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s10971-007-1566-2 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author Nea76244d5ca7464daa0c9f1c4f34ce05
4 schema:citation sg:pub.10.1007/bf00486300
5 sg:pub.10.1038/225420a0
6 https://doi.org/10.1002/(sici)1099-1492(199802)11:1<19::aid-nbm499>3.0.co;2-o
7 https://doi.org/10.1002/1521-4095(20020318)14:6<433::aid-adma433>3.0.co;2-w
8 https://doi.org/10.1002/adma.19930050603
9 https://doi.org/10.1002/adma.19930050604
10 https://doi.org/10.1016/0010-8545(88)80032-8
11 https://doi.org/10.1016/s0009-2614(99)01130-6
12 https://doi.org/10.1016/s0022-3093(98)00842-4
13 https://doi.org/10.1021/cm00043a028
14 https://doi.org/10.1021/cm049250v
15 https://doi.org/10.1021/cm050658h
16 https://doi.org/10.1021/cm970186+
17 https://doi.org/10.1021/cm970270p
18 https://doi.org/10.1021/cm9802806
19 https://doi.org/10.1021/ic00192a009
20 https://doi.org/10.1021/j100017a006
21 https://doi.org/10.1021/j100040a024
22 https://doi.org/10.1021/j100113a028
23 https://doi.org/10.1021/j100364a039
24 https://doi.org/10.1021/ja00071a049
25 https://doi.org/10.1021/ja00097a064
26 https://doi.org/10.1021/ja00437a020
27 https://doi.org/10.1021/ja012721j
28 https://doi.org/10.1021/ja0270524
29 https://doi.org/10.1021/ja984163n
30 https://doi.org/10.1021/jp0458957
31 https://doi.org/10.1021/jp970004z
32 https://doi.org/10.1021/la00019a063
33 https://doi.org/10.1021/la00059a074
34 https://doi.org/10.1039/an9931800385
35 https://doi.org/10.1039/b302119j
36 https://doi.org/10.1063/1.477374
37 https://doi.org/10.1073/pnas.151125698
38 https://doi.org/10.1073/pnas.91.13.5740
39 https://doi.org/10.1073/pnas.91.4.1229
40 https://doi.org/10.1073/pnas.98.4.1577
41 https://doi.org/10.1103/physrevb.47.8565
42 https://doi.org/10.1103/physrevlett.68.3555
43 https://doi.org/10.1103/physrevlett.88.105505
44 https://doi.org/10.1557/jmr.1998.0452
45 schema:datePublished 2007-08
46 schema:datePublishedReg 2007-08-01
47 schema:description The [Ru(bpy)3]2+ ion was encapsulated in a silica based sol–gel thin film, and the luminescence decay time constant of the photo-excited 3MLCT (metal-ligand-charge-transfer) was examined when this thin film was immersed in water, methanol, ethanol, 2-propanol, and glycerol. The luminescence decays of the films in the methanol, 2-propanol, and glycerol were better explained by a KWW model, while the luminescence decay of film immersed in water and ethanol were both well explained by a single exponential decay. Intriguingly, the dynamics of the dopants immersed in water, ethanol as well as in sol–gel bulk deviated from a single exponential fit and began to better explained by the the KWW model as temperature increased. The energy gap, ΔE(sol–gel film) and ΔE(solution), between the lowest 3MLCT state and atom localized 3dd state for dopants under the presence of all solvents tested in this study were extracted from the temperature dependence study of the luminescence decay time constant. Generally, the ΔE(sol–gel film) values of ethanol and water were reduced from ΔE(solution), and ΔE(sol–gel film) value in all solvents matched the value of ΔE for sol–gel bulk. The effect on the dynamics in solvent over three weeks was investigated, and the films immersed in water presented the most remarkable monotonic increase in relaxation rates finally approaching the asymptotic value observed in the water solution. This phenomenon was considered to correspond to a trapping environment change due to a hydrophilic interaction through sequential intrusion of water or ethanol solvent into sol–gel pores.
48 schema:genre research_article
49 schema:inLanguage en
50 schema:isAccessibleForFree false
51 schema:isPartOf N19e7693006a342548746ebc2749d241b
52 N1a05d602be6d4f298bcf5554c2197ef5
53 sg:journal.1048337
54 schema:name The photodynamics of the [Ru(bpy)3]2+ ion dopant in a solvent exposed silica sol–gel thin film
55 schema:pagination 259-268
56 schema:productId N23262c54d1ec4cbd844ddd644747f9d3
57 N76e47ba6596b454c9f9c57ab70b0f7d7
58 N93e0be2326814aadbf65475693fc9b4b
59 schema:sameAs https://app.dimensions.ai/details/publication/pub.1008685318
60 https://doi.org/10.1007/s10971-007-1566-2
61 schema:sdDatePublished 2019-04-11T12:56
62 schema:sdLicense https://scigraph.springernature.com/explorer/license/
63 schema:sdPublisher Nf9334991cdc24212bf45810141e173c3
64 schema:url http://link.springer.com/10.1007%2Fs10971-007-1566-2
65 sgo:license sg:explorer/license/
66 sgo:sdDataset articles
67 rdf:type schema:ScholarlyArticle
68 N19e7693006a342548746ebc2749d241b schema:issueNumber 2
69 rdf:type schema:PublicationIssue
70 N1a05d602be6d4f298bcf5554c2197ef5 schema:volumeNumber 43
71 rdf:type schema:PublicationVolume
72 N23262c54d1ec4cbd844ddd644747f9d3 schema:name dimensions_id
73 schema:value pub.1008685318
74 rdf:type schema:PropertyValue
75 N61c8d0d255b54c9db76ed9eb4d2f1637 rdf:first Ndb6c6d29c39b4c29a84f6a95dde7fe1e
76 rdf:rest N6573124ebfbc4a67a62423654b9102da
77 N6573124ebfbc4a67a62423654b9102da rdf:first Ncaf8a5c1d22c4e22b8195a736424e406
78 rdf:rest rdf:nil
79 N76e47ba6596b454c9f9c57ab70b0f7d7 schema:name readcube_id
80 schema:value 2960fc0ca807c22e790540626f4484f579c5bb9db0d59ae7d691f14c3edc688d
81 rdf:type schema:PropertyValue
82 N93e0be2326814aadbf65475693fc9b4b schema:name doi
83 schema:value 10.1007/s10971-007-1566-2
84 rdf:type schema:PropertyValue
85 Ncaf8a5c1d22c4e22b8195a736424e406 schema:affiliation https://www.grid.ac/institutes/grid.5386.8
86 schema:familyName Bourne
87 schema:givenName Jonathan W.
88 rdf:type schema:Person
89 Ndb6c6d29c39b4c29a84f6a95dde7fe1e schema:affiliation https://www.grid.ac/institutes/grid.16416.34
90 schema:familyName Johnson
91 schema:givenName Bradley E.
92 rdf:type schema:Person
93 Nea76244d5ca7464daa0c9f1c4f34ce05 rdf:first sg:person.01341666755.99
94 rdf:rest N61c8d0d255b54c9db76ed9eb4d2f1637
95 Nf9334991cdc24212bf45810141e173c3 schema:name Springer Nature - SN SciGraph project
96 rdf:type schema:Organization
97 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
98 schema:name Chemical Sciences
99 rdf:type schema:DefinedTerm
100 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
101 schema:name Physical Chemistry (incl. Structural)
102 rdf:type schema:DefinedTerm
103 sg:grant.3012279 http://pending.schema.org/fundedItem sg:pub.10.1007/s10971-007-1566-2
104 rdf:type schema:MonetaryGrant
105 sg:journal.1048337 schema:issn 0928-0707
106 1573-4846
107 schema:name Journal of Sol-Gel Science and Technology
108 rdf:type schema:Periodical
109 sg:person.01341666755.99 schema:affiliation https://www.grid.ac/institutes/grid.264269.d
110 schema:familyName Yokoyama
111 schema:givenName Kazushige
112 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01341666755.99
113 rdf:type schema:Person
114 sg:pub.10.1007/bf00486300 schema:sameAs https://app.dimensions.ai/details/publication/pub.1052364135
115 https://doi.org/10.1007/bf00486300
116 rdf:type schema:CreativeWork
117 sg:pub.10.1038/225420a0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1008580609
118 https://doi.org/10.1038/225420a0
119 rdf:type schema:CreativeWork
120 https://doi.org/10.1002/(sici)1099-1492(199802)11:1<19::aid-nbm499>3.0.co;2-o schema:sameAs https://app.dimensions.ai/details/publication/pub.1044595659
121 rdf:type schema:CreativeWork
122 https://doi.org/10.1002/1521-4095(20020318)14:6<433::aid-adma433>3.0.co;2-w schema:sameAs https://app.dimensions.ai/details/publication/pub.1002400282
123 rdf:type schema:CreativeWork
124 https://doi.org/10.1002/adma.19930050603 schema:sameAs https://app.dimensions.ai/details/publication/pub.1000488169
125 rdf:type schema:CreativeWork
126 https://doi.org/10.1002/adma.19930050604 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027506186
127 rdf:type schema:CreativeWork
128 https://doi.org/10.1016/0010-8545(88)80032-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039134373
129 rdf:type schema:CreativeWork
130 https://doi.org/10.1016/s0009-2614(99)01130-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1028458764
131 rdf:type schema:CreativeWork
132 https://doi.org/10.1016/s0022-3093(98)00842-4 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027857379
133 rdf:type schema:CreativeWork
134 https://doi.org/10.1021/cm00043a028 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055407324
135 rdf:type schema:CreativeWork
136 https://doi.org/10.1021/cm049250v schema:sameAs https://app.dimensions.ai/details/publication/pub.1055411043
137 rdf:type schema:CreativeWork
138 https://doi.org/10.1021/cm050658h schema:sameAs https://app.dimensions.ai/details/publication/pub.1055411482
139 rdf:type schema:CreativeWork
140 https://doi.org/10.1021/cm970186+ schema:sameAs https://app.dimensions.ai/details/publication/pub.1055418556
141 rdf:type schema:CreativeWork
142 https://doi.org/10.1021/cm970270p schema:sameAs https://app.dimensions.ai/details/publication/pub.1055418603
143 rdf:type schema:CreativeWork
144 https://doi.org/10.1021/cm9802806 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055419122
145 rdf:type schema:CreativeWork
146 https://doi.org/10.1021/ic00192a009 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055546637
147 rdf:type schema:CreativeWork
148 https://doi.org/10.1021/j100017a006 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055649261
149 rdf:type schema:CreativeWork
150 https://doi.org/10.1021/j100040a024 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055650466
151 rdf:type schema:CreativeWork
152 https://doi.org/10.1021/j100113a028 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055653474
153 rdf:type schema:CreativeWork
154 https://doi.org/10.1021/j100364a039 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055667030
155 rdf:type schema:CreativeWork
156 https://doi.org/10.1021/ja00071a049 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055704244
157 rdf:type schema:CreativeWork
158 https://doi.org/10.1021/ja00097a064 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055706682
159 rdf:type schema:CreativeWork
160 https://doi.org/10.1021/ja00437a020 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055732427
161 rdf:type schema:CreativeWork
162 https://doi.org/10.1021/ja012721j schema:sameAs https://app.dimensions.ai/details/publication/pub.1051869268
163 rdf:type schema:CreativeWork
164 https://doi.org/10.1021/ja0270524 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039971168
165 rdf:type schema:CreativeWork
166 https://doi.org/10.1021/ja984163n schema:sameAs https://app.dimensions.ai/details/publication/pub.1055871226
167 rdf:type schema:CreativeWork
168 https://doi.org/10.1021/jp0458957 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056057122
169 rdf:type schema:CreativeWork
170 https://doi.org/10.1021/jp970004z schema:sameAs https://app.dimensions.ai/details/publication/pub.1056123965
171 rdf:type schema:CreativeWork
172 https://doi.org/10.1021/la00019a063 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056137566
173 rdf:type schema:CreativeWork
174 https://doi.org/10.1021/la00059a074 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056139954
175 rdf:type schema:CreativeWork
176 https://doi.org/10.1039/an9931800385 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039295218
177 rdf:type schema:CreativeWork
178 https://doi.org/10.1039/b302119j schema:sameAs https://app.dimensions.ai/details/publication/pub.1051497822
179 rdf:type schema:CreativeWork
180 https://doi.org/10.1063/1.477374 schema:sameAs https://app.dimensions.ai/details/publication/pub.1058066029
181 rdf:type schema:CreativeWork
182 https://doi.org/10.1073/pnas.151125698 schema:sameAs https://app.dimensions.ai/details/publication/pub.1017765347
183 rdf:type schema:CreativeWork
184 https://doi.org/10.1073/pnas.91.13.5740 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041174406
185 rdf:type schema:CreativeWork
186 https://doi.org/10.1073/pnas.91.4.1229 schema:sameAs https://app.dimensions.ai/details/publication/pub.1014829679
187 rdf:type schema:CreativeWork
188 https://doi.org/10.1073/pnas.98.4.1577 schema:sameAs https://app.dimensions.ai/details/publication/pub.1032768763
189 rdf:type schema:CreativeWork
190 https://doi.org/10.1103/physrevb.47.8565 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060566746
191 rdf:type schema:CreativeWork
192 https://doi.org/10.1103/physrevlett.68.3555 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060804788
193 rdf:type schema:CreativeWork
194 https://doi.org/10.1103/physrevlett.88.105505 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060824579
195 rdf:type schema:CreativeWork
196 https://doi.org/10.1557/jmr.1998.0452 schema:sameAs https://app.dimensions.ai/details/publication/pub.1067901153
197 rdf:type schema:CreativeWork
198 https://www.grid.ac/institutes/grid.16416.34 schema:alternateName University of Rochester
199 schema:name Medical Center, University of Rochester, 14627, Rochester, NY, USA
200 rdf:type schema:Organization
201 https://www.grid.ac/institutes/grid.264269.d schema:alternateName SUNY Geneseo
202 schema:name Department of Chemistry, State University of New York at Geneseo, 14454, Geneseo, NY, USA
203 rdf:type schema:Organization
204 https://www.grid.ac/institutes/grid.5386.8 schema:alternateName Cornell University
205 schema:name Weill Medical College, Cornell University, 10021, New York, NY, USA
206 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...