Separation of curium from americium using composite sorbents and complexing agent solutions View Full Text


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Article Info

DATE

2014-09-19

AUTHORS

Kamila Št’astná, Jan John, Ferdinand Šebesta, Martin Vlk

ABSTRACT

The EXAm and the AmSel liquid–liquid extraction processes have been used as bases for the development of chromatographic systems for separation of curium(III) from americium(III). The liquid organic phases were replaced by composite sorbents with PAN binding matrix and complexing agent in nitric acid solutions were employed as aqueous phases. The influence of complexing agent and nitric acid concentrations on weight distribution coefficients and separation factor and the kinetics of the actinide uptake were determined in batch experiments with trace amounts of 241Am and 244Cm. The efficiency of Cm(III) separation from Am(III) was evaluated in column experiment. More... »

PAGES

349-355

References to SciGraph publications

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  • 1979-09. Analytical separation of americium and curium using high performance liquid chromatography in JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
  • 2010-01-06. Extraction chromatographic material with HDEHP on polyacrylonitrile (PAN) in JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
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