Molecular structure of 1-methyl-1-fluoroquasisilatrane (2-methyl-2-fluoro-1,3-dioxa-6-aza-2-silacyclooctane) View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2008-07

AUTHORS

A. A. Korlyukov, M. G. Voronkov, É. A. Zelbst, E. A. Grebneva, O. M. Trofimova, M. Yu. Antipin

ABSTRACT

The molecular structure of 1-methyl-1-fluoroquasisilatrane (2-methyl-2-fluoro-1,3-dioxa-6-aza-2-silacyclooctane) MeFSi(OCH2CH2)2NH (I) is determined by single crystal X-ray diffraction at 100 K. The coordination polyhedron of the silicon atom in this molecule is a slightly distorted trigonal bipyramid with an NH group and a strongly electron-withdrawing fluorine atom in the axial positions, and two endocyclic oxygen atoms and a CH3 group in three vertices of the equatorial plane. The axial angle N→SiF is 171°. The length of the transannular donor-acceptor bond N→Si (2.058 Å) is as small as in 1-fluorosilatrane. The axial bond F-Si (1.660 Å) is longer than that in 1-fluorosilatrane and tetrahedral silicon compounds. More... »

PAGES

732-736

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10947-008-0102-8

DOI

http://dx.doi.org/10.1007/s10947-008-0102-8

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1047422002


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "A. N. Nesmeyanov Institute of Organoelement Compounds", 
          "id": "https://www.grid.ac/institutes/grid.431939.5", 
          "name": [
            "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Korlyukov", 
        "givenName": "A. A.", 
        "id": "sg:person.01050521013.60", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01050521013.60"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "A. E. Favorskii Irkutsk Institute of Chemistry, Siberian Division, Russian Academy of Sciences, Irkutsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Voronkov", 
        "givenName": "M. G.", 
        "id": "sg:person.016410733065.70", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016410733065.70"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "Irkutsk State Pedagogical University, Irkutsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Zelbst", 
        "givenName": "\u00c9. A.", 
        "id": "sg:person.010354623007.45", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010354623007.45"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "A. E. Favorskii Irkutsk Institute of Chemistry, Siberian Division, Russian Academy of Sciences, Irkutsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Grebneva", 
        "givenName": "E. A.", 
        "id": "sg:person.010114234171.52", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010114234171.52"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "A. E. Favorskii Irkutsk Institute of Chemistry, Siberian Division, Russian Academy of Sciences, Irkutsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Trofimova", 
        "givenName": "O. M.", 
        "id": "sg:person.010446355057.52", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010446355057.52"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "A. N. Nesmeyanov Institute of Organoelement Compounds", 
          "id": "https://www.grid.ac/institutes/grid.431939.5", 
          "name": [
            "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Antipin", 
        "givenName": "M. Yu.", 
        "id": "sg:person.010142146727.55", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010142146727.55"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1016/0022-328x(84)80270-3", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1008053029"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0022-328x(00)86939-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1009145736"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0022-328x(00)90508-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012211805"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0022-328x(86)80213-3", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012819494"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10947-007-0059-z", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1028676829", 
          "https://doi.org/10.1007/s10947-007-0059-z"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/pl00000112", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1031456819", 
          "https://doi.org/10.1007/pl00000112"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0022-328x(00)92570-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034359323"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/zaac.19855200121", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1044025196"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2008-07", 
    "datePublishedReg": "2008-07-01", 
    "description": "The molecular structure of 1-methyl-1-fluoroquasisilatrane (2-methyl-2-fluoro-1,3-dioxa-6-aza-2-silacyclooctane) MeFSi(OCH2CH2)2NH (I) is determined by single crystal X-ray diffraction at 100 K. The coordination polyhedron of the silicon atom in this molecule is a slightly distorted trigonal bipyramid with an NH group and a strongly electron-withdrawing fluorine atom in the axial positions, and two endocyclic oxygen atoms and a CH3 group in three vertices of the equatorial plane. The axial angle N\u2192SiF is 171\u00b0. The length of the transannular donor-acceptor bond N\u2192Si (2.058 \u00c5) is as small as in 1-fluorosilatrane. The axial bond F-Si (1.660 \u00c5) is longer than that in 1-fluorosilatrane and tetrahedral silicon compounds.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s10947-008-0102-8", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1135923", 
        "issn": [
          "0022-4766", 
          "2542-0976"
        ], 
        "name": "Journal of Structural Chemistry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "4", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "49"
      }
    ], 
    "name": "Molecular structure of 1-methyl-1-fluoroquasisilatrane (2-methyl-2-fluoro-1,3-dioxa-6-aza-2-silacyclooctane)", 
    "pagination": "732-736", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "e1e72f1649cdf229992171962042da71c355fcd796a6cf240d9dbe4aa8249f0f"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s10947-008-0102-8"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1047422002"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s10947-008-0102-8", 
      "https://app.dimensions.ai/details/publication/pub.1047422002"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T16:43", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8669_00000515.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007%2Fs10947-008-0102-8"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10947-008-0102-8'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10947-008-0102-8'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10947-008-0102-8'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10947-008-0102-8'


 

This table displays all metadata directly associated to this object as RDF triples.

127 TRIPLES      21 PREDICATES      35 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s10947-008-0102-8 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author Nebc5cf94ada14e29b2c0f5c8d9d05951
4 schema:citation sg:pub.10.1007/pl00000112
5 sg:pub.10.1007/s10947-007-0059-z
6 https://doi.org/10.1002/zaac.19855200121
7 https://doi.org/10.1016/0022-328x(84)80270-3
8 https://doi.org/10.1016/0022-328x(86)80213-3
9 https://doi.org/10.1016/s0022-328x(00)86939-9
10 https://doi.org/10.1016/s0022-328x(00)90508-4
11 https://doi.org/10.1016/s0022-328x(00)92570-1
12 schema:datePublished 2008-07
13 schema:datePublishedReg 2008-07-01
14 schema:description The molecular structure of 1-methyl-1-fluoroquasisilatrane (2-methyl-2-fluoro-1,3-dioxa-6-aza-2-silacyclooctane) MeFSi(OCH2CH2)2NH (I) is determined by single crystal X-ray diffraction at 100 K. The coordination polyhedron of the silicon atom in this molecule is a slightly distorted trigonal bipyramid with an NH group and a strongly electron-withdrawing fluorine atom in the axial positions, and two endocyclic oxygen atoms and a CH3 group in three vertices of the equatorial plane. The axial angle N→SiF is 171°. The length of the transannular donor-acceptor bond N→Si (2.058 Å) is as small as in 1-fluorosilatrane. The axial bond F-Si (1.660 Å) is longer than that in 1-fluorosilatrane and tetrahedral silicon compounds.
15 schema:genre research_article
16 schema:inLanguage en
17 schema:isAccessibleForFree false
18 schema:isPartOf N9464085d6d3d499eb242e532b12cf654
19 Ne4bb49e56b93474e94cef235354a71d4
20 sg:journal.1135923
21 schema:name Molecular structure of 1-methyl-1-fluoroquasisilatrane (2-methyl-2-fluoro-1,3-dioxa-6-aza-2-silacyclooctane)
22 schema:pagination 732-736
23 schema:productId N82d8efc9df40453196aa703f14cf6f47
24 Nbe8ced5753e84cb684fa8937d679806e
25 Nc444895c20d24a28b8386b264f67f9c0
26 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047422002
27 https://doi.org/10.1007/s10947-008-0102-8
28 schema:sdDatePublished 2019-04-10T16:43
29 schema:sdLicense https://scigraph.springernature.com/explorer/license/
30 schema:sdPublisher N58bea62e46e245c18d831ebfa5f4d64c
31 schema:url http://link.springer.com/10.1007%2Fs10947-008-0102-8
32 sgo:license sg:explorer/license/
33 sgo:sdDataset articles
34 rdf:type schema:ScholarlyArticle
35 N03071aaf9c0e4fdbb8780482374c133b rdf:first sg:person.010114234171.52
36 rdf:rest N50fd7f4c7cf1440dba614a54a26f2c8c
37 N1f74fdc3b62d44cb9963cce45ad8ce6c rdf:first sg:person.016410733065.70
38 rdf:rest Nbfc5fafe334945de893b457698ff7cf5
39 N29a630b7df2c45ceb455119b81efe193 rdf:first sg:person.010142146727.55
40 rdf:rest rdf:nil
41 N50fd7f4c7cf1440dba614a54a26f2c8c rdf:first sg:person.010446355057.52
42 rdf:rest N29a630b7df2c45ceb455119b81efe193
43 N58bea62e46e245c18d831ebfa5f4d64c schema:name Springer Nature - SN SciGraph project
44 rdf:type schema:Organization
45 N82d8efc9df40453196aa703f14cf6f47 schema:name readcube_id
46 schema:value e1e72f1649cdf229992171962042da71c355fcd796a6cf240d9dbe4aa8249f0f
47 rdf:type schema:PropertyValue
48 N9464085d6d3d499eb242e532b12cf654 schema:volumeNumber 49
49 rdf:type schema:PublicationVolume
50 Na2d93d4ea8a14bf4b14702f7093fb4c9 schema:name Irkutsk State Pedagogical University, Irkutsk, Russia
51 rdf:type schema:Organization
52 Nbe8ced5753e84cb684fa8937d679806e schema:name doi
53 schema:value 10.1007/s10947-008-0102-8
54 rdf:type schema:PropertyValue
55 Nbfc5fafe334945de893b457698ff7cf5 rdf:first sg:person.010354623007.45
56 rdf:rest N03071aaf9c0e4fdbb8780482374c133b
57 Nc444895c20d24a28b8386b264f67f9c0 schema:name dimensions_id
58 schema:value pub.1047422002
59 rdf:type schema:PropertyValue
60 Ne4bb49e56b93474e94cef235354a71d4 schema:issueNumber 4
61 rdf:type schema:PublicationIssue
62 Nebc5cf94ada14e29b2c0f5c8d9d05951 rdf:first sg:person.01050521013.60
63 rdf:rest N1f74fdc3b62d44cb9963cce45ad8ce6c
64 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
65 schema:name Chemical Sciences
66 rdf:type schema:DefinedTerm
67 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
68 schema:name Physical Chemistry (incl. Structural)
69 rdf:type schema:DefinedTerm
70 sg:journal.1135923 schema:issn 0022-4766
71 2542-0976
72 schema:name Journal of Structural Chemistry
73 rdf:type schema:Periodical
74 sg:person.010114234171.52 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
75 schema:familyName Grebneva
76 schema:givenName E. A.
77 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010114234171.52
78 rdf:type schema:Person
79 sg:person.010142146727.55 schema:affiliation https://www.grid.ac/institutes/grid.431939.5
80 schema:familyName Antipin
81 schema:givenName M. Yu.
82 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010142146727.55
83 rdf:type schema:Person
84 sg:person.010354623007.45 schema:affiliation Na2d93d4ea8a14bf4b14702f7093fb4c9
85 schema:familyName Zelbst
86 schema:givenName É. A.
87 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010354623007.45
88 rdf:type schema:Person
89 sg:person.010446355057.52 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
90 schema:familyName Trofimova
91 schema:givenName O. M.
92 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010446355057.52
93 rdf:type schema:Person
94 sg:person.01050521013.60 schema:affiliation https://www.grid.ac/institutes/grid.431939.5
95 schema:familyName Korlyukov
96 schema:givenName A. A.
97 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01050521013.60
98 rdf:type schema:Person
99 sg:person.016410733065.70 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
100 schema:familyName Voronkov
101 schema:givenName M. G.
102 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016410733065.70
103 rdf:type schema:Person
104 sg:pub.10.1007/pl00000112 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031456819
105 https://doi.org/10.1007/pl00000112
106 rdf:type schema:CreativeWork
107 sg:pub.10.1007/s10947-007-0059-z schema:sameAs https://app.dimensions.ai/details/publication/pub.1028676829
108 https://doi.org/10.1007/s10947-007-0059-z
109 rdf:type schema:CreativeWork
110 https://doi.org/10.1002/zaac.19855200121 schema:sameAs https://app.dimensions.ai/details/publication/pub.1044025196
111 rdf:type schema:CreativeWork
112 https://doi.org/10.1016/0022-328x(84)80270-3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1008053029
113 rdf:type schema:CreativeWork
114 https://doi.org/10.1016/0022-328x(86)80213-3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012819494
115 rdf:type schema:CreativeWork
116 https://doi.org/10.1016/s0022-328x(00)86939-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1009145736
117 rdf:type schema:CreativeWork
118 https://doi.org/10.1016/s0022-328x(00)90508-4 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012211805
119 rdf:type schema:CreativeWork
120 https://doi.org/10.1016/s0022-328x(00)92570-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034359323
121 rdf:type schema:CreativeWork
122 https://www.grid.ac/institutes/grid.431939.5 schema:alternateName A. N. Nesmeyanov Institute of Organoelement Compounds
123 schema:name A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia
124 rdf:type schema:Organization
125 https://www.grid.ac/institutes/grid.4886.2 schema:alternateName Russian Academy of Sciences
126 schema:name A. E. Favorskii Irkutsk Institute of Chemistry, Siberian Division, Russian Academy of Sciences, Irkutsk, Russia
127 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...