Improvements of polypropylene grafted maleic anhydride with ultrasonication, pre-irradiation and co-irradiation methods View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2011-11

AUTHORS

Jun Qian, Zhijuan Huang, Shuaiying Dang, Yongshen Xu

ABSTRACT

This paper presented many improvements of polypropylene (PP) grafted maleic anhydride (MAH), including how to increase graft degree (G) and graft efficiency (GE) of MAH onto PP and how to reduce side reactions during grafting. Three grafting methods ultrasonication, pre-irradiation and co-irradiation were employed, and a lot of additives were adopted in our research, such as styrene (St), ethyl benzoate, dibutyl phthalate (DBP), 2,2′-bipyridine, divinylbenzene (DVB), benzoyl peroxide (BPO) and p-hydroquinone. The effects of the different grafting methods and additives were determined by G and GE values, viscosity, FTIR and DSC. Experimental results showed that the highest G value was obtained in co-irradiation method in the presence of St, and side reactions could be also reduced. The best reflux time for G value measuring, the storage time on G and batch feeding times of MAH on G in pre-irradiation method, and the mechanism of PP grafted MAH were all studied. More... »

PAGES

1557-1565

References to SciGraph publications

  • 1982. Maleic Anhydride in NONE
  • Identifiers

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    http://scigraph.springernature.com/pub.10.1007/s10965-010-9560-8

    DOI

    http://dx.doi.org/10.1007/s10965-010-9560-8

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