Balance, uniformity, and asymmetry of the structure of volborthite Cu3(OH)2(V2O7)·2H2O View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2008-07

AUTHORS

A. A. Kashaev, I. V. Rozhdestvenskaya, I. I. Bannova, A. N. Sapozhnikov, O. D. Glebova

ABSTRACT

Four structural models of volborthite Cu3(OH)2(V2O7)·2H2O (a = 10.646(2) Å, b = 5.867(1) Å, c = 14.432(2) Å, β = 95.19(1)°, V = 897.7(5) Å3, Z = 4, R/Rw = 0.038/0.046) calculated in the space groups determined from the systematic absences are compared. Based on the structure balance and the similarity of constituting polyhedra, values of the R factor, and isotropic thermal parameters, the space group Ia is found to be preferable, which is the only possible asymmetric and uniform variant. Hydrogen atoms of OH-groups, oxygen atoms and, partially, hydrogen atoms of water are localized. More... »

PAGES

708-711

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10947-008-0098-0

DOI

http://dx.doi.org/10.1007/s10947-008-0098-0

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1024362313


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