Complex formation of trivalent americium with salicylic acid at very low concentrations View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2010-10

AUTHORS

Melanie Müller, Margret Acker, Steffen Taut, Gert Bernhard

ABSTRACT

For the first time, the complexation of americium(III) with salicylic acid was studied at trace metal concentrations using a 2.0 m Long Path Flow Cell for UV–vis spectroscopy. The detection limit of Am(III) in aqueous solution at pH 3.0 was found to be 5 × 10−9 M. Two Am(III)-salicylate complexes were formed at pH 5.0 in 0.1 M NaClO4, indicated by a clear red shift of the absorption maximum. The absorption spectra obtained from spectrophotometric titration were analyzed by means of factor analysis and complex stabilities were calculated to be log β110 = 2.56 ± 0.08 and log β120 = 3.93 ± 0.19. More... »

PAGES

175-180

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10967-010-0639-9

DOI

http://dx.doi.org/10.1007/s10967-010-0639-9

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1037860428


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