Irreversible Dissociation of Tris-2,2′-Bipyridyl-iron(II) Complex in TEOS-Derived Acidic Silica Sol View Full Text


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Article Info

DATE

2005-08

AUTHORS

Chikashi Nakanishi, Mamoru Senna

ABSTRACT

Irreversible dissociation of tris-2,2′-bipyridine iron(II) (Fe(II)-bpy) to completion in acidic silica sol was elucidated in an attempt to designing silica-supported complex compounds. Liberated Fe(II) was oxidized to form tetrahedral [FeCl4]− ion, preventing regeneration back to Fe(II)-bpy. Change in the rate of dissociation was also discussed by taking competitive coordination of Cl and H2O with Fe(II) into account. More... »

PAGES

137-142

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10971-005-1389-y

DOI

http://dx.doi.org/10.1007/s10971-005-1389-y

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1029776450


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