Recognition of perrhenate and pertechnetate by a neutral macrocyclic receptor View Full Text


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Article Info

DATE

2009-11

AUTHORS

E. A. Katayev, G. V. Kolesnikov, V. N. Khrustalev, M. Yu. Antipin, R. K. Askerov, A. M. Maharramov, K. E. German, G. A. Kirakosyan, I. G. Tananaev, T. V. Timofeeva

ABSTRACT

The synthesis and anion binding properties of a neutral macrocyclic receptor bearing H-bond donor coordination sites are described. The anion binding studies by use of UV-vis and 99Tc NMR methods revealed that the receptor can coordinate perrhenate and pertechnetate in dimethylsulfoxide and chloroform solutions with the relatively high binding constants, viz. log Ka > 4. The coordination mode of the perrhenate to the receptor was determined by a single-crystal X-ray diffraction analysis. More... »

PAGES

385

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10967-009-0172-x

DOI

http://dx.doi.org/10.1007/s10967-009-0172-x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1052615085


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