Crystal structures of alkaloid peganine and its cocrystal with peganol View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2009-12

AUTHORS

R. Ya. Okmanov, A. G. Tozhiboev, K. K. Turgunov, B. Tashkhodzhaev, Z. M. Khakimova, T. S. Tulyaganov, Kh. M. Shakhidoyatov

ABSTRACT

X-ray diffraction (XRD) is used to investigate the crystal structures of the alkaloid peganine, its hemihydrate and nitrate. It is shown that (±)-peganine forms a cocrystal with the alkaloid peganol. It is typical of the alkaloid (−)-peganine crystal structures to form a closed dimer pair because of reciprocal O-H⋯N1 hydrogen bonds. Analogous H-bonds are also observed in the (±)-peganine-(±)-peganol cocrystal, where the center of symmetry binds together similar molecules to form associates. In (±)-peganine nitrate crystals, the NH+ and OH groups of the alkaloid form H-bonds simultaneously with two oxygen atoms of nitric acid anions. More... »

PAGES

1149-1154

References to SciGraph publications

  • 2007-05. Structures of crystalline mixed peganole-brompeganole systems in JOURNAL OF STRUCTURAL CHEMISTRY
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s10947-009-0168-y

    DOI

    http://dx.doi.org/10.1007/s10947-009-0168-y

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