Hydrolytic and thermal stability of magnesium potassium phosphate compound for immobilization of high level waste View Full Text


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Article Info

DATE

2018-12

AUTHORS

Sergey E. Vinokurov, Svetlana A. Kulikova, Boris F. Myasoedov

ABSTRACT

The samples of the magnesium potassium phosphate (MPP) compound have been synthesized during solidification of high level waste (HLW) surrogate. The compound consists of a main phosphate phases Mg1.1Na0.35K0.45PO4 × (4–6)H2O and MgCs0.5Na0.2K0.3PO4 × (5–6)H2O. Differential leaching rates of 239Pu, 152Eu and 90Sr from the MPP compound after heat treatment (450 °C) are 7.8 × 10−9; 1.7 × 10−7 and 8.8 × 10−6 g cm−2 day−1, respectively. The coefficient of thermal expansion of MPP compound—(11.6 ± 0.3) × 10−6 °C−1; coefficient of thermal conductivity averages 0.5 W m−1 K−1. The properties of MPP compound meet the regulatory requirements for solidified HLW. More... »

PAGES

1-5

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10967-018-6181-x

DOI

http://dx.doi.org/10.1007/s10967-018-6181-x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1107037793


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