New Ionic Liquid Based on the CMPO Pattern for the Sequential Extraction of U(VI), Am(III) and Eu(III) View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2018-08

AUTHORS

Dariia Ternova, Ali Ouadi, Valérie Mazan, Sylvia Georg, Maria Boltoeva, Vitaly Kalchenko, Stanislas Miroshnichenko, Isabelle Billard, Clotilde Gaillard

ABSTRACT

Extraction of U(VI), Eu(III) and Am(III) has been performed from acidic aqueous solutions (HNO3, HClO4) into the ionic liquid [C4mim][Tf2N] in which a new extracting task-specific ionic liquid, based on the CMPO unit {namely 1-[3-[2-(octylphenylphosphoryl)acetamido]propyl]-3-methyl-1H-imidazol-3-ium bis(trifluoromethane)sulfonamide, hereafter noted OctPh-CMPO-IL}, was dissolved at low concentration (0.01 mol·L−1). EXAFS and UV–Vis spectroscopy measurements were performed to characterize the extracted species. The extraction of U(VI) is more efficient than the extraction of trivalent Am and Eu using this TSIL, for both acids and their concentration range. We obtained evidence that the metal ions are extracted as a solvate (UO2(OctPh-CMPO-IL)3) by a cation exchange mechanism. Nitrate or perchlorate ions do not play a direct role in the extraction by being part of the extracted complexes, but the replacement of nitric acid for perchloric acid entails a drop in the selectivity between U and Eu. However, our TSIL allows a sequential separation of U(VI) and Eu/Am(III) using the same HNO3 concentration and same nature of the organic phase, just by changing the ligand concentration. More... »

PAGES

1309-1325

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10953-018-0730-3

DOI

http://dx.doi.org/10.1007/s10953-018-0730-3

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1101554899


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263 Université de Strasbourg, IPHC, 23 rue du Loess, 67037, Strasbourg, France
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265 https://www.grid.ac/institutes/grid.450307.5 schema:alternateName Grenoble Alpes University
266 schema:name CNRS, LEPMI, 1130 rue de la Piscine, 38402, Saint Martin d’Hères, France
267 Université Grenoble Alpes, LEPMI, 38000, Grenoble, France
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269 https://www.grid.ac/institutes/grid.462474.7 schema:alternateName Institute of Nuclear physics of Lyon
270 schema:name IPNL, CNRS, Université de Lyon, UMR 5822, 69622, Villeurbanne, France
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272 https://www.grid.ac/institutes/grid.464621.3 schema:alternateName Institute of Organic Chemistry
273 schema:name CNRS, UMR7178, 67037, Strasbourg, France
274 Institute of Organic Chemistry, NASU, Kiev, Ukraine
275 Université de Strasbourg, IPHC, 23 rue du Loess, 67037, Strasbourg, France
276 rdf:type schema:Organization
 




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