The Synthesis of New Triazole Ligands and Determination of Complex Stability Constants with Transition Metal Cations in Aqueous Media View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2008-09-13

AUTHORS

Miraç Ocak, Nurhan Gümrükçüoğlu, Ümmühan Ocak, Hans-Jurgen Buschmann, Eckard Schollmeyer

ABSTRACT

Six new triazole compounds were synthesized. These compounds containing the substituted benzylidenamino group were obtained by reaction of 3-(pyridine-4-yl)-5-p-tolyl-4-amino-4H-l,2,4-triazole 1 with the corresponding aldehyde. The reduced forms were prepared with NaBH4 in methanol. The structures of the compounds were determined by IR, 1H NMR, and 13C NMR spectral data, and their interaction with cations such as Li+, Na+, K+, Rb+, Cs+, Ba2+, Sr2+, Ca2+, Cu2+, Cr3+, Co2+, Ni2+, Zn2+, Cd2+, Pb2+ and Ag+ were investigated by using UV-visible spectrophotometry. Of the tested metal cations, Cu2+, Cr3+, Co2+, Ni2+, Zn2+, Cd2+, Pb2+ and Ag+ complexed with the ligands. The complex stability constants (log 10K) were measured in slightly acidic aqueous media at 25.0±0.1 °C. These stability constants were determined by measuring the increase in solubility of the nearly insoluble ligand molecule due to complex formation with a soluble cation, and this method is discussed. It was found that the position of chlorine atoms on the benzene ring strongly affects the complexation of Cu2+ ion with these ligands. More... »

PAGES

1489-1497

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10953-008-9331-x

DOI

http://dx.doi.org/10.1007/s10953-008-9331-x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1053367102


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Inorganic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Department of Chemistry, Faculty of Arts and Sciences, KT\u00dc, Trabzon, Turkey", 
          "id": "http://www.grid.ac/institutes/grid.31564.35", 
          "name": [
            "Department of Chemistry, Faculty of Arts and Sciences, KT\u00dc, Trabzon, Turkey"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ocak", 
        "givenName": "Mira\u00e7", 
        "id": "sg:person.01350027204.20", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01350027204.20"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Chemistry, Faculty of Arts and Sciences, Giresun University, Giresun, Turkey", 
          "id": "http://www.grid.ac/institutes/grid.411709.a", 
          "name": [
            "Department of Chemistry, Faculty of Arts and Sciences, Giresun University, Giresun, Turkey"
          ], 
          "type": "Organization"
        }, 
        "familyName": "G\u00fcmr\u00fck\u00e7\u00fco\u011flu", 
        "givenName": "Nurhan", 
        "id": "sg:person.0753475044.95", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0753475044.95"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Chemistry, Faculty of Arts and Sciences, KT\u00dc, Trabzon, Turkey", 
          "id": "http://www.grid.ac/institutes/grid.31564.35", 
          "name": [
            "Department of Chemistry, Faculty of Arts and Sciences, KT\u00dc, Trabzon, Turkey"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ocak", 
        "givenName": "\u00dcmm\u00fchan", 
        "id": "sg:person.013554471525.88", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013554471525.88"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Deutsches Textilforschungszentrum Nord-West e.V., Adlerstrasse 1, 47798, Krefeld, Germany", 
          "id": "http://www.grid.ac/institutes/grid.472759.a", 
          "name": [
            "Deutsches Textilforschungszentrum Nord-West e.V., Adlerstrasse 1, 47798, Krefeld, Germany"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Buschmann", 
        "givenName": "Hans-Jurgen", 
        "id": "sg:person.016164770762.25", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016164770762.25"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Deutsches Textilforschungszentrum Nord-West e.V., Adlerstrasse 1, 47798, Krefeld, Germany", 
          "id": "http://www.grid.ac/institutes/grid.472759.a", 
          "name": [
            "Deutsches Textilforschungszentrum Nord-West e.V., Adlerstrasse 1, 47798, Krefeld, Germany"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Schollmeyer", 
        "givenName": "Eckard", 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1023/a:1011159119554", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1030813211", 
          "https://doi.org/10.1023/a:1011159119554"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2008-09-13", 
    "datePublishedReg": "2008-09-13", 
    "description": "Six new triazole compounds were synthesized. These compounds containing the substituted benzylidenamino group were obtained by reaction of 3-(pyridine-4-yl)-5-p-tolyl-4-amino-4H-l,2,4-triazole 1 with the corresponding aldehyde. The reduced forms were prepared with NaBH4 in methanol. The structures of the compounds were determined by IR, 1H NMR, and 13C NMR spectral data, and their interaction with cations such as Li+, Na+, K+, Rb+, Cs+, Ba2+, Sr2+, Ca2+, Cu2+, Cr3+, Co2+, Ni2+, Zn2+, Cd2+, Pb2+ and Ag+ were investigated by using UV-visible spectrophotometry. Of the tested metal cations, Cu2+, Cr3+, Co2+, Ni2+, Zn2+, Cd2+, Pb2+ and Ag+ complexed with the ligands. The complex stability constants (log\u200910K) were measured in slightly acidic aqueous media at 25.0\u00b10.1\u2009\u00b0C. These stability constants were determined by measuring the increase in solubility of the nearly insoluble ligand molecule due to complex formation with a soluble cation, and this method is discussed. It was found that the position of chlorine atoms on the benzene ring strongly affects the complexation of Cu2+ ion with these ligands.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/s10953-008-9331-x", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1015946", 
        "issn": [
          "0095-9782", 
          "1572-8927"
        ], 
        "name": "Journal of Solution Chemistry", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "11", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "37"
      }
    ], 
    "keywords": [
      "complex stability constants", 
      "stability constants", 
      "metal cations", 
      "aqueous media", 
      "New Triazole Ligands", 
      "UV-visible spectrophotometry", 
      "transition metal cations", 
      "acidic aqueous media", 
      "complexation of Cu2", 
      "NMR spectral data", 
      "new triazole compounds", 
      "triazole ligands", 
      "ligand molecules", 
      "corresponding aldehydes", 
      "chlorine atoms", 
      "triazole compounds", 
      "cations", 
      "Cu2", 
      "benzene ring", 
      "spectral data", 
      "reduced forms", 
      "ligands", 
      "complex formation", 
      "compounds", 
      "Pb2", 
      "Ni2", 
      "Zn2", 
      "Cr3", 
      "Cd2", 
      "soluble cations", 
      "constants", 
      "CO2", 
      "NaBH4", 
      "complexation", 
      "NMR", 
      "IR", 
      "aldehydes", 
      "ions", 
      "methanol", 
      "solubility", 
      "synthesis", 
      "atoms", 
      "molecules", 
      "Sr2", 
      "spectrophotometry", 
      "reaction", 
      "Ba2", 
      "ring", 
      "determination", 
      "formation", 
      "structure", 
      "medium", 
      "interaction", 
      "method", 
      "form", 
      "group", 
      "position", 
      "Ca2", 
      "increase", 
      "data", 
      "substituted benzylidenamino group", 
      "benzylidenamino group", 
      "tolyl-4-amino-4H", 
      "insoluble ligand molecule"
    ], 
    "name": "The Synthesis of New Triazole Ligands and Determination of Complex Stability Constants with Transition Metal Cations in Aqueous Media", 
    "pagination": "1489-1497", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1053367102"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s10953-008-9331-x"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s10953-008-9331-x", 
      "https://app.dimensions.ai/details/publication/pub.1053367102"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2021-12-01T19:20", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20211201/entities/gbq_results/article/article_468.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/s10953-008-9331-x"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10953-008-9331-x'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10953-008-9331-x'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10953-008-9331-x'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10953-008-9331-x'


 

This table displays all metadata directly associated to this object as RDF triples.

163 TRIPLES      22 PREDICATES      91 URIs      81 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s10953-008-9331-x schema:about anzsrc-for:03
2 anzsrc-for:0302
3 anzsrc-for:0306
4 schema:author N1fd0e97f4655467a971d278cd64226a2
5 schema:citation sg:pub.10.1023/a:1011159119554
6 schema:datePublished 2008-09-13
7 schema:datePublishedReg 2008-09-13
8 schema:description Six new triazole compounds were synthesized. These compounds containing the substituted benzylidenamino group were obtained by reaction of 3-(pyridine-4-yl)-5-p-tolyl-4-amino-4H-l,2,4-triazole 1 with the corresponding aldehyde. The reduced forms were prepared with NaBH4 in methanol. The structures of the compounds were determined by IR, 1H NMR, and 13C NMR spectral data, and their interaction with cations such as Li+, Na+, K+, Rb+, Cs+, Ba2+, Sr2+, Ca2+, Cu2+, Cr3+, Co2+, Ni2+, Zn2+, Cd2+, Pb2+ and Ag+ were investigated by using UV-visible spectrophotometry. Of the tested metal cations, Cu2+, Cr3+, Co2+, Ni2+, Zn2+, Cd2+, Pb2+ and Ag+ complexed with the ligands. The complex stability constants (log 10K) were measured in slightly acidic aqueous media at 25.0±0.1 °C. These stability constants were determined by measuring the increase in solubility of the nearly insoluble ligand molecule due to complex formation with a soluble cation, and this method is discussed. It was found that the position of chlorine atoms on the benzene ring strongly affects the complexation of Cu2+ ion with these ligands.
9 schema:genre article
10 schema:inLanguage en
11 schema:isAccessibleForFree false
12 schema:isPartOf N86b74b31f0984085885b4631f3a7dd74
13 Nf6fa708250c744f29dcbee0b26fccc83
14 sg:journal.1015946
15 schema:keywords Ba2
16 CO2
17 Ca2
18 Cd2
19 Cr3
20 Cu2
21 IR
22 NMR
23 NMR spectral data
24 NaBH4
25 New Triazole Ligands
26 Ni2
27 Pb2
28 Sr2
29 UV-visible spectrophotometry
30 Zn2
31 acidic aqueous media
32 aldehydes
33 aqueous media
34 atoms
35 benzene ring
36 benzylidenamino group
37 cations
38 chlorine atoms
39 complex formation
40 complex stability constants
41 complexation
42 complexation of Cu2
43 compounds
44 constants
45 corresponding aldehydes
46 data
47 determination
48 form
49 formation
50 group
51 increase
52 insoluble ligand molecule
53 interaction
54 ions
55 ligand molecules
56 ligands
57 medium
58 metal cations
59 methanol
60 method
61 molecules
62 new triazole compounds
63 position
64 reaction
65 reduced forms
66 ring
67 solubility
68 soluble cations
69 spectral data
70 spectrophotometry
71 stability constants
72 structure
73 substituted benzylidenamino group
74 synthesis
75 tolyl-4-amino-4H
76 transition metal cations
77 triazole compounds
78 triazole ligands
79 schema:name The Synthesis of New Triazole Ligands and Determination of Complex Stability Constants with Transition Metal Cations in Aqueous Media
80 schema:pagination 1489-1497
81 schema:productId Nd00f9cb8ba1a43d8ad38492029ecc9a0
82 Ne20368a53e9e4ff090683bc029e64567
83 schema:sameAs https://app.dimensions.ai/details/publication/pub.1053367102
84 https://doi.org/10.1007/s10953-008-9331-x
85 schema:sdDatePublished 2021-12-01T19:20
86 schema:sdLicense https://scigraph.springernature.com/explorer/license/
87 schema:sdPublisher Nd1c8c5b782014a6a80265049b3798969
88 schema:url https://doi.org/10.1007/s10953-008-9331-x
89 sgo:license sg:explorer/license/
90 sgo:sdDataset articles
91 rdf:type schema:ScholarlyArticle
92 N1fd0e97f4655467a971d278cd64226a2 rdf:first sg:person.01350027204.20
93 rdf:rest Ncbc39c576890484aa461ee9606d7ba23
94 N3212d0e2987645c28fa328520c6267d4 rdf:first sg:person.013554471525.88
95 rdf:rest Ne20257fcd0b94c319ae51b036d04ba37
96 N86b74b31f0984085885b4631f3a7dd74 schema:volumeNumber 37
97 rdf:type schema:PublicationVolume
98 Ncbc39c576890484aa461ee9606d7ba23 rdf:first sg:person.0753475044.95
99 rdf:rest N3212d0e2987645c28fa328520c6267d4
100 Nd00f9cb8ba1a43d8ad38492029ecc9a0 schema:name doi
101 schema:value 10.1007/s10953-008-9331-x
102 rdf:type schema:PropertyValue
103 Nd1c8c5b782014a6a80265049b3798969 schema:name Springer Nature - SN SciGraph project
104 rdf:type schema:Organization
105 Ndf56a5cd18754e2fb319f2906555ac31 schema:affiliation grid-institutes:grid.472759.a
106 schema:familyName Schollmeyer
107 schema:givenName Eckard
108 rdf:type schema:Person
109 Ne20257fcd0b94c319ae51b036d04ba37 rdf:first sg:person.016164770762.25
110 rdf:rest Nee50e2f7a31a4e939d8543d88331d69d
111 Ne20368a53e9e4ff090683bc029e64567 schema:name dimensions_id
112 schema:value pub.1053367102
113 rdf:type schema:PropertyValue
114 Nee50e2f7a31a4e939d8543d88331d69d rdf:first Ndf56a5cd18754e2fb319f2906555ac31
115 rdf:rest rdf:nil
116 Nf6fa708250c744f29dcbee0b26fccc83 schema:issueNumber 11
117 rdf:type schema:PublicationIssue
118 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
119 schema:name Chemical Sciences
120 rdf:type schema:DefinedTerm
121 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
122 schema:name Inorganic Chemistry
123 rdf:type schema:DefinedTerm
124 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
125 schema:name Physical Chemistry (incl. Structural)
126 rdf:type schema:DefinedTerm
127 sg:journal.1015946 schema:issn 0095-9782
128 1572-8927
129 schema:name Journal of Solution Chemistry
130 schema:publisher Springer Nature
131 rdf:type schema:Periodical
132 sg:person.01350027204.20 schema:affiliation grid-institutes:grid.31564.35
133 schema:familyName Ocak
134 schema:givenName Miraç
135 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01350027204.20
136 rdf:type schema:Person
137 sg:person.013554471525.88 schema:affiliation grid-institutes:grid.31564.35
138 schema:familyName Ocak
139 schema:givenName Ümmühan
140 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013554471525.88
141 rdf:type schema:Person
142 sg:person.016164770762.25 schema:affiliation grid-institutes:grid.472759.a
143 schema:familyName Buschmann
144 schema:givenName Hans-Jurgen
145 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016164770762.25
146 rdf:type schema:Person
147 sg:person.0753475044.95 schema:affiliation grid-institutes:grid.411709.a
148 schema:familyName Gümrükçüoğlu
149 schema:givenName Nurhan
150 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0753475044.95
151 rdf:type schema:Person
152 sg:pub.10.1023/a:1011159119554 schema:sameAs https://app.dimensions.ai/details/publication/pub.1030813211
153 https://doi.org/10.1023/a:1011159119554
154 rdf:type schema:CreativeWork
155 grid-institutes:grid.31564.35 schema:alternateName Department of Chemistry, Faculty of Arts and Sciences, KTÜ, Trabzon, Turkey
156 schema:name Department of Chemistry, Faculty of Arts and Sciences, KTÜ, Trabzon, Turkey
157 rdf:type schema:Organization
158 grid-institutes:grid.411709.a schema:alternateName Department of Chemistry, Faculty of Arts and Sciences, Giresun University, Giresun, Turkey
159 schema:name Department of Chemistry, Faculty of Arts and Sciences, Giresun University, Giresun, Turkey
160 rdf:type schema:Organization
161 grid-institutes:grid.472759.a schema:alternateName Deutsches Textilforschungszentrum Nord-West e.V., Adlerstrasse 1, 47798, Krefeld, Germany
162 schema:name Deutsches Textilforschungszentrum Nord-West e.V., Adlerstrasse 1, 47798, Krefeld, Germany
163 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...