Crystal And Molecular Structure of Zinc DI-(4-Chlorphenylthioacetate) Dihydrate View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2010-08

AUTHORS

M. G. Voronkov, V. S. Fundamenskii, É. A. Zelbst, A. A. Kashaev, A. N. Mirskova, S. N. Adamovich

ABSTRACT

Zinc di-(4-chlorphenylthioacetate) dihydrate (4-ClC6H4SCH2COO)2Zn·2H2O (ZTD) is obtained in the reaction of protatrane 4-chlorphenylthioacetate 4-ClC6H4SCH2COOs-2·N+H(CH2CH2OH)3 with zinc dichloride (ZnCl2) in aqueous alcohol. X-ray diffraction is used to study the crystal structure of ZTD and compare it with related compounds. All intermolecular O…O contacts of the neighboring zinc polyhedra are short in ZTD molecules. Apparently, the short intermolecular O…O contacts cause distortions of the octahedral environment of the zinc atom. More... »

PAGES

790-792

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10947-010-0119-7

DOI

http://dx.doi.org/10.1007/s10947-010-0119-7

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1043064100


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