Irreversible Dissociation of Tris-2,2′-Bipyridyl-iron(II) Complex in TEOS-Derived Acidic Silica Sol View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2005-08

AUTHORS

Chikashi Nakanishi, Mamoru Senna

ABSTRACT

Irreversible dissociation of tris-2,2′-bipyridine iron(II) (Fe(II)-bpy) to completion in acidic silica sol was elucidated in an attempt to designing silica-supported complex compounds. Liberated Fe(II) was oxidized to form tetrahedral [FeCl4]− ion, preventing regeneration back to Fe(II)-bpy. Change in the rate of dissociation was also discussed by taking competitive coordination of Cl and H2O with Fe(II) into account. More... »

PAGES

137-142

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10971-005-1389-y

DOI

http://dx.doi.org/10.1007/s10971-005-1389-y

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1029776450


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Engineering", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0912", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Materials Engineering", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Department of Applied Chemistry, Faculty of Science and Technology, Keio University, 3-14-1 Hiyoshi, Kohoku-ku, 223-8522, Yokohama, Japan", 
          "id": "http://www.grid.ac/institutes/grid.26091.3c", 
          "name": [
            "Department of Applied Chemistry, Faculty of Science and Technology, Keio University, 3-14-1 Hiyoshi, Kohoku-ku, 223-8522, Yokohama, Japan"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Nakanishi", 
        "givenName": "Chikashi", 
        "id": "sg:person.0776221433.68", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0776221433.68"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Applied Chemistry, Faculty of Science and Technology, Keio University, 3-14-1 Hiyoshi, Kohoku-ku, 223-8522, Yokohama, Japan", 
          "id": "http://www.grid.ac/institutes/grid.26091.3c", 
          "name": [
            "Department of Applied Chemistry, Faculty of Science and Technology, Keio University, 3-14-1 Hiyoshi, Kohoku-ku, 223-8522, Yokohama, Japan"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Senna", 
        "givenName": "Mamoru", 
        "id": "sg:person.011363404413.06", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011363404413.06"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1023/a:1020749604691", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1044964919", 
          "https://doi.org/10.1023/a:1020749604691"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2005-08", 
    "datePublishedReg": "2005-08-01", 
    "description": "Irreversible dissociation of tris-2,2\u2032-bipyridine iron(II) (Fe(II)-bpy) to completion in acidic silica sol was elucidated in an attempt to designing silica-supported complex compounds. Liberated Fe(II) was oxidized to form tetrahedral [FeCl4]\u2212 ion, preventing regeneration back to Fe(II)-bpy. Change in the rate of dissociation was also discussed by taking competitive coordination of Cl and H2O with Fe(II) into account.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/s10971-005-1389-y", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1048337", 
        "issn": [
          "0928-0707", 
          "1573-4846"
        ], 
        "name": "Journal of Sol-Gel Science and Technology", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "2", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "35"
      }
    ], 
    "keywords": [
      "acidic silica sol", 
      "silica sol", 
      "irreversible dissociation", 
      "competitive coordination", 
      "complex compounds", 
      "rate of dissociation", 
      "dissociation", 
      "sol", 
      "bpy", 
      "bipyridine", 
      "bipyridyl", 
      "ions", 
      "compounds", 
      "H2O", 
      "tri", 
      "Cl", 
      "coordination", 
      "liberated", 
      "regeneration", 
      "rate", 
      "changes", 
      "attempt", 
      "account", 
      "completion"
    ], 
    "name": "Irreversible Dissociation of Tris-2,2\u2032-Bipyridyl-iron(II) Complex in TEOS-Derived Acidic Silica Sol", 
    "pagination": "137-142", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1029776450"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s10971-005-1389-y"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s10971-005-1389-y", 
      "https://app.dimensions.ai/details/publication/pub.1029776450"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-08-04T16:55", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220804/entities/gbq_results/article/article_406.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/s10971-005-1389-y"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10971-005-1389-y'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10971-005-1389-y'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10971-005-1389-y'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10971-005-1389-y'


 

This table displays all metadata directly associated to this object as RDF triples.

92 TRIPLES      21 PREDICATES      50 URIs      41 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s10971-005-1389-y schema:about anzsrc-for:09
2 anzsrc-for:0912
3 schema:author N4a630d84800a48d29dbad8da1ba5cc2d
4 schema:citation sg:pub.10.1023/a:1020749604691
5 schema:datePublished 2005-08
6 schema:datePublishedReg 2005-08-01
7 schema:description Irreversible dissociation of tris-2,2′-bipyridine iron(II) (Fe(II)-bpy) to completion in acidic silica sol was elucidated in an attempt to designing silica-supported complex compounds. Liberated Fe(II) was oxidized to form tetrahedral [FeCl4]− ion, preventing regeneration back to Fe(II)-bpy. Change in the rate of dissociation was also discussed by taking competitive coordination of Cl and H2O with Fe(II) into account.
8 schema:genre article
9 schema:isAccessibleForFree false
10 schema:isPartOf Ncb522d862380411ea74626bf57c1486c
11 Nf80bd48dd2fa424e81dddca9d8241b38
12 sg:journal.1048337
13 schema:keywords Cl
14 H2O
15 account
16 acidic silica sol
17 attempt
18 bipyridine
19 bipyridyl
20 bpy
21 changes
22 competitive coordination
23 completion
24 complex compounds
25 compounds
26 coordination
27 dissociation
28 ions
29 irreversible dissociation
30 liberated
31 rate
32 rate of dissociation
33 regeneration
34 silica sol
35 sol
36 tri
37 schema:name Irreversible Dissociation of Tris-2,2′-Bipyridyl-iron(II) Complex in TEOS-Derived Acidic Silica Sol
38 schema:pagination 137-142
39 schema:productId N86e43e688ad14430bd2d5ae62279dde1
40 Nc55c5dc26fad4fb9ba21b864353e3892
41 schema:sameAs https://app.dimensions.ai/details/publication/pub.1029776450
42 https://doi.org/10.1007/s10971-005-1389-y
43 schema:sdDatePublished 2022-08-04T16:55
44 schema:sdLicense https://scigraph.springernature.com/explorer/license/
45 schema:sdPublisher N60caa36226ba4582b3bb27a9ff324748
46 schema:url https://doi.org/10.1007/s10971-005-1389-y
47 sgo:license sg:explorer/license/
48 sgo:sdDataset articles
49 rdf:type schema:ScholarlyArticle
50 N4a630d84800a48d29dbad8da1ba5cc2d rdf:first sg:person.0776221433.68
51 rdf:rest N53ae835389be48479ca3289a0fd4c1fe
52 N53ae835389be48479ca3289a0fd4c1fe rdf:first sg:person.011363404413.06
53 rdf:rest rdf:nil
54 N60caa36226ba4582b3bb27a9ff324748 schema:name Springer Nature - SN SciGraph project
55 rdf:type schema:Organization
56 N86e43e688ad14430bd2d5ae62279dde1 schema:name dimensions_id
57 schema:value pub.1029776450
58 rdf:type schema:PropertyValue
59 Nc55c5dc26fad4fb9ba21b864353e3892 schema:name doi
60 schema:value 10.1007/s10971-005-1389-y
61 rdf:type schema:PropertyValue
62 Ncb522d862380411ea74626bf57c1486c schema:issueNumber 2
63 rdf:type schema:PublicationIssue
64 Nf80bd48dd2fa424e81dddca9d8241b38 schema:volumeNumber 35
65 rdf:type schema:PublicationVolume
66 anzsrc-for:09 schema:inDefinedTermSet anzsrc-for:
67 schema:name Engineering
68 rdf:type schema:DefinedTerm
69 anzsrc-for:0912 schema:inDefinedTermSet anzsrc-for:
70 schema:name Materials Engineering
71 rdf:type schema:DefinedTerm
72 sg:journal.1048337 schema:issn 0928-0707
73 1573-4846
74 schema:name Journal of Sol-Gel Science and Technology
75 schema:publisher Springer Nature
76 rdf:type schema:Periodical
77 sg:person.011363404413.06 schema:affiliation grid-institutes:grid.26091.3c
78 schema:familyName Senna
79 schema:givenName Mamoru
80 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011363404413.06
81 rdf:type schema:Person
82 sg:person.0776221433.68 schema:affiliation grid-institutes:grid.26091.3c
83 schema:familyName Nakanishi
84 schema:givenName Chikashi
85 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0776221433.68
86 rdf:type schema:Person
87 sg:pub.10.1023/a:1020749604691 schema:sameAs https://app.dimensions.ai/details/publication/pub.1044964919
88 https://doi.org/10.1023/a:1020749604691
89 rdf:type schema:CreativeWork
90 grid-institutes:grid.26091.3c schema:alternateName Department of Applied Chemistry, Faculty of Science and Technology, Keio University, 3-14-1 Hiyoshi, Kohoku-ku, 223-8522, Yokohama, Japan
91 schema:name Department of Applied Chemistry, Faculty of Science and Technology, Keio University, 3-14-1 Hiyoshi, Kohoku-ku, 223-8522, Yokohama, Japan
92 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...