Polyacrylonitrile based composite materials with extracting agents containing chemically bonded CMPO groups for separation of actinoids View Full Text


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Article Info

DATE

2014-09-09

AUTHORS

Jan Kameník, Ferdinand Šebesta, Jan John, Volker Böhmer, Valentyn Rudzevich, Bohumír Grüner

ABSTRACT

Composite materials made from polyacrylonitrile binding polymer and solid extracting agents with functional groups of diphenyl-carbamoylmethylphosphine oxide bonded to a platform of calix[4]arenes and cobalt bis(dicarbollide) cluster anion were tested for application in column chromatography. They exhibited high affinity for americium, plutonium, uranium, and europium ions in nitric acid solutions. However, europium distribution isotherm in 3 M HNO3 indicated low capacity and unsatisfactory employment of the functional groups. Similar material with octyl(phenyl)-N,N′-diisobutylcarbamoylmethylphosphine oxide extracting agent had both high affinity and uptake capacity. More... »

PAGES

313-319

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10967-014-3543-x

DOI

http://dx.doi.org/10.1007/s10967-014-3543-x

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