Ontology type: schema:ScholarlyArticle
2005-08
AUTHORSChikashi Nakanishi, Mamoru Senna
ABSTRACTIrreversible dissociation of tris-2,2′-bipyridine iron(II) (Fe(II)-bpy) to completion in acidic silica sol was elucidated in an attempt to designing silica-supported complex compounds. Liberated Fe(II) was oxidized to form tetrahedral [FeCl4]− ion, preventing regeneration back to Fe(II)-bpy. Change in the rate of dissociation was also discussed by taking competitive coordination of Cl and H2O with Fe(II) into account. More... »
PAGES137-142
http://scigraph.springernature.com/pub.10.1007/s10971-005-1389-y
DOIhttp://dx.doi.org/10.1007/s10971-005-1389-y
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