Synthesis of [M(NH3)5Cl](ReO4)2 (M = Cr, Co, Ru, Rh, Ir) and investigation of thermolysis products. Crystal structure of [Rh(NH3)5Cl](ReO4)2 View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2006-11

AUTHORS

Yu. V. Shubin, E. Yu. Filatov, I. A. Baidina, K. V. Yusenko, A. V. Zadesenetz, S. V. Korenev

ABSTRACT

Complex salts [M(NH3)5Cl](ReO4)2, where M = Cr, Co, Ru, Rh, Ir, have been prepared. The crystal structure of [Rh(NH3)5Cl](ReO4)2 was determined by single crystal X-ray diffraction. Crystal data: a = 17.369(4) Å, b = 7.7990(16) Å, c = 11.218(2) Å, V = 1430.5(5) Å3, space group C2/m, Z = 4, dcalc = 3.19 g/cm3, R = 0.0447. Complex salts from the above series are shown to be isostructural; they were defined by X-ray crystallography. Thermal decomposition of the compounds in an inert atmosphere and under hydrogen has been studied. According to X-ray phase analysis (XRPA) data, the M0.33Re0.67 (M = Co, Ru, Rh, Ir) monophase solid solutions are the products of reduction of the salts under hydrogen. More... »

PAGES

1103-1110

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10947-006-0432-3

DOI

http://dx.doi.org/10.1007/s10947-006-0432-3

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1051215407


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