X-ray diffraction investigation of siloxanes. I. Effects of organic substituents at the silicon atoms on the structure of acyclic trisiloxane-1,5-diols ... View Full Text


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Article Info

DATE

2006-11

AUTHORS

S. T. Malinovskii, A. Tesuro Vallina, H. Stoeckli-Evans

ABSTRACT

The molecular and crystal structure of four acyclic trisiloxane compounds, which differ in substituents at the silicon atoms (Ph-phenyl, mPh-methoxyphenyl, 2mPh-dimethoxyphenyl), was investigated by X-ray diffraction analysis. Due to intermolecular hydrogen bonding between the oxygen atoms of the diol fragments, the crystal structure of 1,1,5,5-tetramethyl-3,3-diphenyl-1,3,5-trisiloxane-1,5-diol (C16H24O4Si3) (I) is a double chain architecture with hydrogen-bonded dimeric motifs of C(8)R44(12) type in graph set representation. In 1,1,5,5-tetramethyl-3,3-(2-methoxybenzo)-1,3,5-trisiloxane-1,5-diol (C18H28O6Si3) (II) and 1,1,5,5-tetramethyl-3,3-(2,6-dimethoxybenzo)-1,3,5-trisiloxane-1,5-diol (C20H32O8Si3) (III), a double chain structure with a graph set R33(8)D33(10) is formed. In contrast to I–III, 1,1,3,3,5,5-hexaphenyl-1,3,5-trisiloxane-1,5-diol (C36H32O4Si3) (IV) has an intramolecular hydrogen bond S(8). The independent molecules are joined by O-H...O intermolecular hydrogen bonds into centrosymmetrical dimers; the system of hydrogen bonds in general may be described as S(8)R44(8). More... »

PAGES

1127-1133

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10947-006-0435-0

DOI

http://dx.doi.org/10.1007/s10947-006-0435-0

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1017294078


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