X-ray diffraction study of [Ru(NH3)5Cl][ReCl6] and [Ru(NH3)5Cl]2[ReCl6]Cl2 and their thermolysis products. Crystal-chemical analysis of the Ru-Re system View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2009-02

AUTHORS

S. A. Martynova, K. V. Yusenko, I. V. Korolkov, I. A. Baidina, S. V. Korenev

ABSTRACT

Binary complex salts [Ru(NH3)5Cl][ReCl6] and [Ru(NH3)5Cl]2[ReCl6]Cl2 were synthesized and characterized. An X-ray diffraction analysis showed that they were isostructural with the previously obtained isoformula salts [Rh(NH3)5Cl][OsCl6] and [Ir(NH3)5Cl]2[PtCl6]Cl2, respectively. Thermolysis of these compounds under hydrogen and helium was studied. According to X-ray phase analysis data, bimetallic solid solutions Ru0.67Re0.33 and Ru0.50Re0.50 were the final products of thermolysis. Their unit cell parameters correspond to the characteristics of alloys with similar compositions. More... »

PAGES

120-126

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10947-009-0016-0

DOI

http://dx.doi.org/10.1007/s10947-009-0016-0

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1025634354


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