Synthesis, structure and magnetic properties of the pentanuclear complex [Fe2(CN)12Ni3(L)6]·27H2O, where L is nitronyl nitroxide View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2009-12

AUTHORS

H. Higashikawa, K. Inoue, K. Yu. Maryunina, G. V. Romanenko, A. S. Bogomyakov, O. V. Kuznetsova, E. Yu. Fursova, V. I. Ovcharenko

ABSTRACT

We succeeded in synthesizing a new high-spin complex [Fe2(CN)12Ni3(L)6]·27H2O, where L is stable nitroxide 2-(imidazol-4-yl)-4,4,5,5-tetramethyl-2-imidazoline-3-oxide-1-oxyl. According to X-ray diffraction data, the metal core of the pentanuclear [Fe2(CN)12Ni3(L)6] molecule is a trigonal bipyramid with Fe atoms occupying the axial positions and linked via CN bridges to {NiL2} fragments laying in the equatorial plane. A peculiarity of this coordination compound is a large number of water molecules per the [Fe2(CN)12Ni3(L)6] pentanuclear molecule in the structure. The complex character of the μeff(T) dependence points to many competing channels of exchange interactions between the three types of paramagnetic centers. More... »

PAGES

1155-1158

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10947-009-0169-x

DOI

http://dx.doi.org/10.1007/s10947-009-0169-x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1026850540


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Department of Chemistry, Faculty of Science, Hiroshima University, 1-3-1 Kagamiyama, 739-8526, Higashi-hiroshima, Hiroshima, Japan", 
          "id": "http://www.grid.ac/institutes/grid.257022.0", 
          "name": [
            "Department of Chemistry, Faculty of Science, Hiroshima University, 1-3-1 Kagamiyama, 739-8526, Higashi-hiroshima, Hiroshima, Japan"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Higashikawa", 
        "givenName": "H.", 
        "id": "sg:person.010320537205.82", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010320537205.82"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Chemistry, Faculty of Science, Hiroshima University, 1-3-1 Kagamiyama, 739-8526, Higashi-hiroshima, Hiroshima, Japan", 
          "id": "http://www.grid.ac/institutes/grid.257022.0", 
          "name": [
            "Department of Chemistry, Faculty of Science, Hiroshima University, 1-3-1 Kagamiyama, 739-8526, Higashi-hiroshima, Hiroshima, Japan"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Inoue", 
        "givenName": "K.", 
        "id": "sg:person.015042513561.53", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015042513561.53"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "International Tomography Center, Russian Academy of Sciences, Novosibirsk, Russia", 
          "id": "http://www.grid.ac/institutes/grid.415877.8", 
          "name": [
            "International Tomography Center, Russian Academy of Sciences, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Maryunina", 
        "givenName": "K. Yu.", 
        "id": "sg:person.015020535341.47", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015020535341.47"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "International Tomography Center, Russian Academy of Sciences, Novosibirsk, Russia", 
          "id": "http://www.grid.ac/institutes/grid.415877.8", 
          "name": [
            "International Tomography Center, Russian Academy of Sciences, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Romanenko", 
        "givenName": "G. V.", 
        "id": "sg:person.0664032236.40", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0664032236.40"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "International Tomography Center, Russian Academy of Sciences, Novosibirsk, Russia", 
          "id": "http://www.grid.ac/institutes/grid.415877.8", 
          "name": [
            "International Tomography Center, Russian Academy of Sciences, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Bogomyakov", 
        "givenName": "A. S.", 
        "id": "sg:person.0776526105.71", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0776526105.71"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "International Tomography Center, Russian Academy of Sciences, Novosibirsk, Russia", 
          "id": "http://www.grid.ac/institutes/grid.415877.8", 
          "name": [
            "International Tomography Center, Russian Academy of Sciences, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kuznetsova", 
        "givenName": "O. V.", 
        "id": "sg:person.014656244141.04", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014656244141.04"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "International Tomography Center, Russian Academy of Sciences, Novosibirsk, Russia", 
          "id": "http://www.grid.ac/institutes/grid.415877.8", 
          "name": [
            "International Tomography Center, Russian Academy of Sciences, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Fursova", 
        "givenName": "E. Yu.", 
        "id": "sg:person.07501453217.49", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07501453217.49"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "International Tomography Center, Russian Academy of Sciences, Novosibirsk, Russia", 
          "id": "http://www.grid.ac/institutes/grid.415877.8", 
          "name": [
            "International Tomography Center, Russian Academy of Sciences, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ovcharenko", 
        "givenName": "V. I.", 
        "id": "sg:person.0732145436.56", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0732145436.56"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "2009-12", 
    "datePublishedReg": "2009-12-01", 
    "description": "We succeeded in synthesizing a new high-spin complex [Fe2(CN)12Ni3(L)6]\u00b727H2O, where L is stable nitroxide 2-(imidazol-4-yl)-4,4,5,5-tetramethyl-2-imidazoline-3-oxide-1-oxyl. According to X-ray diffraction data, the metal core of the pentanuclear [Fe2(CN)12Ni3(L)6] molecule is a trigonal bipyramid with Fe atoms occupying the axial positions and linked via CN bridges to {NiL2} fragments laying in the equatorial plane. A peculiarity of this coordination compound is a large number of water molecules per the [Fe2(CN)12Ni3(L)6] pentanuclear molecule in the structure. The complex character of the \u03bceff(T) dependence points to many competing channels of exchange interactions between the three types of paramagnetic centers.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/s10947-009-0169-x", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1135923", 
        "issn": [
          "0022-4766", 
          "2542-0976"
        ], 
        "name": "Journal of Structural Chemistry", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "6", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "50"
      }
    ], 
    "keywords": [
      "high-spin complexes", 
      "ray diffraction data", 
      "coordination compounds", 
      "water molecules", 
      "pentanuclear complex", 
      "nitronyl nitroxide", 
      "CN bridges", 
      "metal core", 
      "trigonal bipyramid", 
      "paramagnetic centers", 
      "axial positions", 
      "magnetic properties", 
      "diffraction data", 
      "molecules", 
      "Fe atoms", 
      "equatorial plane", 
      "exchange interaction", 
      "complexes", 
      "NiL2", 
      "bipyramid", 
      "nitroxides", 
      "synthesis", 
      "atoms", 
      "compounds", 
      "structure", 
      "properties", 
      "bridge", 
      "interaction", 
      "core", 
      "complex character", 
      "dependence", 
      "fragments", 
      "character", 
      "peculiarities", 
      "large number", 
      "plane", 
      "center", 
      "position", 
      "types", 
      "channels", 
      "number", 
      "data", 
      "new high-spin complex", 
      "pentanuclear [Fe2(CN)12Ni3(L)6] molecule"
    ], 
    "name": "Synthesis, structure and magnetic properties of the pentanuclear complex [Fe2(CN)12Ni3(L)6]\u00b727H2O, where L is nitronyl nitroxide", 
    "pagination": "1155-1158", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1026850540"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s10947-009-0169-x"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s10947-009-0169-x", 
      "https://app.dimensions.ai/details/publication/pub.1026850540"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2021-11-01T18:12", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20211101/entities/gbq_results/article/article_486.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/s10947-009-0169-x"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10947-009-0169-x'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10947-009-0169-x'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10947-009-0169-x'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10947-009-0169-x'


 

This table displays all metadata directly associated to this object as RDF triples.

154 TRIPLES      21 PREDICATES      70 URIs      62 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s10947-009-0169-x schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author Ndbd7cebe2ee34a96b4f6e063776b2a21
4 schema:datePublished 2009-12
5 schema:datePublishedReg 2009-12-01
6 schema:description We succeeded in synthesizing a new high-spin complex [Fe2(CN)12Ni3(L)6]·27H2O, where L is stable nitroxide 2-(imidazol-4-yl)-4,4,5,5-tetramethyl-2-imidazoline-3-oxide-1-oxyl. According to X-ray diffraction data, the metal core of the pentanuclear [Fe2(CN)12Ni3(L)6] molecule is a trigonal bipyramid with Fe atoms occupying the axial positions and linked via CN bridges to {NiL2} fragments laying in the equatorial plane. A peculiarity of this coordination compound is a large number of water molecules per the [Fe2(CN)12Ni3(L)6] pentanuclear molecule in the structure. The complex character of the μeff(T) dependence points to many competing channels of exchange interactions between the three types of paramagnetic centers.
7 schema:genre article
8 schema:inLanguage en
9 schema:isAccessibleForFree false
10 schema:isPartOf N2913811258b04d3c8d760e20171ac264
11 Nbbe35209f0104749ae65630db138d0ff
12 sg:journal.1135923
13 schema:keywords CN bridges
14 Fe atoms
15 NiL2
16 atoms
17 axial positions
18 bipyramid
19 bridge
20 center
21 channels
22 character
23 complex character
24 complexes
25 compounds
26 coordination compounds
27 core
28 data
29 dependence
30 diffraction data
31 equatorial plane
32 exchange interaction
33 fragments
34 high-spin complexes
35 interaction
36 large number
37 magnetic properties
38 metal core
39 molecules
40 new high-spin complex
41 nitronyl nitroxide
42 nitroxides
43 number
44 paramagnetic centers
45 peculiarities
46 pentanuclear [Fe2(CN)12Ni3(L)6] molecule
47 pentanuclear complex
48 plane
49 position
50 properties
51 ray diffraction data
52 structure
53 synthesis
54 trigonal bipyramid
55 types
56 water molecules
57 schema:name Synthesis, structure and magnetic properties of the pentanuclear complex [Fe2(CN)12Ni3(L)6]·27H2O, where L is nitronyl nitroxide
58 schema:pagination 1155-1158
59 schema:productId N743477d04cd342409b8af8c7625e4c35
60 N9a7aa158d59e498fa7fc6ea45fa0cd84
61 schema:sameAs https://app.dimensions.ai/details/publication/pub.1026850540
62 https://doi.org/10.1007/s10947-009-0169-x
63 schema:sdDatePublished 2021-11-01T18:12
64 schema:sdLicense https://scigraph.springernature.com/explorer/license/
65 schema:sdPublisher Nd88af5e29bc14b359209aec6e9e1517d
66 schema:url https://doi.org/10.1007/s10947-009-0169-x
67 sgo:license sg:explorer/license/
68 sgo:sdDataset articles
69 rdf:type schema:ScholarlyArticle
70 N2913811258b04d3c8d760e20171ac264 schema:issueNumber 6
71 rdf:type schema:PublicationIssue
72 N2de6bb2c7ad94345b012aa7701e8a3da rdf:first sg:person.07501453217.49
73 rdf:rest Nbdad1001e47c4bfe9c998ccd02115563
74 N57666dfd3e7140788b06f1a586321d55 rdf:first sg:person.0776526105.71
75 rdf:rest N7f50f48079cf431a87c09690be7cea78
76 N743477d04cd342409b8af8c7625e4c35 schema:name doi
77 schema:value 10.1007/s10947-009-0169-x
78 rdf:type schema:PropertyValue
79 N7f50f48079cf431a87c09690be7cea78 rdf:first sg:person.014656244141.04
80 rdf:rest N2de6bb2c7ad94345b012aa7701e8a3da
81 N85eecc9a3c854a18a38e8689e8f9512d rdf:first sg:person.015020535341.47
82 rdf:rest Nc6f267ea3d5b4db5b3042b8bef3ed87d
83 N9a7aa158d59e498fa7fc6ea45fa0cd84 schema:name dimensions_id
84 schema:value pub.1026850540
85 rdf:type schema:PropertyValue
86 Nac0633d532724dafba88bc065ec54695 rdf:first sg:person.015042513561.53
87 rdf:rest N85eecc9a3c854a18a38e8689e8f9512d
88 Nbbe35209f0104749ae65630db138d0ff schema:volumeNumber 50
89 rdf:type schema:PublicationVolume
90 Nbdad1001e47c4bfe9c998ccd02115563 rdf:first sg:person.0732145436.56
91 rdf:rest rdf:nil
92 Nc6f267ea3d5b4db5b3042b8bef3ed87d rdf:first sg:person.0664032236.40
93 rdf:rest N57666dfd3e7140788b06f1a586321d55
94 Nd88af5e29bc14b359209aec6e9e1517d schema:name Springer Nature - SN SciGraph project
95 rdf:type schema:Organization
96 Ndbd7cebe2ee34a96b4f6e063776b2a21 rdf:first sg:person.010320537205.82
97 rdf:rest Nac0633d532724dafba88bc065ec54695
98 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
99 schema:name Chemical Sciences
100 rdf:type schema:DefinedTerm
101 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
102 schema:name Physical Chemistry (incl. Structural)
103 rdf:type schema:DefinedTerm
104 sg:journal.1135923 schema:issn 0022-4766
105 2542-0976
106 schema:name Journal of Structural Chemistry
107 schema:publisher Springer Nature
108 rdf:type schema:Periodical
109 sg:person.010320537205.82 schema:affiliation grid-institutes:grid.257022.0
110 schema:familyName Higashikawa
111 schema:givenName H.
112 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010320537205.82
113 rdf:type schema:Person
114 sg:person.014656244141.04 schema:affiliation grid-institutes:grid.415877.8
115 schema:familyName Kuznetsova
116 schema:givenName O. V.
117 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014656244141.04
118 rdf:type schema:Person
119 sg:person.015020535341.47 schema:affiliation grid-institutes:grid.415877.8
120 schema:familyName Maryunina
121 schema:givenName K. Yu.
122 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015020535341.47
123 rdf:type schema:Person
124 sg:person.015042513561.53 schema:affiliation grid-institutes:grid.257022.0
125 schema:familyName Inoue
126 schema:givenName K.
127 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015042513561.53
128 rdf:type schema:Person
129 sg:person.0664032236.40 schema:affiliation grid-institutes:grid.415877.8
130 schema:familyName Romanenko
131 schema:givenName G. V.
132 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0664032236.40
133 rdf:type schema:Person
134 sg:person.0732145436.56 schema:affiliation grid-institutes:grid.415877.8
135 schema:familyName Ovcharenko
136 schema:givenName V. I.
137 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0732145436.56
138 rdf:type schema:Person
139 sg:person.07501453217.49 schema:affiliation grid-institutes:grid.415877.8
140 schema:familyName Fursova
141 schema:givenName E. Yu.
142 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07501453217.49
143 rdf:type schema:Person
144 sg:person.0776526105.71 schema:affiliation grid-institutes:grid.415877.8
145 schema:familyName Bogomyakov
146 schema:givenName A. S.
147 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0776526105.71
148 rdf:type schema:Person
149 grid-institutes:grid.257022.0 schema:alternateName Department of Chemistry, Faculty of Science, Hiroshima University, 1-3-1 Kagamiyama, 739-8526, Higashi-hiroshima, Hiroshima, Japan
150 schema:name Department of Chemistry, Faculty of Science, Hiroshima University, 1-3-1 Kagamiyama, 739-8526, Higashi-hiroshima, Hiroshima, Japan
151 rdf:type schema:Organization
152 grid-institutes:grid.415877.8 schema:alternateName International Tomography Center, Russian Academy of Sciences, Novosibirsk, Russia
153 schema:name International Tomography Center, Russian Academy of Sciences, Novosibirsk, Russia
154 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...