Crystal and molecular structure of N-(1-silatranylmethyl)benzimidazole View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2005-11

AUTHORS

M. G. Voronkov, É. A. Zelbst, V. S. Fundamensky, Yu. V. Katkevich, Yu. I. Bolgova, O. M. Trofimova, N. F. Chernov

ABSTRACT

The crystal and molecular structure of N-(1-silatranylmethyl)benzimidazole was established by X-ray diffraction. The coordination polyhedron of the silicon atom in this molecule is a trigonal bipyramid. The bond lengths and angles of the N-(1-silatranylmethyl)benzimidazole (SMBI) molecule are compared with the corresponding values for other derivatives of this heterocycle. The silatranylmethyl group, having a high electron-donor inductive effect, does not increase the total aromaticity of the SMBI molecule. More... »

PAGES

1122-1125

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10947-006-0255-2

DOI

http://dx.doi.org/10.1007/s10947-006-0255-2

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1021654293


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "A. E. Favorsky Irkutsk Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, Russia", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "A. E. Favorsky Irkutsk Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Voronkov", 
        "givenName": "M. G.", 
        "id": "sg:person.016410733065.70", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016410733065.70"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Irkutsk State Pedagogical University, Russia", 
          "id": "http://www.grid.ac/institutes/None", 
          "name": [
            "Irkutsk State Pedagogical University, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Zelbst", 
        "givenName": "\u00c9. A.", 
        "id": "sg:person.010354623007.45", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010354623007.45"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Irkutsk State Pedagogical University, Russia", 
          "id": "http://www.grid.ac/institutes/None", 
          "name": [
            "Irkutsk State Pedagogical University, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Fundamensky", 
        "givenName": "V. S.", 
        "id": "sg:person.016337253113.99", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016337253113.99"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Irkutsk State Pedagogical University, Russia", 
          "id": "http://www.grid.ac/institutes/None", 
          "name": [
            "Irkutsk State Pedagogical University, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Katkevich", 
        "givenName": "Yu. V.", 
        "id": "sg:person.016377745416.49", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016377745416.49"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "A. E. Favorsky Irkutsk Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, Russia", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "A. E. Favorsky Irkutsk Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Bolgova", 
        "givenName": "Yu. I.", 
        "id": "sg:person.016473435547.10", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016473435547.10"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "A. E. Favorsky Irkutsk Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, Russia", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "A. E. Favorsky Irkutsk Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Trofimova", 
        "givenName": "O. M.", 
        "id": "sg:person.010446355057.52", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010446355057.52"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "A. E. Favorsky Irkutsk Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, Russia", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "A. E. Favorsky Irkutsk Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Chernov", 
        "givenName": "N. F.", 
        "id": "sg:person.012621274514.60", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012621274514.60"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "2005-11", 
    "datePublishedReg": "2005-11-01", 
    "description": "The crystal and molecular structure of N-(1-silatranylmethyl)benzimidazole was established by X-ray diffraction. The coordination polyhedron of the silicon atom in this molecule is a trigonal bipyramid. The bond lengths and angles of the N-(1-silatranylmethyl)benzimidazole (SMBI) molecule are compared with the corresponding values for other derivatives of this heterocycle. The silatranylmethyl group, having a high electron-donor inductive effect, does not increase the total aromaticity of the SMBI molecule.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/s10947-006-0255-2", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1135923", 
        "issn": [
          "0022-4766", 
          "2542-0976"
        ], 
        "name": "Journal of Structural Chemistry", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "6", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "46"
      }
    ], 
    "keywords": [
      "molecular structure", 
      "coordination polyhedron", 
      "ray diffraction", 
      "trigonal bipyramid", 
      "total aromaticity", 
      "silicon atoms", 
      "molecules", 
      "inductive effect", 
      "crystals", 
      "heterocycles", 
      "bipyramid", 
      "diffraction", 
      "bonds", 
      "aromaticity", 
      "structure", 
      "atoms", 
      "polyhedra", 
      "derivatives", 
      "corresponding values", 
      "angle", 
      "group", 
      "values", 
      "effect", 
      "silatranylmethyl group", 
      "high electron-donor inductive effect", 
      "electron-donor inductive effect", 
      "SMBI molecule"
    ], 
    "name": "Crystal and molecular structure of N-(1-silatranylmethyl)benzimidazole", 
    "pagination": "1122-1125", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1021654293"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s10947-006-0255-2"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s10947-006-0255-2", 
      "https://app.dimensions.ai/details/publication/pub.1021654293"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2021-11-01T18:08", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20211101/entities/gbq_results/article/article_405.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/s10947-006-0255-2"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10947-006-0255-2'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10947-006-0255-2'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10947-006-0255-2'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10947-006-0255-2'


 

This table displays all metadata directly associated to this object as RDF triples.

130 TRIPLES      21 PREDICATES      53 URIs      45 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s10947-006-0255-2 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author Nb57d068992504b7cb577f2b8a36d2937
4 schema:datePublished 2005-11
5 schema:datePublishedReg 2005-11-01
6 schema:description The crystal and molecular structure of N-(1-silatranylmethyl)benzimidazole was established by X-ray diffraction. The coordination polyhedron of the silicon atom in this molecule is a trigonal bipyramid. The bond lengths and angles of the N-(1-silatranylmethyl)benzimidazole (SMBI) molecule are compared with the corresponding values for other derivatives of this heterocycle. The silatranylmethyl group, having a high electron-donor inductive effect, does not increase the total aromaticity of the SMBI molecule.
7 schema:genre article
8 schema:inLanguage en
9 schema:isAccessibleForFree false
10 schema:isPartOf N97e9b0455be44712851622bef3596da6
11 Nebf7daeabd4d4bc69db40692c9ac2ab0
12 sg:journal.1135923
13 schema:keywords SMBI molecule
14 angle
15 aromaticity
16 atoms
17 bipyramid
18 bonds
19 coordination polyhedron
20 corresponding values
21 crystals
22 derivatives
23 diffraction
24 effect
25 electron-donor inductive effect
26 group
27 heterocycles
28 high electron-donor inductive effect
29 inductive effect
30 molecular structure
31 molecules
32 polyhedra
33 ray diffraction
34 silatranylmethyl group
35 silicon atoms
36 structure
37 total aromaticity
38 trigonal bipyramid
39 values
40 schema:name Crystal and molecular structure of N-(1-silatranylmethyl)benzimidazole
41 schema:pagination 1122-1125
42 schema:productId N31a7ddf743254b50a3d070f931df8912
43 Ne8dca3d65b5441f2af8e28a7453953e8
44 schema:sameAs https://app.dimensions.ai/details/publication/pub.1021654293
45 https://doi.org/10.1007/s10947-006-0255-2
46 schema:sdDatePublished 2021-11-01T18:08
47 schema:sdLicense https://scigraph.springernature.com/explorer/license/
48 schema:sdPublisher N2415f47e8b194e528e1794cff7f7c1f2
49 schema:url https://doi.org/10.1007/s10947-006-0255-2
50 sgo:license sg:explorer/license/
51 sgo:sdDataset articles
52 rdf:type schema:ScholarlyArticle
53 N0f9f564f9dc3475cb00ef7a509682738 rdf:first sg:person.016337253113.99
54 rdf:rest N8bb7ba35a51240a086601b7ae6378735
55 N144ceb292a1c48aaa249f121c464bb2e rdf:first sg:person.012621274514.60
56 rdf:rest rdf:nil
57 N15cd81c217694fb2bf9ff2a78dd49d28 rdf:first sg:person.010354623007.45
58 rdf:rest N0f9f564f9dc3475cb00ef7a509682738
59 N2415f47e8b194e528e1794cff7f7c1f2 schema:name Springer Nature - SN SciGraph project
60 rdf:type schema:Organization
61 N31a7ddf743254b50a3d070f931df8912 schema:name doi
62 schema:value 10.1007/s10947-006-0255-2
63 rdf:type schema:PropertyValue
64 N3895764c8f7447028b669caefc6caa0c rdf:first sg:person.016473435547.10
65 rdf:rest Naf5dc12f9a844d23a96b053b286d4dc2
66 N8bb7ba35a51240a086601b7ae6378735 rdf:first sg:person.016377745416.49
67 rdf:rest N3895764c8f7447028b669caefc6caa0c
68 N97e9b0455be44712851622bef3596da6 schema:volumeNumber 46
69 rdf:type schema:PublicationVolume
70 Naf5dc12f9a844d23a96b053b286d4dc2 rdf:first sg:person.010446355057.52
71 rdf:rest N144ceb292a1c48aaa249f121c464bb2e
72 Nb57d068992504b7cb577f2b8a36d2937 rdf:first sg:person.016410733065.70
73 rdf:rest N15cd81c217694fb2bf9ff2a78dd49d28
74 Ne8dca3d65b5441f2af8e28a7453953e8 schema:name dimensions_id
75 schema:value pub.1021654293
76 rdf:type schema:PropertyValue
77 Nebf7daeabd4d4bc69db40692c9ac2ab0 schema:issueNumber 6
78 rdf:type schema:PublicationIssue
79 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
80 schema:name Chemical Sciences
81 rdf:type schema:DefinedTerm
82 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
83 schema:name Physical Chemistry (incl. Structural)
84 rdf:type schema:DefinedTerm
85 sg:journal.1135923 schema:issn 0022-4766
86 2542-0976
87 schema:name Journal of Structural Chemistry
88 schema:publisher Springer Nature
89 rdf:type schema:Periodical
90 sg:person.010354623007.45 schema:affiliation grid-institutes:None
91 schema:familyName Zelbst
92 schema:givenName É. A.
93 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010354623007.45
94 rdf:type schema:Person
95 sg:person.010446355057.52 schema:affiliation grid-institutes:grid.4886.2
96 schema:familyName Trofimova
97 schema:givenName O. M.
98 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010446355057.52
99 rdf:type schema:Person
100 sg:person.012621274514.60 schema:affiliation grid-institutes:grid.4886.2
101 schema:familyName Chernov
102 schema:givenName N. F.
103 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012621274514.60
104 rdf:type schema:Person
105 sg:person.016337253113.99 schema:affiliation grid-institutes:None
106 schema:familyName Fundamensky
107 schema:givenName V. S.
108 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016337253113.99
109 rdf:type schema:Person
110 sg:person.016377745416.49 schema:affiliation grid-institutes:None
111 schema:familyName Katkevich
112 schema:givenName Yu. V.
113 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016377745416.49
114 rdf:type schema:Person
115 sg:person.016410733065.70 schema:affiliation grid-institutes:grid.4886.2
116 schema:familyName Voronkov
117 schema:givenName M. G.
118 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016410733065.70
119 rdf:type schema:Person
120 sg:person.016473435547.10 schema:affiliation grid-institutes:grid.4886.2
121 schema:familyName Bolgova
122 schema:givenName Yu. I.
123 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016473435547.10
124 rdf:type schema:Person
125 grid-institutes:None schema:alternateName Irkutsk State Pedagogical University, Russia
126 schema:name Irkutsk State Pedagogical University, Russia
127 rdf:type schema:Organization
128 grid-institutes:grid.4886.2 schema:alternateName A. E. Favorsky Irkutsk Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, Russia
129 schema:name A. E. Favorsky Irkutsk Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, Russia
130 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...