Organic radicals in natural apatites according to EPR data: Potential genetic and paleoclimatic indicators View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2010-06

AUTHORS

L. G. Gilinskaya

ABSTRACT

In a group of natural marine apatites Ca5(PO4)3(F, OH), organic ĊH3, ĊH2—R, HOĊHR, (CH3)2—ĊR, and —Ċorg radicals are identified by EPR. The relation between the EPR spectra of the observed organic radicals, the valence form, and the structural location of impurity vanadium ions (V4+ (VO2+) on the Ca2+ II site or V5+ (VO4)3- → (PO4)3-) is established. The structure of organic radicals correlates with the type of organic matter in the sample under analysis: sapropelic or humic, depending on the climatic conditions of mineral genesis. More... »

PAGES

471-481

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10947-010-0069-0

DOI

http://dx.doi.org/10.1007/s10947-010-0069-0

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1017015650


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0305", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Organic Chemistry", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Institute of Geology and Mineralogy, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia", 
          "id": "http://www.grid.ac/institutes/grid.415877.8", 
          "name": [
            "Institute of Geology and Mineralogy, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Gilinskaya", 
        "givenName": "L. G.", 
        "id": "sg:person.07416050056.87", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07416050056.87"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1023/b:jory.0000029819.16581.8a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1010757020", 
          "https://doi.org/10.1023/b:jory.0000029819.16581.8a"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00745608", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1040833954", 
          "https://doi.org/10.1007/bf00745608"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/978-1-4757-9012-2_7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1025073271", 
          "https://doi.org/10.1007/978-1-4757-9012-2_7"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/978-1-4757-9012-2_8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1037698005", 
          "https://doi.org/10.1007/978-1-4757-9012-2_8"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10789-005-0158-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1030094871", 
          "https://doi.org/10.1007/s10789-005-0158-1"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1023/b:jory.0000017938.42883.9f", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1000923909", 
          "https://doi.org/10.1023/b:jory.0000017938.42883.9f"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02903540", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1051474947", 
          "https://doi.org/10.1007/bf02903540"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/332526a0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1000870766", 
          "https://doi.org/10.1038/332526a0"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1023/b:jory.0000034811.28903.9b", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1037860654", 
          "https://doi.org/10.1023/b:jory.0000034811.28903.9b"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2010-06", 
    "datePublishedReg": "2010-06-01", 
    "description": "In a group of natural marine apatites Ca5(PO4)3(F, OH), organic \u010aH3, \u010aH2\u2014R, HO\u010aHR, (CH3)2\u2014\u010aR, and \u2014\u010aorg radicals are identified by EPR. The relation between the EPR spectra of the observed organic radicals, the valence form, and the structural location of impurity vanadium ions (V4+ (VO2+) on the Ca2+ II site or V5+ (VO4)3- \u2192 (PO4)3-) is established. The structure of organic radicals correlates with the type of organic matter in the sample under analysis: sapropelic or humic, depending on the climatic conditions of mineral genesis.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/s10947-010-0069-0", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1135923", 
        "issn": [
          "0022-4766", 
          "1573-8779"
        ], 
        "name": "Journal of Structural Chemistry", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "3", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "51"
      }
    ], 
    "keywords": [
      "organic radicals", 
      "vanadium ions", 
      "EPR spectra", 
      "valence forms", 
      "EPR data", 
      "natural apatite", 
      "radicals", 
      "organic matter", 
      "marine apatites", 
      "mineral genesis", 
      "EPR", 
      "\u010aH3", 
      "ions", 
      "apatite", 
      "spectra", 
      "\u010aH2", 
      "structure", 
      "paleoclimatic indicators", 
      "structural location", 
      "samples", 
      "climatic conditions", 
      "sapropelic", 
      "conditions", 
      "form", 
      "group", 
      "matter", 
      "analysis", 
      "types", 
      "genesis", 
      "location", 
      "data", 
      "indicators", 
      "relation", 
      "correlates"
    ], 
    "name": "Organic radicals in natural apatites according to EPR data: Potential genetic and paleoclimatic indicators", 
    "pagination": "471-481", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1017015650"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s10947-010-0069-0"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s10947-010-0069-0", 
      "https://app.dimensions.ai/details/publication/pub.1017015650"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-11-24T20:55", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20221124/entities/gbq_results/article/article_514.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/s10947-010-0069-0"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10947-010-0069-0'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10947-010-0069-0'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10947-010-0069-0'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10947-010-0069-0'


 

This table displays all metadata directly associated to this object as RDF triples.

127 TRIPLES      21 PREDICATES      68 URIs      51 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s10947-010-0069-0 schema:about anzsrc-for:03
2 anzsrc-for:0305
3 schema:author N4b221f42163147b5b9fc9bc06d2e7389
4 schema:citation sg:pub.10.1007/978-1-4757-9012-2_7
5 sg:pub.10.1007/978-1-4757-9012-2_8
6 sg:pub.10.1007/bf00745608
7 sg:pub.10.1007/bf02903540
8 sg:pub.10.1007/s10789-005-0158-1
9 sg:pub.10.1023/b:jory.0000017938.42883.9f
10 sg:pub.10.1023/b:jory.0000029819.16581.8a
11 sg:pub.10.1023/b:jory.0000034811.28903.9b
12 sg:pub.10.1038/332526a0
13 schema:datePublished 2010-06
14 schema:datePublishedReg 2010-06-01
15 schema:description In a group of natural marine apatites Ca5(PO4)3(F, OH), organic ĊH3, ĊH2—R, HOĊHR, (CH3)2—ĊR, and —Ċorg radicals are identified by EPR. The relation between the EPR spectra of the observed organic radicals, the valence form, and the structural location of impurity vanadium ions (V4+ (VO2+) on the Ca2+ II site or V5+ (VO4)3- → (PO4)3-) is established. The structure of organic radicals correlates with the type of organic matter in the sample under analysis: sapropelic or humic, depending on the climatic conditions of mineral genesis.
16 schema:genre article
17 schema:isAccessibleForFree false
18 schema:isPartOf N0d63a3be6716497fbf6625bd4c1f0459
19 Nb34c480f92794b92b16f68772cdf9bc7
20 sg:journal.1135923
21 schema:keywords EPR
22 EPR data
23 EPR spectra
24 analysis
25 apatite
26 climatic conditions
27 conditions
28 correlates
29 data
30 form
31 genesis
32 group
33 indicators
34 ions
35 location
36 marine apatites
37 matter
38 mineral genesis
39 natural apatite
40 organic matter
41 organic radicals
42 paleoclimatic indicators
43 radicals
44 relation
45 samples
46 sapropelic
47 spectra
48 structural location
49 structure
50 types
51 valence forms
52 vanadium ions
53 ĊH2
54 ĊH3
55 schema:name Organic radicals in natural apatites according to EPR data: Potential genetic and paleoclimatic indicators
56 schema:pagination 471-481
57 schema:productId N0770a3353bbc4190af9ada0a96219ed4
58 Nfd4dbc787acd44eab5c0af745bacc973
59 schema:sameAs https://app.dimensions.ai/details/publication/pub.1017015650
60 https://doi.org/10.1007/s10947-010-0069-0
61 schema:sdDatePublished 2022-11-24T20:55
62 schema:sdLicense https://scigraph.springernature.com/explorer/license/
63 schema:sdPublisher N6c3ab3964a4a465985bf0f5dbe9c5e5a
64 schema:url https://doi.org/10.1007/s10947-010-0069-0
65 sgo:license sg:explorer/license/
66 sgo:sdDataset articles
67 rdf:type schema:ScholarlyArticle
68 N0770a3353bbc4190af9ada0a96219ed4 schema:name doi
69 schema:value 10.1007/s10947-010-0069-0
70 rdf:type schema:PropertyValue
71 N0d63a3be6716497fbf6625bd4c1f0459 schema:volumeNumber 51
72 rdf:type schema:PublicationVolume
73 N4b221f42163147b5b9fc9bc06d2e7389 rdf:first sg:person.07416050056.87
74 rdf:rest rdf:nil
75 N6c3ab3964a4a465985bf0f5dbe9c5e5a schema:name Springer Nature - SN SciGraph project
76 rdf:type schema:Organization
77 Nb34c480f92794b92b16f68772cdf9bc7 schema:issueNumber 3
78 rdf:type schema:PublicationIssue
79 Nfd4dbc787acd44eab5c0af745bacc973 schema:name dimensions_id
80 schema:value pub.1017015650
81 rdf:type schema:PropertyValue
82 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
83 schema:name Chemical Sciences
84 rdf:type schema:DefinedTerm
85 anzsrc-for:0305 schema:inDefinedTermSet anzsrc-for:
86 schema:name Organic Chemistry
87 rdf:type schema:DefinedTerm
88 sg:journal.1135923 schema:issn 0022-4766
89 1573-8779
90 schema:name Journal of Structural Chemistry
91 schema:publisher Springer Nature
92 rdf:type schema:Periodical
93 sg:person.07416050056.87 schema:affiliation grid-institutes:grid.415877.8
94 schema:familyName Gilinskaya
95 schema:givenName L. G.
96 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07416050056.87
97 rdf:type schema:Person
98 sg:pub.10.1007/978-1-4757-9012-2_7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1025073271
99 https://doi.org/10.1007/978-1-4757-9012-2_7
100 rdf:type schema:CreativeWork
101 sg:pub.10.1007/978-1-4757-9012-2_8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1037698005
102 https://doi.org/10.1007/978-1-4757-9012-2_8
103 rdf:type schema:CreativeWork
104 sg:pub.10.1007/bf00745608 schema:sameAs https://app.dimensions.ai/details/publication/pub.1040833954
105 https://doi.org/10.1007/bf00745608
106 rdf:type schema:CreativeWork
107 sg:pub.10.1007/bf02903540 schema:sameAs https://app.dimensions.ai/details/publication/pub.1051474947
108 https://doi.org/10.1007/bf02903540
109 rdf:type schema:CreativeWork
110 sg:pub.10.1007/s10789-005-0158-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1030094871
111 https://doi.org/10.1007/s10789-005-0158-1
112 rdf:type schema:CreativeWork
113 sg:pub.10.1023/b:jory.0000017938.42883.9f schema:sameAs https://app.dimensions.ai/details/publication/pub.1000923909
114 https://doi.org/10.1023/b:jory.0000017938.42883.9f
115 rdf:type schema:CreativeWork
116 sg:pub.10.1023/b:jory.0000029819.16581.8a schema:sameAs https://app.dimensions.ai/details/publication/pub.1010757020
117 https://doi.org/10.1023/b:jory.0000029819.16581.8a
118 rdf:type schema:CreativeWork
119 sg:pub.10.1023/b:jory.0000034811.28903.9b schema:sameAs https://app.dimensions.ai/details/publication/pub.1037860654
120 https://doi.org/10.1023/b:jory.0000034811.28903.9b
121 rdf:type schema:CreativeWork
122 sg:pub.10.1038/332526a0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1000870766
123 https://doi.org/10.1038/332526a0
124 rdf:type schema:CreativeWork
125 grid-institutes:grid.415877.8 schema:alternateName Institute of Geology and Mineralogy, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia
126 schema:name Institute of Geology and Mineralogy, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia
127 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...