Extraction of thallium and indium isotopes as the homologues of nihonium into the ionic liquids View Full Text


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Article Info

DATE

2018-10-27

AUTHORS

Katerina Cubova, Miroslava Semelova, Mojmir Nemec, Jan John, Juraj Milacic, Jon Petter Omtvedt, Jan Stursa

ABSTRACT

Extraction of thallium and indium, as the homologues of nihonium, from HCl solutions into hydrophobic ionic liquids was studied. In the presence of NaClO2 as the oxidizing agent, thallium is effectively extracted into all the tested ionic liquids from 0.2 to 5 M HCl. In absence of NaClO2, thallium extraction strongly depends on the HCl concentration and no extraction of indium was observed. Using [C6mim][NTf2] and [Tbma][NTf2], the thallium/indium separation factors SF(Tl/In) > 4 × 104 can be achieved. Hence, the system with NaClO2 oxidizing agent can be considered a candidate for the future studies of nihonium chemical properties. More... »

PAGES

2455-2461

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10967-018-6270-x

DOI

http://dx.doi.org/10.1007/s10967-018-6270-x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1107880675


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