Ontology type: schema:ScholarlyArticle
2014-03
AUTHORSY. M. Kulyako, S. A. Perevalov, T. I. Trofimov, D. A. Malikov, S. E. Vinokurov, M. D. Samsonov, B. F. Myasoedov, A. M. Fedoseev, A. A. Bessonov, A. Y. Shadrin
ABSTRACTIt was established that heating to 90 °C of nitrate solutions of U, Np and Pu in the presence of hydrazine hydrate results in the formation of hydrated dioxides of these elements. On ignition under inert or reducing conditions in the temperature range of 280–800 °C hydrated uranium dioxide transmogrify into crystalline UO2. On ignition in air atmosphere UO2·nH2O turns into UO3 at 440 °C and into U3O8 at 570–800 °C. It was shown that thermolysis of the solution containing a mixture of uranium, neptunium and plutonium nitrates at 90 °C in the presence of hydrazine hydrate allows one to prepare hydrated dioxides (U, Np, Pu)O2·nH2O which on heating to ~300 °C transmogrify into crystalline product of UO2, NpO2 and PuO2 solid solution. The technique of preparation of solid solutions of U and Pu dioxides is very promising as simple and effective method of production of MOX-fuel for. More... »
PAGES1293-1298
http://scigraph.springernature.com/pub.10.1007/s10967-013-2756-8
DOIhttp://dx.doi.org/10.1007/s10967-013-2756-8
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1023854065
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Physical Chemistry (incl. Structural)",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Chemical Sciences",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "Russian Academy of Sciences",
"id": "https://www.grid.ac/institutes/grid.4886.2",
"name": [
"Vernadsky Institute of Geochemistry and Analytical Chemistry of RAS, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Kulyako",
"givenName": "Y. M.",
"type": "Person"
},
{
"affiliation": {
"alternateName": "Russian Academy of Sciences",
"id": "https://www.grid.ac/institutes/grid.4886.2",
"name": [
"Vernadsky Institute of Geochemistry and Analytical Chemistry of RAS, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Perevalov",
"givenName": "S. A.",
"id": "sg:person.016136377041.89",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016136377041.89"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Russian Academy of Sciences",
"id": "https://www.grid.ac/institutes/grid.4886.2",
"name": [
"Vernadsky Institute of Geochemistry and Analytical Chemistry of RAS, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Trofimov",
"givenName": "T. I.",
"id": "sg:person.012337060065.95",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012337060065.95"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Russian Academy of Sciences",
"id": "https://www.grid.ac/institutes/grid.4886.2",
"name": [
"Vernadsky Institute of Geochemistry and Analytical Chemistry of RAS, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Malikov",
"givenName": "D. A.",
"id": "sg:person.011464650714.23",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011464650714.23"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Russian Academy of Sciences",
"id": "https://www.grid.ac/institutes/grid.4886.2",
"name": [
"Vernadsky Institute of Geochemistry and Analytical Chemistry of RAS, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Vinokurov",
"givenName": "S. E.",
"id": "sg:person.014523414565.96",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014523414565.96"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Russian Academy of Sciences",
"id": "https://www.grid.ac/institutes/grid.4886.2",
"name": [
"Vernadsky Institute of Geochemistry and Analytical Chemistry of RAS, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Samsonov",
"givenName": "M. D.",
"id": "sg:person.013133732575.13",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013133732575.13"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Russian Academy of Sciences",
"id": "https://www.grid.ac/institutes/grid.4886.2",
"name": [
"Vernadsky Institute of Geochemistry and Analytical Chemistry of RAS, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Myasoedov",
"givenName": "B. F.",
"id": "sg:person.01207500637.58",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01207500637.58"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Frumkin Institute of Physical Chemistry and Electrochemistry",
"id": "https://www.grid.ac/institutes/grid.465278.a",
"name": [
"Frumkin Institute of Physical Chemistry and Electrochemistry of RAS, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Fedoseev",
"givenName": "A. M.",
"id": "sg:person.013016540647.93",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013016540647.93"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Frumkin Institute of Physical Chemistry and Electrochemistry",
"id": "https://www.grid.ac/institutes/grid.465278.a",
"name": [
"Frumkin Institute of Physical Chemistry and Electrochemistry of RAS, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Bessonov",
"givenName": "A. A.",
"id": "sg:person.012652727757.25",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012652727757.25"
],
"type": "Person"
},
{
"affiliation": {
"name": [
"Bochvar Institute (VNIINM), Center on Radioactive Waste and Spent Nuclear Fuel Management and Decommissioning, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Shadrin",
"givenName": "A. Y.",
"id": "sg:person.010262257175.26",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010262257175.26"
],
"type": "Person"
}
],
"citation": [
{
"id": "sg:pub.10.1023/b:aten.0000038098.44375.1a",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1006180414",
"https://doi.org/10.1023/b:aten.0000038098.44375.1a"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf01914521",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1007264671",
"https://doi.org/10.1007/bf01914521"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf01914521",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1007264671",
"https://doi.org/10.1007/bf01914521"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1134/s0036023609080087",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1020447274",
"https://doi.org/10.1134/s0036023609080087"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1134/s0036023609080087",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1020447274",
"https://doi.org/10.1134/s0036023609080087"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1023/a:1014811604126",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1021235393",
"https://doi.org/10.1023/a:1014811604126"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1134/s106636221004003x",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1030974051",
"https://doi.org/10.1134/s106636221004003x"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1524/ract.1984.36.12.75",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1067646111"
],
"type": "CreativeWork"
}
],
"datePublished": "2014-03",
"datePublishedReg": "2014-03-01",
"description": "It was established that heating to 90 \u00b0C of nitrate solutions of U, Np and Pu in the presence of hydrazine hydrate results in the formation of hydrated dioxides of these elements. On ignition under inert or reducing conditions in the temperature range of 280\u2013800 \u00b0C hydrated uranium dioxide transmogrify into crystalline UO2. On ignition in air atmosphere UO2\u00b7nH2O turns into UO3 at 440 \u00b0C and into U3O8 at 570\u2013800 \u00b0C. It was shown that thermolysis of the solution containing a mixture of uranium, neptunium and plutonium nitrates at 90 \u00b0C in the presence of hydrazine hydrate allows one to prepare hydrated dioxides (U, Np, Pu)O2\u00b7nH2O which on heating to ~300 \u00b0C transmogrify into crystalline product of UO2, NpO2 and PuO2 solid solution. The technique of preparation of solid solutions of U and Pu dioxides is very promising as simple and effective method of production of MOX-fuel for.",
"genre": "research_article",
"id": "sg:pub.10.1007/s10967-013-2756-8",
"inLanguage": [
"en"
],
"isAccessibleForFree": false,
"isFundedItemOf": [
{
"id": "sg:grant.5350809",
"type": "MonetaryGrant"
},
{
"id": "sg:grant.5341872",
"type": "MonetaryGrant"
}
],
"isPartOf": [
{
"id": "sg:journal.1094634",
"issn": [
"0236-5731",
"1588-2780"
],
"name": "Journal of Radioanalytical and Nuclear Chemistry",
"type": "Periodical"
},
{
"issueNumber": "3",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "299"
}
],
"name": "UO2, NpO2 and PuO2 preparation in aqueous nitrate solutions in the presence of hydrazine hydrate",
"pagination": "1293-1298",
"productId": [
{
"name": "readcube_id",
"type": "PropertyValue",
"value": [
"71a4e78ec335ff533f9e7b9bb73c6f92599fea4a95accaf74ebf1eba0ba5aa4c"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1007/s10967-013-2756-8"
]
},
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1023854065"
]
}
],
"sameAs": [
"https://doi.org/10.1007/s10967-013-2756-8",
"https://app.dimensions.ai/details/publication/pub.1023854065"
],
"sdDataset": "articles",
"sdDatePublished": "2019-04-11T02:01",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8700_00000512.jsonl",
"type": "ScholarlyArticle",
"url": "http://link.springer.com/10.1007%2Fs10967-013-2756-8"
}
]Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10967-013-2756-8'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10967-013-2756-8'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10967-013-2756-8'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10967-013-2756-8'
This table displays all metadata directly associated to this object as RDF triples.
155 TRIPLES
21 PREDICATES
33 URIs
19 LITERALS
7 BLANK NODES