Excess Molar Enthalpies for Binary and Ternary Mixtures Containing Cyclic Ethers, Lactam and Cyclic Ketones View Full Text


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Article Info

DATE

2017-08-29

AUTHORS

Sunita Malik, Heena Gupta, Dimple Sharma, Vinod Kumar Sharma

ABSTRACT

Excess molar enthalpies HE\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$ H_{{}}^{\text{E}} $$\end{document} for binary 1,3-dioxolane (1) + 1,4-dioxane (2) or N-methylpyrrolidin-2-one (2) + cyclohexanone or cycloheptanone (3) and H123E\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$ H_{123}^{\text{E}} $$\end{document} for ternary 1,3-dioxolane (1) + N-methylpyrrolidin-2-one or 1,4-dioxane (2) + cyclohexanone or cycloheptanone (3) mixtures have been measured over the entire mole fraction range at 308.15 K and atmospheric pressure using a micro differential calorimeter (Model-l DSC 7 Evo). The HE\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$ H_{{}}^{\text{E}} $$\end{document} and H123E\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$ H_{123}^{\text{E}} $$\end{document} data have been correlated with composition by fitting of the corresponding data to the Redlich–Kister equation. The topology of the constituent molecules (Graph theory) has been utilized to predict H123E\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$ H_{123}^{\text{E}} $$\end{document} values of the present mixtures. It is observed that the H123E\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$ H_{123}^{\text{E}} $$\end{document} values calculated by Graph theory compare well with their corresponding experimental values. The H123E\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$ H_{123}^{\text{E}} $$\end{document} data have also been tested in terms of the Prigogine–Flory–Patterson (PFP) theory. More... »

PAGES

1639-1657

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http://scigraph.springernature.com/pub.10.1007/s10953-017-0670-3

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http://dx.doi.org/10.1007/s10953-017-0670-3

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