Solution Thermodynamics of Ethylhexyl Triazone in Some Ethanol + Ethyl Acetate Mixtures View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2010-10

AUTHORS

Sylvia J. Rodríguez, Diana M. Cristancho, Paula C. Neita, Edgar F. Vargas, Fleming Martínez

ABSTRACT

Ethylhexyl triazone (EHT) is a sunscreen agent that is widely used in skin care product formulations, whose physicochemical properties have not been previously studied in detail. For this reason, solubility data were measured for EHT in ethanol (EtOH) + ethyl acetate (AcOEt) mixtures at five temperatures. By using the van’t Hoff and Gibbs equations, the thermodynamic functions: Gibbs energy, enthalpy, and entropy of solution, and of mixing, were evaluated from these solubilities. The solubility is greatest in mixtures with 0.10 and 0.20 mass fraction EtOH, but decrease as the EtOH mass fraction increases in the solvent mixtures. By means of an enthalpy-entropy compensation analysis, a nonlinear versus compensation plot was obtained having both negative and positive slopes as the solvent composition was varied. Accordingly to these results, it follows that the driving function for solubility of EHT is the entropy for solutions rich in EtOH or AcOEt, whereas in mixtures of medium composition, the driving function is the enthalpy. More... »

PAGES

1122-1133

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10953-010-9575-0

DOI

http://dx.doi.org/10.1007/s10953-010-9575-0

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1025386288


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