Stability of phenyl trifluoromethyl sulfone as diluent in a grouped actinide extraction process View Full Text


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Article Info

DATE

2015-04

AUTHORS

Jenny Halleröd, Christian Ekberg, Mark Foreman, Elin Löfström Engdahl, Emma Aneheim

ABSTRACT

In this work, stability experiments have been performed on a phenyl trifluoromethyl sulfone based solvent containing 6,6′-bis(5,6-dialkyl-[1,2,4-]triazin-3-yl)-2,2′-bipyridine and tri-butyl phosphate. This solvent is intended to be used in a grouped actinide extraction process for partitioning and transmutation purposes. The distribution ratio for americium was determined to approximately 20 and for europium approximately 0.26 giving a separation factor of 77. The solvent maintain good distribution ratios and separation factors during both gamma irradiation of 6.6 kGy h−1 for up to 24 h and acid contact for up to 6 weeks at room temperature. More... »

PAGES

287-291

References to SciGraph publications

  • 2011-09. Thermal stability of UNEX/HCCD-PEG diluent FS-13 in JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
  • 2007-10. Reprocessing of spent solvent of the UNEX process in RADIOCHEMISTRY
  • Identifiers

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    http://scigraph.springernature.com/pub.10.1007/s10967-014-3657-1

    DOI

    http://dx.doi.org/10.1007/s10967-014-3657-1

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