Crystaland molecular structure of 4,4′-bipyridinium bis(trans-2-hydroxycinnamate) bis(4,4′-bipyridine) View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2009-12

AUTHORS

Y. Y. Zhang, Y. Gio, H. X. Chen, W. J. Xu, Z. M. Jin

ABSTRACT

4,4′-Bipyridinium bis(trans-2-hydroxycinnamate) bis(4,4′-bipyridine), 0.5(C10H10N2)2+ (C9H7O3)−·C10H8N2, crystallizes in triclinic system, space group P-1, with a = 7.4211(8) Åb = 9.9516(11) Å, c = 13.8587(15)Å, β = 92.510(2)°, α = 96.772(2)°, γ = 99.164(2)°, V = 1001.33(19) Å3, ρcalc = 1.321 g/cm3, Z = 2. In the crystal, the whole trans-2-hydroxycinnamate is disordered over two sites with different occupancies. The molecular species are linked by O-H⋯N and N-H⋯O hydrogen bonds into five-molecule hydrogen bonded chain associates that are further linked by C-H⋯O hydrogen bonds into layers with the major orientation of the disordered 2-hydroxycinnamate. However such hydrogen bonds are not observed with the minor orientation. More... »

PAGES

1208-1211

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10947-009-0181-1

DOI

http://dx.doi.org/10.1007/s10947-009-0181-1

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1028709942


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