Unusual molecular structure of (C=O→Si←O′=C′) bis(2-methyl-4-pyrone-3-oxy)difluoro(λ6)siliconium View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2009-12

AUTHORS

M. G. Voronkov, A. A. Korlyukov, È. A. Zel’bst, E. A. Grebneva, O. M. Trofimova, M. Yu. Antipin

ABSTRACT

X-ray diffraction is used to determine the crystal and molecular structure of spirocyclic (C=O→Si←O′=C′) bis(2-methyl-4-pyrone-3-oxy)difluoro(λ6)siliconium containing a hypervalent silicon atom and the previously unknown F2SiO4 coordination center. The coordination polyhedron of the silicon atom is a slightly distorted octahedron.

PAGES

1204-1207

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10947-009-0180-2

DOI

http://dx.doi.org/10.1007/s10947-009-0180-2

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1041216866


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