Nitric acid adduct formation during crystallization of barium and strontium nitrates and their co-precipitation from nitric acid media View Full Text


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Article Info

DATE

2015-04

AUTHORS

N. E. Mishina, B. Ya. Zilberman, A. A. Lumpov, T. I. Koltsova, E. A. Puzikov, D. V. Ryabkov

ABSTRACT

The molar solubilities of Ba, Sr and Pb nitrates in nitric acid as a function of total nitrate concentration is presented and described by the mass action law, indicating on formation of the adducts with nitric acid. Precipitates of Ba(NO3)2 and Sr(NO3)2 crystallized from nitric acid were studied by ISP OES and IR spectroscopy. The data obtained confirmed formation of metastable adducts with nitric acid. IR and X-ray diffraction studies of the mixed salt systems indicated conversion of the mixed salts into (Ba,Sr)(NO3)2 solid solution of discrete structure in range of total nitrate ion concentration ~6 mol/L. More... »

PAGES

387-393

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10967-014-3691-z

DOI

http://dx.doi.org/10.1007/s10967-014-3691-z

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1009766353


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