Ordering of Cu(II) ions in supported copper-titanium oxide catalysts View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2006-11

AUTHORS

A. A. Altynnikov, L. T. Tsikoza, V. F. Anufrienko

ABSTRACT

Two types of ESR spectrum (A and B) of exchange-coupled Cu2+ ions have been found for Cu-Ti-O catalysts at 77 K and 300 K. In associates A and B, the Cu2+ ions form a system with orbital ordering. The difference between the spectra is due to the difference between the ground states of adjacent Cu2+ ions in the associates: the ground states are \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document} $$d_{x^2 } $$ \end{document} and \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document} $$d_{y^2 } $$ \end{document} for A type associates and \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document} $$d_{x^2 - y^2 } $$ \end{document} and \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document} $$d_{z^2 - x^2 } $$ \end{document} for B type associates. The copper associates lie on the surface of the TiO2 (anatase) support microparticles. More... »

PAGES

1161-1169

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10947-006-0439-9

DOI

http://dx.doi.org/10.1007/s10947-006-0439-9

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1012098338


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "G. K. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk", 
          "id": "http://www.grid.ac/institutes/grid.415877.8", 
          "name": [
            "G. K. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Altynnikov", 
        "givenName": "A. A.", 
        "id": "sg:person.012750151547.11", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012750151547.11"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "G. K. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk", 
          "id": "http://www.grid.ac/institutes/grid.415877.8", 
          "name": [
            "G. K. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Tsikoza", 
        "givenName": "L. T.", 
        "id": "sg:person.0767554705.05", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0767554705.05"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "G. K. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk", 
          "id": "http://www.grid.ac/institutes/grid.415877.8", 
          "name": [
            "G. K. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Anufrienko", 
        "givenName": "V. F.", 
        "id": "sg:person.013477314655.59", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013477314655.59"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1007/bf02071032", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1042003629", 
          "https://doi.org/10.1007/bf02071032"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/3-540-09455-5_1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1031333095", 
          "https://doi.org/10.1007/3-540-09455-5_1"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02076536", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1042659543", 
          "https://doi.org/10.1007/bf02076536"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02162711", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1038190391", 
          "https://doi.org/10.1007/bf02162711"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02129860", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006805511", 
          "https://doi.org/10.1007/bf02129860"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02071031", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1045649351", 
          "https://doi.org/10.1007/bf02071031"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2006-11", 
    "datePublishedReg": "2006-11-01", 
    "description": "Two types of ESR spectrum (A and B) of exchange-coupled Cu2+ ions have been found for Cu-Ti-O catalysts at 77 K and 300 K. In associates A and B, the Cu2+ ions form a system with orbital ordering. The difference between the spectra is due to the difference between the ground states of adjacent Cu2+ ions in the associates: the ground states are \\documentclass[12pt]{minimal}\n\t\t\t\t\\usepackage{amsmath}\n\t\t\t\t\\usepackage{wasysym}\n\t\t\t\t\\usepackage{amsfonts}\n\t\t\t\t\\usepackage{amssymb}\n\t\t\t\t\\usepackage{amsbsy}\n\t\t\t\t\\usepackage{mathrsfs}\n\t\t\t\t\\usepackage{upgreek}\n\t\t\t\t\\setlength{\\oddsidemargin}{-69pt}\n\t\t\t\t\\begin{document}\n$$d_{x^2 } $$\n\\end{document} and \\documentclass[12pt]{minimal}\n\t\t\t\t\\usepackage{amsmath}\n\t\t\t\t\\usepackage{wasysym}\n\t\t\t\t\\usepackage{amsfonts}\n\t\t\t\t\\usepackage{amssymb}\n\t\t\t\t\\usepackage{amsbsy}\n\t\t\t\t\\usepackage{mathrsfs}\n\t\t\t\t\\usepackage{upgreek}\n\t\t\t\t\\setlength{\\oddsidemargin}{-69pt}\n\t\t\t\t\\begin{document}\n$$d_{y^2 } $$\n\\end{document} for A type associates and \\documentclass[12pt]{minimal}\n\t\t\t\t\\usepackage{amsmath}\n\t\t\t\t\\usepackage{wasysym}\n\t\t\t\t\\usepackage{amsfonts}\n\t\t\t\t\\usepackage{amssymb}\n\t\t\t\t\\usepackage{amsbsy}\n\t\t\t\t\\usepackage{mathrsfs}\n\t\t\t\t\\usepackage{upgreek}\n\t\t\t\t\\setlength{\\oddsidemargin}{-69pt}\n\t\t\t\t\\begin{document}\n$$d_{x^2  - y^2 } $$\n\\end{document} and \\documentclass[12pt]{minimal}\n\t\t\t\t\\usepackage{amsmath}\n\t\t\t\t\\usepackage{wasysym}\n\t\t\t\t\\usepackage{amsfonts}\n\t\t\t\t\\usepackage{amssymb}\n\t\t\t\t\\usepackage{amsbsy}\n\t\t\t\t\\usepackage{mathrsfs}\n\t\t\t\t\\usepackage{upgreek}\n\t\t\t\t\\setlength{\\oddsidemargin}{-69pt}\n\t\t\t\t\\begin{document}\n$$d_{z^2  - x^2 } $$\n\\end{document} for B type associates. The copper associates lie on the surface of the TiO2 (anatase) support microparticles.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/s10947-006-0439-9", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1135923", 
        "issn": [
          "0022-4766", 
          "0136-7463"
        ], 
        "name": "Journal of Structural Chemistry", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "6", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "47"
      }
    ], 
    "keywords": [
      "O catalysts", 
      "oxide catalysts", 
      "adjacent Cu2", 
      "ESR spectra", 
      "ground state", 
      "Cu2", 
      "ions", 
      "catalyst", 
      "exchange-coupled Cu2", 
      "orbital ordering", 
      "spectra", 
      "Cu-Ti", 
      "microparticles", 
      "surface", 
      "ordering", 
      "state", 
      "associates", 
      "system", 
      "types", 
      "differences"
    ], 
    "name": "Ordering of Cu(II) ions in supported copper-titanium oxide catalysts", 
    "pagination": "1161-1169", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1012098338"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s10947-006-0439-9"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s10947-006-0439-9", 
      "https://app.dimensions.ai/details/publication/pub.1012098338"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-08-04T16:55", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220804/entities/gbq_results/article/article_416.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/s10947-006-0439-9"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10947-006-0439-9'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10947-006-0439-9'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10947-006-0439-9'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10947-006-0439-9'


 

This table displays all metadata directly associated to this object as RDF triples.

115 TRIPLES      21 PREDICATES      51 URIs      37 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s10947-006-0439-9 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author Ndf1bd8536bb041b3ac81455a3ab56d86
4 schema:citation sg:pub.10.1007/3-540-09455-5_1
5 sg:pub.10.1007/bf02071031
6 sg:pub.10.1007/bf02071032
7 sg:pub.10.1007/bf02076536
8 sg:pub.10.1007/bf02129860
9 sg:pub.10.1007/bf02162711
10 schema:datePublished 2006-11
11 schema:datePublishedReg 2006-11-01
12 schema:description Two types of ESR spectrum (A and B) of exchange-coupled Cu2+ ions have been found for Cu-Ti-O catalysts at 77 K and 300 K. In associates A and B, the Cu2+ ions form a system with orbital ordering. The difference between the spectra is due to the difference between the ground states of adjacent Cu2+ ions in the associates: the ground states are \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document} $$d_{x^2 } $$ \end{document} and \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document} $$d_{y^2 } $$ \end{document} for A type associates and \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document} $$d_{x^2 - y^2 } $$ \end{document} and \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document} $$d_{z^2 - x^2 } $$ \end{document} for B type associates. The copper associates lie on the surface of the TiO2 (anatase) support microparticles.
13 schema:genre article
14 schema:isAccessibleForFree false
15 schema:isPartOf N19d6af4602204693aa1d480d8f08e5c9
16 N6ae56a8a9d7d464898af647cee4ef6ec
17 sg:journal.1135923
18 schema:keywords Cu-Ti
19 Cu2
20 ESR spectra
21 O catalysts
22 adjacent Cu2
23 associates
24 catalyst
25 differences
26 exchange-coupled Cu2
27 ground state
28 ions
29 microparticles
30 orbital ordering
31 ordering
32 oxide catalysts
33 spectra
34 state
35 surface
36 system
37 types
38 schema:name Ordering of Cu(II) ions in supported copper-titanium oxide catalysts
39 schema:pagination 1161-1169
40 schema:productId N6224c3995e32419383cce19fca882657
41 Nd3728aa7c31e44b5b8da8ff9ad2c3e8a
42 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012098338
43 https://doi.org/10.1007/s10947-006-0439-9
44 schema:sdDatePublished 2022-08-04T16:55
45 schema:sdLicense https://scigraph.springernature.com/explorer/license/
46 schema:sdPublisher Na92c9236eeb744ce8b151ba79621883c
47 schema:url https://doi.org/10.1007/s10947-006-0439-9
48 sgo:license sg:explorer/license/
49 sgo:sdDataset articles
50 rdf:type schema:ScholarlyArticle
51 N19d6af4602204693aa1d480d8f08e5c9 schema:issueNumber 6
52 rdf:type schema:PublicationIssue
53 N3b032a454818402088e89ac6c231d3bd rdf:first sg:person.0767554705.05
54 rdf:rest N4f2b9a0a4219401a9778fb441302949f
55 N4f2b9a0a4219401a9778fb441302949f rdf:first sg:person.013477314655.59
56 rdf:rest rdf:nil
57 N6224c3995e32419383cce19fca882657 schema:name doi
58 schema:value 10.1007/s10947-006-0439-9
59 rdf:type schema:PropertyValue
60 N6ae56a8a9d7d464898af647cee4ef6ec schema:volumeNumber 47
61 rdf:type schema:PublicationVolume
62 Na92c9236eeb744ce8b151ba79621883c schema:name Springer Nature - SN SciGraph project
63 rdf:type schema:Organization
64 Nd3728aa7c31e44b5b8da8ff9ad2c3e8a schema:name dimensions_id
65 schema:value pub.1012098338
66 rdf:type schema:PropertyValue
67 Ndf1bd8536bb041b3ac81455a3ab56d86 rdf:first sg:person.012750151547.11
68 rdf:rest N3b032a454818402088e89ac6c231d3bd
69 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
70 schema:name Chemical Sciences
71 rdf:type schema:DefinedTerm
72 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
73 schema:name Physical Chemistry (incl. Structural)
74 rdf:type schema:DefinedTerm
75 sg:journal.1135923 schema:issn 0022-4766
76 0136-7463
77 schema:name Journal of Structural Chemistry
78 schema:publisher Springer Nature
79 rdf:type schema:Periodical
80 sg:person.012750151547.11 schema:affiliation grid-institutes:grid.415877.8
81 schema:familyName Altynnikov
82 schema:givenName A. A.
83 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012750151547.11
84 rdf:type schema:Person
85 sg:person.013477314655.59 schema:affiliation grid-institutes:grid.415877.8
86 schema:familyName Anufrienko
87 schema:givenName V. F.
88 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013477314655.59
89 rdf:type schema:Person
90 sg:person.0767554705.05 schema:affiliation grid-institutes:grid.415877.8
91 schema:familyName Tsikoza
92 schema:givenName L. T.
93 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0767554705.05
94 rdf:type schema:Person
95 sg:pub.10.1007/3-540-09455-5_1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031333095
96 https://doi.org/10.1007/3-540-09455-5_1
97 rdf:type schema:CreativeWork
98 sg:pub.10.1007/bf02071031 schema:sameAs https://app.dimensions.ai/details/publication/pub.1045649351
99 https://doi.org/10.1007/bf02071031
100 rdf:type schema:CreativeWork
101 sg:pub.10.1007/bf02071032 schema:sameAs https://app.dimensions.ai/details/publication/pub.1042003629
102 https://doi.org/10.1007/bf02071032
103 rdf:type schema:CreativeWork
104 sg:pub.10.1007/bf02076536 schema:sameAs https://app.dimensions.ai/details/publication/pub.1042659543
105 https://doi.org/10.1007/bf02076536
106 rdf:type schema:CreativeWork
107 sg:pub.10.1007/bf02129860 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006805511
108 https://doi.org/10.1007/bf02129860
109 rdf:type schema:CreativeWork
110 sg:pub.10.1007/bf02162711 schema:sameAs https://app.dimensions.ai/details/publication/pub.1038190391
111 https://doi.org/10.1007/bf02162711
112 rdf:type schema:CreativeWork
113 grid-institutes:grid.415877.8 schema:alternateName G. K. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk
114 schema:name G. K. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk
115 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...