Photocatalytic degradation of 2,4-dichlorophenoxiacetic acid and 2,4,6-trichlorophenol with ZrO2 and Mn/ZrO2 sol-gel materials View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2006-02-24

AUTHORS

T. López, M. Alvarez, F. Tzompantzi, M. Picquart

ABSTRACT

Because of its semiconductor properties, sol-gel zirconia can be used as a photocatalyst. When zirconia is doped with transition metals, its electronic properties are modified. In this work, sol-gel Mn/ZrO2 and ZrO2 materials were tested for photocatalytic degradation of 2,4-dichlorophenoxiacetic acid and 2,4,6-trichlorophenol. The powders were characterized by XRD, UV-Vis and Raman spectroscopy. The apparent rate constants were calculated assuming pseudo-first order kinetics. The results reveal that ZrO2 is effective as a photocatalyst; moreover, its photocatalytic properties improve when it is doped with manganese. More... »

PAGES

207-211

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10971-005-6630-1

DOI

http://dx.doi.org/10.1007/s10971-005-6630-1

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1047805839


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Engineering", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0912", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Materials Engineering", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Department of Chemistry, Universidad Aut\u00f3noma Metropolitana-Iztapalapa, P. O. Box 44-534, 09340, M\u00e9xico, D. F.", 
          "id": "http://www.grid.ac/institutes/grid.7220.7", 
          "name": [
            "Department of Chemistry, Universidad Aut\u00f3noma Metropolitana-Iztapalapa, P. O. Box 44-534, 09340, M\u00e9xico, D. F."
          ], 
          "type": "Organization"
        }, 
        "familyName": "L\u00f3pez", 
        "givenName": "T.", 
        "id": "sg:person.01224263261.90", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01224263261.90"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Chemistry, Universidad Aut\u00f3noma Metropolitana-Iztapalapa, P. O. Box 44-534, 09340, M\u00e9xico, D. F.", 
          "id": "http://www.grid.ac/institutes/grid.7220.7", 
          "name": [
            "Department of Chemistry, Universidad Aut\u00f3noma Metropolitana-Iztapalapa, P. O. Box 44-534, 09340, M\u00e9xico, D. F."
          ], 
          "type": "Organization"
        }, 
        "familyName": "Alvarez", 
        "givenName": "M.", 
        "id": "sg:person.0662622527.19", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0662622527.19"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Instituto Mexicano del Petr\u00f3leo, Eje Central L\u00e1zaro C\u00e1rdenas 152, 07000, M\u00e9xico, D.F., M\u00e9xico", 
          "id": "http://www.grid.ac/institutes/grid.419156.e", 
          "name": [
            "Instituto Mexicano del Petr\u00f3leo, Eje Central L\u00e1zaro C\u00e1rdenas 152, 07000, M\u00e9xico, D.F., M\u00e9xico"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Tzompantzi", 
        "givenName": "F.", 
        "id": "sg:person.011000766245.10", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011000766245.10"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Physics, Universidad Aut\u00f3noma Metropolitana-Iztapalapa, P. O. Box 44-534, 09340, M\u00e9xico, D. F.", 
          "id": "http://www.grid.ac/institutes/grid.7220.7", 
          "name": [
            "Department of Physics, Universidad Aut\u00f3noma Metropolitana-Iztapalapa, P. O. Box 44-534, 09340, M\u00e9xico, D. F."
          ], 
          "type": "Organization"
        }, 
        "familyName": "Picquart", 
        "givenName": "M.", 
        "id": "sg:person.0772163367.18", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0772163367.18"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1023/a:1011272521955", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1019595345", 
          "https://doi.org/10.1023/a:1011272521955"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2006-02-24", 
    "datePublishedReg": "2006-02-24", 
    "description": "Because of its semiconductor properties, sol-gel zirconia can be used as a photocatalyst. When zirconia is doped with transition metals, its electronic properties are modified. In this work, sol-gel Mn/ZrO2 and ZrO2 materials were tested for photocatalytic degradation of 2,4-dichlorophenoxiacetic acid and 2,4,6-trichlorophenol. The powders were characterized by XRD, UV-Vis and Raman spectroscopy. The apparent rate constants were calculated assuming pseudo-first order kinetics. The results reveal that ZrO2 is effective as a photocatalyst; moreover, its photocatalytic properties improve when it is doped with manganese.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/s10971-005-6630-1", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1048337", 
        "issn": [
          "0928-0707", 
          "1573-4846"
        ], 
        "name": "Journal of Sol-Gel Science and Technology", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "3", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "37"
      }
    ], 
    "keywords": [
      "photocatalytic degradation", 
      "sol-gel zirconia", 
      "sol-gel materials", 
      "Mn/ZrO2", 
      "pseudo-first order kinetics", 
      "apparent rate constants", 
      "UV-Vis", 
      "transition metals", 
      "photocatalytic properties", 
      "Raman spectroscopy", 
      "electronic properties", 
      "ZrO2 materials", 
      "semiconductor properties", 
      "order kinetics", 
      "dichlorophenoxiacetic acid", 
      "rate constants", 
      "photocatalyst", 
      "ZrO2", 
      "trichlorophenol", 
      "zirconia", 
      "properties", 
      "acid", 
      "spectroscopy", 
      "XRD", 
      "materials", 
      "degradation", 
      "metals", 
      "manganese", 
      "kinetics", 
      "constants", 
      "powder", 
      "work", 
      "results"
    ], 
    "name": "Photocatalytic degradation of 2,4-dichlorophenoxiacetic acid and 2,4,6-trichlorophenol with ZrO2 and Mn/ZrO2 sol-gel materials", 
    "pagination": "207-211", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1047805839"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s10971-005-6630-1"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s10971-005-6630-1", 
      "https://app.dimensions.ai/details/publication/pub.1047805839"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-11-24T20:51", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20221124/entities/gbq_results/article/article_418.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/s10971-005-6630-1"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10971-005-6630-1'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10971-005-6630-1'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10971-005-6630-1'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10971-005-6630-1'


 

This table displays all metadata directly associated to this object as RDF triples.

120 TRIPLES      21 PREDICATES      58 URIs      49 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s10971-005-6630-1 schema:about anzsrc-for:09
2 anzsrc-for:0912
3 schema:author N351a16535f9f4b9eb295fc98600d862a
4 schema:citation sg:pub.10.1023/a:1011272521955
5 schema:datePublished 2006-02-24
6 schema:datePublishedReg 2006-02-24
7 schema:description Because of its semiconductor properties, sol-gel zirconia can be used as a photocatalyst. When zirconia is doped with transition metals, its electronic properties are modified. In this work, sol-gel Mn/ZrO2 and ZrO2 materials were tested for photocatalytic degradation of 2,4-dichlorophenoxiacetic acid and 2,4,6-trichlorophenol. The powders were characterized by XRD, UV-Vis and Raman spectroscopy. The apparent rate constants were calculated assuming pseudo-first order kinetics. The results reveal that ZrO2 is effective as a photocatalyst; moreover, its photocatalytic properties improve when it is doped with manganese.
8 schema:genre article
9 schema:isAccessibleForFree false
10 schema:isPartOf N6e5439f9dc2f44cea1a75fd1c06767b5
11 Nd1fd6b5f8b4644e08fa17c4793bae550
12 sg:journal.1048337
13 schema:keywords Mn/ZrO2
14 Raman spectroscopy
15 UV-Vis
16 XRD
17 ZrO2
18 ZrO2 materials
19 acid
20 apparent rate constants
21 constants
22 degradation
23 dichlorophenoxiacetic acid
24 electronic properties
25 kinetics
26 manganese
27 materials
28 metals
29 order kinetics
30 photocatalyst
31 photocatalytic degradation
32 photocatalytic properties
33 powder
34 properties
35 pseudo-first order kinetics
36 rate constants
37 results
38 semiconductor properties
39 sol-gel materials
40 sol-gel zirconia
41 spectroscopy
42 transition metals
43 trichlorophenol
44 work
45 zirconia
46 schema:name Photocatalytic degradation of 2,4-dichlorophenoxiacetic acid and 2,4,6-trichlorophenol with ZrO2 and Mn/ZrO2 sol-gel materials
47 schema:pagination 207-211
48 schema:productId N9c57d216cdcd40e5bec2f35e219e1457
49 Nbebfebc290314cd8a526f147de3e4333
50 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047805839
51 https://doi.org/10.1007/s10971-005-6630-1
52 schema:sdDatePublished 2022-11-24T20:51
53 schema:sdLicense https://scigraph.springernature.com/explorer/license/
54 schema:sdPublisher N1fe89d26de14416997b8b07cb10d6fff
55 schema:url https://doi.org/10.1007/s10971-005-6630-1
56 sgo:license sg:explorer/license/
57 sgo:sdDataset articles
58 rdf:type schema:ScholarlyArticle
59 N1fe89d26de14416997b8b07cb10d6fff schema:name Springer Nature - SN SciGraph project
60 rdf:type schema:Organization
61 N351a16535f9f4b9eb295fc98600d862a rdf:first sg:person.01224263261.90
62 rdf:rest Nb63aa3c5501141a984178fe6981ecd64
63 N3fa6cc7c014740da8692249c1dec11f8 rdf:first sg:person.0772163367.18
64 rdf:rest rdf:nil
65 N6e5439f9dc2f44cea1a75fd1c06767b5 schema:volumeNumber 37
66 rdf:type schema:PublicationVolume
67 N9c57d216cdcd40e5bec2f35e219e1457 schema:name doi
68 schema:value 10.1007/s10971-005-6630-1
69 rdf:type schema:PropertyValue
70 Nb63aa3c5501141a984178fe6981ecd64 rdf:first sg:person.0662622527.19
71 rdf:rest Nc1d71ca4935c406bb56614dd2c908c28
72 Nbebfebc290314cd8a526f147de3e4333 schema:name dimensions_id
73 schema:value pub.1047805839
74 rdf:type schema:PropertyValue
75 Nc1d71ca4935c406bb56614dd2c908c28 rdf:first sg:person.011000766245.10
76 rdf:rest N3fa6cc7c014740da8692249c1dec11f8
77 Nd1fd6b5f8b4644e08fa17c4793bae550 schema:issueNumber 3
78 rdf:type schema:PublicationIssue
79 anzsrc-for:09 schema:inDefinedTermSet anzsrc-for:
80 schema:name Engineering
81 rdf:type schema:DefinedTerm
82 anzsrc-for:0912 schema:inDefinedTermSet anzsrc-for:
83 schema:name Materials Engineering
84 rdf:type schema:DefinedTerm
85 sg:journal.1048337 schema:issn 0928-0707
86 1573-4846
87 schema:name Journal of Sol-Gel Science and Technology
88 schema:publisher Springer Nature
89 rdf:type schema:Periodical
90 sg:person.011000766245.10 schema:affiliation grid-institutes:grid.419156.e
91 schema:familyName Tzompantzi
92 schema:givenName F.
93 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011000766245.10
94 rdf:type schema:Person
95 sg:person.01224263261.90 schema:affiliation grid-institutes:grid.7220.7
96 schema:familyName López
97 schema:givenName T.
98 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01224263261.90
99 rdf:type schema:Person
100 sg:person.0662622527.19 schema:affiliation grid-institutes:grid.7220.7
101 schema:familyName Alvarez
102 schema:givenName M.
103 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0662622527.19
104 rdf:type schema:Person
105 sg:person.0772163367.18 schema:affiliation grid-institutes:grid.7220.7
106 schema:familyName Picquart
107 schema:givenName M.
108 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0772163367.18
109 rdf:type schema:Person
110 sg:pub.10.1023/a:1011272521955 schema:sameAs https://app.dimensions.ai/details/publication/pub.1019595345
111 https://doi.org/10.1023/a:1011272521955
112 rdf:type schema:CreativeWork
113 grid-institutes:grid.419156.e schema:alternateName Instituto Mexicano del Petróleo, Eje Central Lázaro Cárdenas 152, 07000, México, D.F., México
114 schema:name Instituto Mexicano del Petróleo, Eje Central Lázaro Cárdenas 152, 07000, México, D.F., México
115 rdf:type schema:Organization
116 grid-institutes:grid.7220.7 schema:alternateName Department of Chemistry, Universidad Autónoma Metropolitana-Iztapalapa, P. O. Box 44-534, 09340, México, D. F.
117 Department of Physics, Universidad Autónoma Metropolitana-Iztapalapa, P. O. Box 44-534, 09340, México, D. F.
118 schema:name Department of Chemistry, Universidad Autónoma Metropolitana-Iztapalapa, P. O. Box 44-534, 09340, México, D. F.
119 Department of Physics, Universidad Autónoma Metropolitana-Iztapalapa, P. O. Box 44-534, 09340, México, D. F.
120 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...