Actinides selective extractants coated magnetite nanoparticles for analytical applications View Full Text


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Article Info

DATE

2017-04-13

AUTHORS

Shashikala Ojha, Sankararao Chappa, Amol M. Mhatre, Krishan Kant Singh, Vivek Chavan, Ashok K. Pandey

ABSTRACT

N,N,N′,N′-tetraoctyl diglycolamide (TODGA) and bis(2-ethylhexy)phosphoric acid (HDEHP) were coated on Fe3O4 nanoparticles under different chemical conditions. The TODGA-coated magnetite nanoparticles (Fe3O4@TODGA) captured representative actinides Am(III) and Pu(IV) at 3–4 M HNO3 with high efficiency. However, the HNO3 induced pre-organization of TODGA, before coating on the magnetite nanoparticles, was found to be important for the sorption of Am(III) and Pu(IV) ions. The Fe3O4@HDEHP particles exhibited selectivity toward Pu(IV), and Am(III) did not sorb from 3 to 4 M HNO3. The quantification of Pu(IV) preconcentrated on coated particles was carried out by removing the extractant coating in dioxane based scintillator, followed by liquid scintillation counting. More... »

PAGES

675-683

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10967-017-5246-6

DOI

http://dx.doi.org/10.1007/s10967-017-5246-6

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1084820038


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