Ontology type: schema:ScholarlyArticle
2005-01
AUTHORSD. G. Samsonenko, Yu. V. Mironov, O. A. Efremova, D. Yu. Naumov, O. A. Gerasko, V. P. Fedin, V. E. Fedorov, W. S. Sheldrick
ABSTRACTSupramolecular compounds [Mn(H2O)4(C36H36N24O12)]2[Re4Te4(CN)12]·12.5H2O (1), (H3O)2[{Mn(H2O)4 (C36H36N24O12)}{Mn(H2O)4} 2{Re4Te4(CN)12}2]·3.5H2O (2) and [{Mn(H2O)3Cl} 2(C36H36N24O12)]Cl2·6H2O (3) were obtained by crystallization at room temperature from water solutions containing macrocyclic cavitand cucurbituryl (C36H36N24O12), aqua complex of manganese(II) (1–3) and chalcocyanide cluster complex [Re4Te4(CN)12]4− (1, 2). From XRD analysis, the cucurbituryl molecule is bound with one (1, 2) or two atoms of manganese (3) through oxygen atoms of carbonyl groups. Compound 2 has a chain structure where cluster complexes of rhenium are linked through bridge manganese atoms into a polymeric ribbon. Compounds 1 and 3 have the island-like type of structure. More... »
PAGESs121-s129
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DOIhttp://dx.doi.org/10.1007/s10947-006-0162-6
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