Liquid–liquid extraction of scandium with nalidixic acid in dichloromethane View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2012-04

AUTHORS

Yasar Arafat Abbasi, Akbar Ali, Muhammad Haleem Khan, Muhammad Mufazzal Saeed, Kashif Naeem

ABSTRACT

The extraction behavior of nalidixic acid (HNA) in CH2Cl2 has been studied for various di- and trivalent metal ions such as Cu(II), Fe(II), Ni(II), Mn(II), Sb(II), Co(II), Sc(III), Y(III), Nd(III) and Eu(III) from aqueous buffer solutions of pH 1–7 with 0.1 mol dm−3 nalidixic acid in dichloromethane. Separation factors of Sc(III) from these metals has shown that its clean separation is possible at pH 3.4–4. The parameters affecting the extraction of Sc(III) were optimized. The composition of the extracted adduct was determined by slope analysis method that came out to be Sc(NA)3. Extraction of Sc(III) was studied in the presence of various cations and anions. Among the anions studied only fluoride, citrate and oxalate have significant interference whereas, Fe(III) has reduced the extraction to 53% that can be removed by using ascorbic acid as reducing agent. The proposed extraction system proved good stability up to six extraction-stripping stages for the extraction of Sc(III). More... »

PAGES

277-283

References to SciGraph publications

  • 1992-11. Carrier-mediated transport of rare earth elements through liquid membranes in JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
  • 1996-01. Liquid-liquid extraction and separation studies of yttrium in JOURNAL OF ANALYTICAL CHEMISTRY
  • 1989-03. Solvent extraction studies using tetracycline as a complexing agent in JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
  • 1997-02. Extraction and separation of scandium salicylate with triphenylphosphine oxide in JOURNAL OF ANALYTICAL CHEMISTRY
  • 2004-03. Improving the Selectivity of the Luminescence Determination of Europium(III) with the Use of a Zirconium Phosphate Solid Support in JOURNAL OF ANALYTICAL CHEMISTRY
  • 1992-03. Separation of carrier-free47Sc from titanium targets in JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
  • 1977-09. Solvent extraction of the lanthanide elements, scandium, uranium and thorium using tetracycline as complexing agent in JOURNAL OF RADIOANALYTICAL CHEMISTRY
  • 1992-06. Carrier-mediated transport of rare earth elements through liquid membranes. Transport of Sc, Y, Ce, Eu, Gd, Tm, Yb through supported liquid membrane containing TOPO in n-dodecane in JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
  • 1989-01. Selective concentration of the lanthanides with simultaneous purification from scandium in JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
  • 2003-03. Solid-phase extraction–spectrophotometric determination of uranium(VI) in natural waters in ANALYTICAL AND BIOANALYTICAL CHEMISTRY
  • 2008-10. Solid phase extraction using silica gel functionalized with Sulfasalazine for preconcentration of uranium(VI) ions from water samples in MICROCHIMICA ACTA
  • 1974-03. Selective ion-exchangers containing phosphorus in their functional groups in JOURNAL OF RADIOANALYTICAL CHEMISTRY
  • 1981-03. Use of tetracycline as complexing agent in radiochemical separations in JOURNAL OF RADIOANALYTICAL CHEMISTRY
  • 1979-09. Thermodynamics of the extraction of scandium(III) by the liquid cation exchangers dinonylnaphthalenesulfonic acid and bis(2-ethylhexyl) phosphoric acid in JOURNAL OF RADIOANALYTICAL CHEMISTRY
  • 2003-08. Solvent extraction of 46Sc with PMBP in JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
  • 1993-11. Covalency of Sc(III), Y(III), Ln(III) and An(III) as manifested in the enthalpies of solution of anhydrous rare earth halides in JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
  • 2005-09. Selective transport of copper(II) ions across a liquid membrane mediated by Piroxicam in ANALYTICAL AND BIOANALYTICAL CHEMISTRY
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s10967-011-1427-x

    DOI

    http://dx.doi.org/10.1007/s10967-011-1427-x

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1041539963


    Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
    Incoming Citations Browse incoming citations for this publication using opencitations.net

    JSON-LD is the canonical representation for SciGraph data.

    TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

    [
      {
        "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
        "about": [
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Inorganic Chemistry", 
            "type": "DefinedTerm"
          }, 
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Chemical Sciences", 
            "type": "DefinedTerm"
          }
        ], 
        "author": [
          {
            "affiliation": {
              "alternateName": "University of Azad Jammu and Kashmir", 
              "id": "https://www.grid.ac/institutes/grid.413058.b", 
              "name": [
                "Department of Chemistry, University of Azad Jammu and Kashmir, Muzaffarabad, AJK, Pakistan"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Abbasi", 
            "givenName": "Yasar Arafat", 
            "id": "sg:person.013071373755.57", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013071373755.57"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Pakistan Institute of Nuclear Science and Technology", 
              "id": "https://www.grid.ac/institutes/grid.420113.5", 
              "name": [
                "Chemistry Division, Pakistan Institute of Nuclear Science and Technology, P.O. Nilore, Islamabad, Pakistan"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Ali", 
            "givenName": "Akbar", 
            "id": "sg:person.011003550200.65", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011003550200.65"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "University of Azad Jammu and Kashmir", 
              "id": "https://www.grid.ac/institutes/grid.413058.b", 
              "name": [
                "Department of Chemistry, University of Azad Jammu and Kashmir, Muzaffarabad, AJK, Pakistan"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Khan", 
            "givenName": "Muhammad Haleem", 
            "id": "sg:person.016133171244.04", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016133171244.04"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Pakistan Institute of Nuclear Science and Technology", 
              "id": "https://www.grid.ac/institutes/grid.420113.5", 
              "name": [
                "Chemistry Division, Pakistan Institute of Nuclear Science and Technology, P.O. Nilore, Islamabad, Pakistan"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Saeed", 
            "givenName": "Muhammad Mufazzal", 
            "id": "sg:person.01011461753.78", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01011461753.78"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Pakistan Institute of Nuclear Science and Technology", 
              "id": "https://www.grid.ac/institutes/grid.420113.5", 
              "name": [
                "Central Analytical Facility Division, Pakistan Institute of Nuclear Science and Technology, P.O. Nilore, Islamabad, Pakistan"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Naeem", 
            "givenName": "Kashif", 
            "id": "sg:person.01365254312.21", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01365254312.21"
            ], 
            "type": "Person"
          }
        ], 
        "citation": [
          {
            "id": "https://doi.org/10.1016/0731-7085(94)00081-6", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1000490740"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0039-9140(88)80004-3", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1006634559"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/s0003-2670(98)00548-0", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1007396709"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02521279", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1008225075", 
              "https://doi.org/10.1007/bf02521279"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02521279", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1008225075", 
              "https://doi.org/10.1007/bf02521279"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s00216-005-3421-z", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1009150124", 
              "https://doi.org/10.1007/s00216-005-3421-z"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s00216-005-3421-z", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1009150124", 
              "https://doi.org/10.1007/s00216-005-3421-z"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.oregeorev.2003.06.002", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1011581679"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s00604-008-0020-7", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1011943617", 
              "https://doi.org/10.1007/s00604-008-0020-7"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s00604-008-0020-7", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1011943617", 
              "https://doi.org/10.1007/s00604-008-0020-7"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02165457", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1012162041", 
              "https://doi.org/10.1007/bf02165457"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02165457", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1012162041", 
              "https://doi.org/10.1007/bf02165457"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/s0039-9140(03)00171-1", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1017053691"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/s0039-9140(03)00171-1", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1017053691"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0003-2670(95)00309-n", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1018815800"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0022-1902(58)80078-0", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1023080409"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0022-1902(58)80078-0", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1023080409"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s002169600021", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1023335188", 
              "https://doi.org/10.1007/s002169600021"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1080/07366290008934724", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1023974037"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02047448", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1026706675", 
              "https://doi.org/10.1007/bf02047448"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02047448", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1026706675", 
              "https://doi.org/10.1007/bf02047448"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.chroma.2004.08.069", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1027506393"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02518344", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1030173483", 
              "https://doi.org/10.1007/bf02518344"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02518344", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1030173483", 
              "https://doi.org/10.1007/bf02518344"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02037705", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1030509796", 
              "https://doi.org/10.1007/bf02037705"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02037705", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1030509796", 
              "https://doi.org/10.1007/bf02037705"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0039-9140(79)80273-8", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1031891271"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/s0039-9140(98)00151-9", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1032005117"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s002160050189", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1032088054", 
              "https://doi.org/10.1007/s002160050189"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/s0003-2670(02)00435-x", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1036318578"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02518006", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1039433591", 
              "https://doi.org/10.1007/bf02518006"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02518006", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1039433591", 
              "https://doi.org/10.1007/bf02518006"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02040715", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1039932184", 
              "https://doi.org/10.1007/bf02040715"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02040715", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1039932184", 
              "https://doi.org/10.1007/bf02040715"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1524/ract.2010.1748", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1041073520"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1023/a:1024720921370", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1041633696", 
              "https://doi.org/10.1023/a:1024720921370"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02163384", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1042422020", 
              "https://doi.org/10.1007/bf02163384"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02163384", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1042422020", 
              "https://doi.org/10.1007/bf02163384"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02037488", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1043566639", 
              "https://doi.org/10.1007/bf02037488"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02037488", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1043566639", 
              "https://doi.org/10.1007/bf02037488"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02520860", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1043834605", 
              "https://doi.org/10.1007/bf02520860"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02520860", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1043834605", 
              "https://doi.org/10.1007/bf02520860"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/s0039-9140(96)02188-1", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1045208376"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0304-386x(90)90014-s", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1046324937"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0304-386x(90)90014-s", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1046324937"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/s0003-2670(97)00465-0", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1048548333"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s00216-003-1762-z", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1050970944", 
              "https://doi.org/10.1007/s00216-003-1762-z"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1080/01496399808544777", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1052418331"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ac60189a013", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055043711"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1023/b:janc.0000018967.31001.b5", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1056311951", 
              "https://doi.org/10.1023/b:janc.0000018967.31001.b5"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.2113/gsecongeo.82.3.757", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1068932396"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.3891/acta.chem.scand.25-0158", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1071493995"
            ], 
            "type": "CreativeWork"
          }
        ], 
        "datePublished": "2012-04", 
        "datePublishedReg": "2012-04-01", 
        "description": "The extraction behavior of nalidixic acid (HNA) in CH2Cl2 has been studied for various di- and trivalent metal ions such as Cu(II), Fe(II), Ni(II), Mn(II), Sb(II), Co(II), Sc(III), Y(III), Nd(III) and Eu(III) from aqueous buffer solutions of pH 1\u20137 with 0.1 mol dm\u22123 nalidixic acid in dichloromethane. Separation factors of Sc(III) from these metals has shown that its clean separation is possible at pH 3.4\u20134. The parameters affecting the extraction of Sc(III) were optimized. The composition of the extracted adduct was determined by slope analysis method that came out to be Sc(NA)3. Extraction of Sc(III) was studied in the presence of various cations and anions. Among the anions studied only fluoride, citrate and oxalate have significant interference whereas, Fe(III) has reduced the extraction to 53% that can be removed by using ascorbic acid as reducing agent. The proposed extraction system proved good stability up to six extraction-stripping stages for the extraction of Sc(III).", 
        "genre": "research_article", 
        "id": "sg:pub.10.1007/s10967-011-1427-x", 
        "inLanguage": [
          "en"
        ], 
        "isAccessibleForFree": false, 
        "isPartOf": [
          {
            "id": "sg:journal.1094634", 
            "issn": [
              "0236-5731", 
              "1588-2780"
            ], 
            "name": "Journal of Radioanalytical and Nuclear Chemistry", 
            "type": "Periodical"
          }, 
          {
            "issueNumber": "1", 
            "type": "PublicationIssue"
          }, 
          {
            "type": "PublicationVolume", 
            "volumeNumber": "292"
          }
        ], 
        "name": "Liquid\u2013liquid extraction of scandium with nalidixic acid in dichloromethane", 
        "pagination": "277-283", 
        "productId": [
          {
            "name": "readcube_id", 
            "type": "PropertyValue", 
            "value": [
              "c5e1de7b98e7418b74c0af81637675da5dee6f5922bdf6002ee599398807bd24"
            ]
          }, 
          {
            "name": "doi", 
            "type": "PropertyValue", 
            "value": [
              "10.1007/s10967-011-1427-x"
            ]
          }, 
          {
            "name": "dimensions_id", 
            "type": "PropertyValue", 
            "value": [
              "pub.1041539963"
            ]
          }
        ], 
        "sameAs": [
          "https://doi.org/10.1007/s10967-011-1427-x", 
          "https://app.dimensions.ai/details/publication/pub.1041539963"
        ], 
        "sdDataset": "articles", 
        "sdDatePublished": "2019-04-10T15:52", 
        "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
        "sdPublisher": {
          "name": "Springer Nature - SN SciGraph project", 
          "type": "Organization"
        }, 
        "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8664_00000515.jsonl", 
        "type": "ScholarlyArticle", 
        "url": "http://link.springer.com/10.1007%2Fs10967-011-1427-x"
      }
    ]
     

    Download the RDF metadata as:  json-ld nt turtle xml License info

    HOW TO GET THIS DATA PROGRAMMATICALLY:

    JSON-LD is a popular format for linked data which is fully compatible with JSON.

    curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10967-011-1427-x'

    N-Triples is a line-based linked data format ideal for batch operations.

    curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10967-011-1427-x'

    Turtle is a human-readable linked data format.

    curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10967-011-1427-x'

    RDF/XML is a standard XML format for linked data.

    curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10967-011-1427-x'


     

    This table displays all metadata directly associated to this object as RDF triples.

    221 TRIPLES      21 PREDICATES      64 URIs      19 LITERALS      7 BLANK NODES

    Subject Predicate Object
    1 sg:pub.10.1007/s10967-011-1427-x schema:about anzsrc-for:03
    2 anzsrc-for:0302
    3 schema:author Nbadbb0328b6c4e27b2e0c73dd65ed78a
    4 schema:citation sg:pub.10.1007/bf02037488
    5 sg:pub.10.1007/bf02037705
    6 sg:pub.10.1007/bf02040715
    7 sg:pub.10.1007/bf02047448
    8 sg:pub.10.1007/bf02163384
    9 sg:pub.10.1007/bf02165457
    10 sg:pub.10.1007/bf02518006
    11 sg:pub.10.1007/bf02518344
    12 sg:pub.10.1007/bf02520860
    13 sg:pub.10.1007/bf02521279
    14 sg:pub.10.1007/s00216-003-1762-z
    15 sg:pub.10.1007/s00216-005-3421-z
    16 sg:pub.10.1007/s002160050189
    17 sg:pub.10.1007/s002169600021
    18 sg:pub.10.1007/s00604-008-0020-7
    19 sg:pub.10.1023/a:1024720921370
    20 sg:pub.10.1023/b:janc.0000018967.31001.b5
    21 https://doi.org/10.1016/0003-2670(95)00309-n
    22 https://doi.org/10.1016/0022-1902(58)80078-0
    23 https://doi.org/10.1016/0039-9140(79)80273-8
    24 https://doi.org/10.1016/0039-9140(88)80004-3
    25 https://doi.org/10.1016/0304-386x(90)90014-s
    26 https://doi.org/10.1016/0731-7085(94)00081-6
    27 https://doi.org/10.1016/j.chroma.2004.08.069
    28 https://doi.org/10.1016/j.oregeorev.2003.06.002
    29 https://doi.org/10.1016/s0003-2670(02)00435-x
    30 https://doi.org/10.1016/s0003-2670(97)00465-0
    31 https://doi.org/10.1016/s0003-2670(98)00548-0
    32 https://doi.org/10.1016/s0039-9140(03)00171-1
    33 https://doi.org/10.1016/s0039-9140(96)02188-1
    34 https://doi.org/10.1016/s0039-9140(98)00151-9
    35 https://doi.org/10.1021/ac60189a013
    36 https://doi.org/10.1080/01496399808544777
    37 https://doi.org/10.1080/07366290008934724
    38 https://doi.org/10.1524/ract.2010.1748
    39 https://doi.org/10.2113/gsecongeo.82.3.757
    40 https://doi.org/10.3891/acta.chem.scand.25-0158
    41 schema:datePublished 2012-04
    42 schema:datePublishedReg 2012-04-01
    43 schema:description The extraction behavior of nalidixic acid (HNA) in CH2Cl2 has been studied for various di- and trivalent metal ions such as Cu(II), Fe(II), Ni(II), Mn(II), Sb(II), Co(II), Sc(III), Y(III), Nd(III) and Eu(III) from aqueous buffer solutions of pH 1–7 with 0.1 mol dm−3 nalidixic acid in dichloromethane. Separation factors of Sc(III) from these metals has shown that its clean separation is possible at pH 3.4–4. The parameters affecting the extraction of Sc(III) were optimized. The composition of the extracted adduct was determined by slope analysis method that came out to be Sc(NA)3. Extraction of Sc(III) was studied in the presence of various cations and anions. Among the anions studied only fluoride, citrate and oxalate have significant interference whereas, Fe(III) has reduced the extraction to 53% that can be removed by using ascorbic acid as reducing agent. The proposed extraction system proved good stability up to six extraction-stripping stages for the extraction of Sc(III).
    44 schema:genre research_article
    45 schema:inLanguage en
    46 schema:isAccessibleForFree false
    47 schema:isPartOf N85af6938ef034441b9076019624dad78
    48 Nc1511349414a4a9786378e4430fb3657
    49 sg:journal.1094634
    50 schema:name Liquid–liquid extraction of scandium with nalidixic acid in dichloromethane
    51 schema:pagination 277-283
    52 schema:productId N271c95e29c6742c0b6b92adc61321ef5
    53 N382b161696b74b79ad7179814bd5bb5d
    54 N3bad675391014387bee5b9b7f0504c16
    55 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041539963
    56 https://doi.org/10.1007/s10967-011-1427-x
    57 schema:sdDatePublished 2019-04-10T15:52
    58 schema:sdLicense https://scigraph.springernature.com/explorer/license/
    59 schema:sdPublisher N370bc7db39924865b9dd0495a87abf0a
    60 schema:url http://link.springer.com/10.1007%2Fs10967-011-1427-x
    61 sgo:license sg:explorer/license/
    62 sgo:sdDataset articles
    63 rdf:type schema:ScholarlyArticle
    64 N271c95e29c6742c0b6b92adc61321ef5 schema:name dimensions_id
    65 schema:value pub.1041539963
    66 rdf:type schema:PropertyValue
    67 N370bc7db39924865b9dd0495a87abf0a schema:name Springer Nature - SN SciGraph project
    68 rdf:type schema:Organization
    69 N382b161696b74b79ad7179814bd5bb5d schema:name doi
    70 schema:value 10.1007/s10967-011-1427-x
    71 rdf:type schema:PropertyValue
    72 N3bad675391014387bee5b9b7f0504c16 schema:name readcube_id
    73 schema:value c5e1de7b98e7418b74c0af81637675da5dee6f5922bdf6002ee599398807bd24
    74 rdf:type schema:PropertyValue
    75 N52b1f94c0b854827b3c56658aca553df rdf:first sg:person.01011461753.78
    76 rdf:rest Na4c5d739fc5a4fefb03c3fe020a41cf5
    77 N5ca0b41e3ff04be7afb5d596f7ddcef8 rdf:first sg:person.016133171244.04
    78 rdf:rest N52b1f94c0b854827b3c56658aca553df
    79 N85af6938ef034441b9076019624dad78 schema:volumeNumber 292
    80 rdf:type schema:PublicationVolume
    81 N88aa92da2e9b42ea8efc5abcbce63283 rdf:first sg:person.011003550200.65
    82 rdf:rest N5ca0b41e3ff04be7afb5d596f7ddcef8
    83 Na4c5d739fc5a4fefb03c3fe020a41cf5 rdf:first sg:person.01365254312.21
    84 rdf:rest rdf:nil
    85 Nbadbb0328b6c4e27b2e0c73dd65ed78a rdf:first sg:person.013071373755.57
    86 rdf:rest N88aa92da2e9b42ea8efc5abcbce63283
    87 Nc1511349414a4a9786378e4430fb3657 schema:issueNumber 1
    88 rdf:type schema:PublicationIssue
    89 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
    90 schema:name Chemical Sciences
    91 rdf:type schema:DefinedTerm
    92 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
    93 schema:name Inorganic Chemistry
    94 rdf:type schema:DefinedTerm
    95 sg:journal.1094634 schema:issn 0236-5731
    96 1588-2780
    97 schema:name Journal of Radioanalytical and Nuclear Chemistry
    98 rdf:type schema:Periodical
    99 sg:person.01011461753.78 schema:affiliation https://www.grid.ac/institutes/grid.420113.5
    100 schema:familyName Saeed
    101 schema:givenName Muhammad Mufazzal
    102 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01011461753.78
    103 rdf:type schema:Person
    104 sg:person.011003550200.65 schema:affiliation https://www.grid.ac/institutes/grid.420113.5
    105 schema:familyName Ali
    106 schema:givenName Akbar
    107 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011003550200.65
    108 rdf:type schema:Person
    109 sg:person.013071373755.57 schema:affiliation https://www.grid.ac/institutes/grid.413058.b
    110 schema:familyName Abbasi
    111 schema:givenName Yasar Arafat
    112 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013071373755.57
    113 rdf:type schema:Person
    114 sg:person.01365254312.21 schema:affiliation https://www.grid.ac/institutes/grid.420113.5
    115 schema:familyName Naeem
    116 schema:givenName Kashif
    117 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01365254312.21
    118 rdf:type schema:Person
    119 sg:person.016133171244.04 schema:affiliation https://www.grid.ac/institutes/grid.413058.b
    120 schema:familyName Khan
    121 schema:givenName Muhammad Haleem
    122 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016133171244.04
    123 rdf:type schema:Person
    124 sg:pub.10.1007/bf02037488 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043566639
    125 https://doi.org/10.1007/bf02037488
    126 rdf:type schema:CreativeWork
    127 sg:pub.10.1007/bf02037705 schema:sameAs https://app.dimensions.ai/details/publication/pub.1030509796
    128 https://doi.org/10.1007/bf02037705
    129 rdf:type schema:CreativeWork
    130 sg:pub.10.1007/bf02040715 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039932184
    131 https://doi.org/10.1007/bf02040715
    132 rdf:type schema:CreativeWork
    133 sg:pub.10.1007/bf02047448 schema:sameAs https://app.dimensions.ai/details/publication/pub.1026706675
    134 https://doi.org/10.1007/bf02047448
    135 rdf:type schema:CreativeWork
    136 sg:pub.10.1007/bf02163384 schema:sameAs https://app.dimensions.ai/details/publication/pub.1042422020
    137 https://doi.org/10.1007/bf02163384
    138 rdf:type schema:CreativeWork
    139 sg:pub.10.1007/bf02165457 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012162041
    140 https://doi.org/10.1007/bf02165457
    141 rdf:type schema:CreativeWork
    142 sg:pub.10.1007/bf02518006 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039433591
    143 https://doi.org/10.1007/bf02518006
    144 rdf:type schema:CreativeWork
    145 sg:pub.10.1007/bf02518344 schema:sameAs https://app.dimensions.ai/details/publication/pub.1030173483
    146 https://doi.org/10.1007/bf02518344
    147 rdf:type schema:CreativeWork
    148 sg:pub.10.1007/bf02520860 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043834605
    149 https://doi.org/10.1007/bf02520860
    150 rdf:type schema:CreativeWork
    151 sg:pub.10.1007/bf02521279 schema:sameAs https://app.dimensions.ai/details/publication/pub.1008225075
    152 https://doi.org/10.1007/bf02521279
    153 rdf:type schema:CreativeWork
    154 sg:pub.10.1007/s00216-003-1762-z schema:sameAs https://app.dimensions.ai/details/publication/pub.1050970944
    155 https://doi.org/10.1007/s00216-003-1762-z
    156 rdf:type schema:CreativeWork
    157 sg:pub.10.1007/s00216-005-3421-z schema:sameAs https://app.dimensions.ai/details/publication/pub.1009150124
    158 https://doi.org/10.1007/s00216-005-3421-z
    159 rdf:type schema:CreativeWork
    160 sg:pub.10.1007/s002160050189 schema:sameAs https://app.dimensions.ai/details/publication/pub.1032088054
    161 https://doi.org/10.1007/s002160050189
    162 rdf:type schema:CreativeWork
    163 sg:pub.10.1007/s002169600021 schema:sameAs https://app.dimensions.ai/details/publication/pub.1023335188
    164 https://doi.org/10.1007/s002169600021
    165 rdf:type schema:CreativeWork
    166 sg:pub.10.1007/s00604-008-0020-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011943617
    167 https://doi.org/10.1007/s00604-008-0020-7
    168 rdf:type schema:CreativeWork
    169 sg:pub.10.1023/a:1024720921370 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041633696
    170 https://doi.org/10.1023/a:1024720921370
    171 rdf:type schema:CreativeWork
    172 sg:pub.10.1023/b:janc.0000018967.31001.b5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056311951
    173 https://doi.org/10.1023/b:janc.0000018967.31001.b5
    174 rdf:type schema:CreativeWork
    175 https://doi.org/10.1016/0003-2670(95)00309-n schema:sameAs https://app.dimensions.ai/details/publication/pub.1018815800
    176 rdf:type schema:CreativeWork
    177 https://doi.org/10.1016/0022-1902(58)80078-0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1023080409
    178 rdf:type schema:CreativeWork
    179 https://doi.org/10.1016/0039-9140(79)80273-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031891271
    180 rdf:type schema:CreativeWork
    181 https://doi.org/10.1016/0039-9140(88)80004-3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006634559
    182 rdf:type schema:CreativeWork
    183 https://doi.org/10.1016/0304-386x(90)90014-s schema:sameAs https://app.dimensions.ai/details/publication/pub.1046324937
    184 rdf:type schema:CreativeWork
    185 https://doi.org/10.1016/0731-7085(94)00081-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1000490740
    186 rdf:type schema:CreativeWork
    187 https://doi.org/10.1016/j.chroma.2004.08.069 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027506393
    188 rdf:type schema:CreativeWork
    189 https://doi.org/10.1016/j.oregeorev.2003.06.002 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011581679
    190 rdf:type schema:CreativeWork
    191 https://doi.org/10.1016/s0003-2670(02)00435-x schema:sameAs https://app.dimensions.ai/details/publication/pub.1036318578
    192 rdf:type schema:CreativeWork
    193 https://doi.org/10.1016/s0003-2670(97)00465-0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1048548333
    194 rdf:type schema:CreativeWork
    195 https://doi.org/10.1016/s0003-2670(98)00548-0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1007396709
    196 rdf:type schema:CreativeWork
    197 https://doi.org/10.1016/s0039-9140(03)00171-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1017053691
    198 rdf:type schema:CreativeWork
    199 https://doi.org/10.1016/s0039-9140(96)02188-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1045208376
    200 rdf:type schema:CreativeWork
    201 https://doi.org/10.1016/s0039-9140(98)00151-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1032005117
    202 rdf:type schema:CreativeWork
    203 https://doi.org/10.1021/ac60189a013 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055043711
    204 rdf:type schema:CreativeWork
    205 https://doi.org/10.1080/01496399808544777 schema:sameAs https://app.dimensions.ai/details/publication/pub.1052418331
    206 rdf:type schema:CreativeWork
    207 https://doi.org/10.1080/07366290008934724 schema:sameAs https://app.dimensions.ai/details/publication/pub.1023974037
    208 rdf:type schema:CreativeWork
    209 https://doi.org/10.1524/ract.2010.1748 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041073520
    210 rdf:type schema:CreativeWork
    211 https://doi.org/10.2113/gsecongeo.82.3.757 schema:sameAs https://app.dimensions.ai/details/publication/pub.1068932396
    212 rdf:type schema:CreativeWork
    213 https://doi.org/10.3891/acta.chem.scand.25-0158 schema:sameAs https://app.dimensions.ai/details/publication/pub.1071493995
    214 rdf:type schema:CreativeWork
    215 https://www.grid.ac/institutes/grid.413058.b schema:alternateName University of Azad Jammu and Kashmir
    216 schema:name Department of Chemistry, University of Azad Jammu and Kashmir, Muzaffarabad, AJK, Pakistan
    217 rdf:type schema:Organization
    218 https://www.grid.ac/institutes/grid.420113.5 schema:alternateName Pakistan Institute of Nuclear Science and Technology
    219 schema:name Central Analytical Facility Division, Pakistan Institute of Nuclear Science and Technology, P.O. Nilore, Islamabad, Pakistan
    220 Chemistry Division, Pakistan Institute of Nuclear Science and Technology, P.O. Nilore, Islamabad, Pakistan
    221 rdf:type schema:Organization
     




    Preview window. Press ESC to close (or click here)


    ...