Ontology type: schema:ScholarlyArticle
2006-11
AUTHORSN. N. Chipanina, T. N. Aksamentova, M. G. Voronkov, V. K. Turchaninov
ABSTRACTAccording to the data of quantum chemical calculations (HF, DFT), the isolated sp,sp conformer of (acetoxymethyl)trifluorosilane — pentacoordinated silicon compound — forms dimers with two intermolecular bonds Si-F→Si. The =O→Si intramolecular coordination bonds become stronger, which leads to the general stabilizing effect. In polar media, dimer formation is energetically unfavorable relative to monomer formation. More... »
PAGES1066-1070
http://scigraph.springernature.com/pub.10.1007/s10947-006-0426-1
DOIhttp://dx.doi.org/10.1007/s10947-006-0426-1
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