Crystal and molecular structure of polyunsaturated macrobicyclic carbosilane C24H38Si6 View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2007-07

AUTHORS

A. A. Korlyukov, M. G. Voronkov, L. V. Zhilitskaya, E. E. Istomina, M. Yu. Antipin

ABSTRACT

The crystal and molecular structure of the polyunsaturated macrocyclic carbosilane 1,4,4,7,7,10,13, 13,16,16-decamethyl-1,4,7,10,13,16-hexasilabicyclo-[8.8.2]-eucosa-5,14-diene-2,8,11,17-tetrain containing SiC(sp), SiC(sp2), and SiC(sp3) endocyclic bonds was studied by XRD. The two strained 12-membered rings of this molecule have different (trans-zigzag and staggered) conformations. The lengths of the endocyclic bonds SiC(sp) are 1.821–1.852 Å, SiC(sp2) 1.855–1.874 Å, and SiC(sp3) 1.847–1.853 Å. The structure of the rings was solved by direct methods and refined by the full-matrix least-squares method. Calculations were carried out with SHELXTL PLUS 5.1 software. More... »

PAGES

719-722

References to SciGraph publications

  • 1991-08. Molecular properties of some new cyclic ethynylsilanes in MONATSHEFTE FÜR CHEMIE - CHEMICAL MONTHLY
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    http://scigraph.springernature.com/pub.10.1007/s10947-007-0109-6

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    http://dx.doi.org/10.1007/s10947-007-0109-6

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