Synthesis and Characterization of ZrO2-CaSO4 Materials Prepared by the Sol–Gel Method View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2004-12

AUTHORS

J. Garcia, T. Lopez, R. Gomez, D. H. Aguilar, P. Quintana

ABSTRACT

Mixtures of ZrO2-CaSO4 in different molar ratio were prepared by the sol–gel method. The precursors were anhydrous calcium sulfate (CaSO4) and zirconium n-butoxide in ethanol. Sulfuric acid was used as a hydrolysis catalyst to carry out the reaction at pH 3. The samples were thermally annealed and characterized by X-ray powder diffraction (XRD). Crystalline structure for selected samples (100, 90, 80% molar ZrO2), were refined by the Rietveld method. Tetragonal zirconia and anhydrite were obtained in all compositions ranges, from 400 up to 800°C, although baddeyelite appears in the zirconia rich end (98% molar) from 600°C. Towards high calcium content, different nanostructured calcium sulfates as gypsum, bassanite and anhydrite were obtained. More... »

PAGES

333-337

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10971-004-5812-6

DOI

http://dx.doi.org/10.1007/s10971-004-5812-6

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https://app.dimensions.ai/details/publication/pub.1030770564


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