Trans-, cis-isomers of (1,1,1-trifluoro-2,4-pentandionato)Pt(II): Volatility, structure and crystal lattice energy View Full Text


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Article Info

DATE

2006-07

AUTHORS

G. I. Zharkova, I. A. Baidina, P. A. Stabnikov, I. K. Igumenov

ABSTRACT

Trans-and cis-complexes of platinum(II) with trifluoroacetylacetone (Pt(tfa)2) have been prepared and studied. The synthesis and the separation technique for the isomers are described. Temperature dependencies of saturated vapor pressure measured with a spoon gauge are reported for the cis-Pt(tfa)2 and trans-Pt(tfa)2 complexes. The isomers show a significant difference in volatility. The structural study of Pt(tfa)2 isomers has been performed. Molecular packings in the crystal of each isomer are considered on the base of structural data. The calculation of van der Waals energy of the crystal lattice of cis-Pt(tfa)2 and trans-Pt(tfa)2 was made by the atom-atom potential technique, their values being compared with experimental ΔHT0 values of sublimation for the complexes. More... »

PAGES

716-725

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10947-006-0360-2

DOI

http://dx.doi.org/10.1007/s10947-006-0360-2

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1003705044


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