Synthesis and structure of (bis(3,5-dimethyl-1H-pyrazol-1-yl)methane)diiodocobalt(II) View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2005-11

AUTHORS

M. B. Bushuev, A. V. Virovets, E. V. Peresypkina, D. Yu. Naumov, A. S. Potapov, A. I. Khlebnikov, S. F. Vasilevsky, L. G. Lavrenova

ABSTRACT

A cobalt(II) iodide complex with bis(3,5-dimethyl-1H-pyrazol-1-yl)methane (L) CoLI2 has been synthesized, and its single crystals have been obtained. The complex compound was characterized by electron spectroscopy and X-ray diffraction analysis. The compound crystallizes in the monoclinic system (a = 8.4044(4) Å, b = 13.3120(5) Å, c = 14.5824(7) Å; β = 94.7290(10)°; V = 1625.92(13) Å3; Z = 4; ρcalc = 2.112 g/cm3; space group P21/m). The structure of the complex is molecular mononuclear. L is a cyclic bidentate ligand; the coordination polyhedron of cobalt is a CoN2I2 tetrahedron formed by the nitrogen atoms of the pyrazole fragments L and iodine atoms. The complex has π-π stacking interactions between the pyrazole rings of CoLI2 molecules, binding the molecules into infinite chains along the b axis. More... »

PAGES

1099-1103

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10947-006-0250-7

DOI

http://dx.doi.org/10.1007/s10947-006-0250-7

DIMENSIONS

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