Ordering of Cu(II) ions in supported copper-titanium oxide catalysts View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2006-11

AUTHORS

A. A. Altynnikov, L. T. Tsikoza, V. F. Anufrienko

ABSTRACT

Two types of ESR spectrum (A and B) of exchange-coupled Cu2+ ions have been found for Cu-Ti-O catalysts at 77 K and 300 K. In associates A and B, the Cu2+ ions form a system with orbital ordering. The difference between the spectra is due to the difference between the ground states of adjacent Cu2+ ions in the associates: the ground states are \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document} $$d_{x^2 } $$ \end{document} and \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document} $$d_{y^2 } $$ \end{document} for A type associates and \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document} $$d_{x^2 - y^2 } $$ \end{document} and \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document} $$d_{z^2 - x^2 } $$ \end{document} for B type associates. The copper associates lie on the surface of the TiO2 (anatase) support microparticles. More... »

PAGES

1161-1169

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10947-006-0439-9

DOI

http://dx.doi.org/10.1007/s10947-006-0439-9

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1012098338


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