X-ray photoelectron and voltammetry studies of the charged state of the metal atom in nickel(II) chelate complexes with ligands containing ... View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2005-05

AUTHORS

L. N. Mazalov, S. V. Trubina, I. M. Oglezneva, N. A. Kryuchkova, O. V. Tarasenko, V. L. Varand, T. E. Kokina, S. V. Larionov

ABSTRACT

X-ray photoelectron and voltammetry studies of the charged state of the metal atom in nickel(II) chelate complexes with ligands containing CS2− and PS2− groups and in heteroligand complexes on their basis were carried out. It is shown that the degree of formal oxidation of the nickel atom in the complexes corresponds to Ni(II). In the case of heteroligand complexes, addition of nitrogen heterocycles causes an increase in the electron density on the atoms of the coordination center. Theoretical data obtained in ab initio quantum chemical model calculations correlate with the experimental results. More... »

PAGES

542-545

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10947-006-0136-8

DOI

http://dx.doi.org/10.1007/s10947-006-0136-8

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1028222040


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0307", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Theoretical and Computational Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Nikolaev Institute of Inorganic Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.425759.8", 
          "name": [
            "A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Mazalov", 
        "givenName": "L. N.", 
        "id": "sg:person.011472411755.16", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011472411755.16"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Nikolaev Institute of Inorganic Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.425759.8", 
          "name": [
            "A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Trubina", 
        "givenName": "S. V.", 
        "id": "sg:person.014374177255.13", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014374177255.13"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Nikolaev Institute of Inorganic Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.425759.8", 
          "name": [
            "A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Oglezneva", 
        "givenName": "I. M.", 
        "id": "sg:person.012156420060.57", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012156420060.57"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Nikolaev Institute of Inorganic Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.425759.8", 
          "name": [
            "A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kryuchkova", 
        "givenName": "N. A.", 
        "id": "sg:person.013737450113.81", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013737450113.81"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Nikolaev Institute of Inorganic Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.425759.8", 
          "name": [
            "A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Tarasenko", 
        "givenName": "O. V.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Nikolaev Institute of Inorganic Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.425759.8", 
          "name": [
            "A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Varand", 
        "givenName": "V. L.", 
        "id": "sg:person.014552033255.10", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014552033255.10"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Nikolaev Institute of Inorganic Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.425759.8", 
          "name": [
            "A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kokina", 
        "givenName": "T. E.", 
        "id": "sg:person.015417414261.66", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015417414261.66"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Nikolaev Institute of Inorganic Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.425759.8", 
          "name": [
            "A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Larionov", 
        "givenName": "S. V.", 
        "id": "sg:person.0651161213.61", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0651161213.61"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1002/cvde.19960020302", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1014076895"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/cvde.19960020302", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1014076895"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0277-5387(99)00352-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1026972731"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0022-0248(80)90098-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1038683443"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0022-0248(80)90098-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1038683443"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2005-05", 
    "datePublishedReg": "2005-05-01", 
    "description": "X-ray photoelectron and voltammetry studies of the charged state of the metal atom in nickel(II) chelate complexes with ligands containing CS2\u2212 and PS2\u2212 groups and in heteroligand complexes on their basis were carried out. It is shown that the degree of formal oxidation of the nickel atom in the complexes corresponds to Ni(II). In the case of heteroligand complexes, addition of nitrogen heterocycles causes an increase in the electron density on the atoms of the coordination center. Theoretical data obtained in ab initio quantum chemical model calculations correlate with the experimental results.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s10947-006-0136-8", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1135923", 
        "issn": [
          "0022-4766", 
          "2542-0976"
        ], 
        "name": "Journal of Structural Chemistry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "3", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "46"
      }
    ], 
    "name": "X-ray photoelectron and voltammetry studies of the charged state of the metal atom in nickel(II) chelate complexes with ligands containing CS2\u2212 and PS2\u2212 groups and in their mixed-ligand complexes", 
    "pagination": "542-545", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "86715f8544ce691988dfe9ba10ad52de57b2acd4ed1add868c82e3c1b1836a1b"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s10947-006-0136-8"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1028222040"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s10947-006-0136-8", 
      "https://app.dimensions.ai/details/publication/pub.1028222040"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T01:07", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8697_00000513.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007%2Fs10947-006-0136-8"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10947-006-0136-8'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10947-006-0136-8'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10947-006-0136-8'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10947-006-0136-8'


 

This table displays all metadata directly associated to this object as RDF triples.

118 TRIPLES      21 PREDICATES      30 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s10947-006-0136-8 schema:about anzsrc-for:03
2 anzsrc-for:0307
3 schema:author N399889a896a14fe59094f7b36fb6c84a
4 schema:citation https://doi.org/10.1002/cvde.19960020302
5 https://doi.org/10.1016/0022-0248(80)90098-6
6 https://doi.org/10.1016/s0277-5387(99)00352-6
7 schema:datePublished 2005-05
8 schema:datePublishedReg 2005-05-01
9 schema:description X-ray photoelectron and voltammetry studies of the charged state of the metal atom in nickel(II) chelate complexes with ligands containing CS2− and PS2− groups and in heteroligand complexes on their basis were carried out. It is shown that the degree of formal oxidation of the nickel atom in the complexes corresponds to Ni(II). In the case of heteroligand complexes, addition of nitrogen heterocycles causes an increase in the electron density on the atoms of the coordination center. Theoretical data obtained in ab initio quantum chemical model calculations correlate with the experimental results.
10 schema:genre research_article
11 schema:inLanguage en
12 schema:isAccessibleForFree false
13 schema:isPartOf N3beeb840b2dd4025b53920048209583c
14 Nf9591b920bdb47e8bb181cff2b6a2ebe
15 sg:journal.1135923
16 schema:name X-ray photoelectron and voltammetry studies of the charged state of the metal atom in nickel(II) chelate complexes with ligands containing CS2− and PS2− groups and in their mixed-ligand complexes
17 schema:pagination 542-545
18 schema:productId Ncd3d4e60aec24909a585714ae8fa8180
19 Ne7daf6cd48bc4db8ae72747a57a340e8
20 Nf26a97c1458743a1a07912961d8dfcb7
21 schema:sameAs https://app.dimensions.ai/details/publication/pub.1028222040
22 https://doi.org/10.1007/s10947-006-0136-8
23 schema:sdDatePublished 2019-04-11T01:07
24 schema:sdLicense https://scigraph.springernature.com/explorer/license/
25 schema:sdPublisher N620ee4f5148b4805b3ecf42a2fec61ea
26 schema:url http://link.springer.com/10.1007%2Fs10947-006-0136-8
27 sgo:license sg:explorer/license/
28 sgo:sdDataset articles
29 rdf:type schema:ScholarlyArticle
30 N2efaaabc29fa418191675c46e7480c22 rdf:first sg:person.012156420060.57
31 rdf:rest N4e0007765bca41eeabe435d0e5ba4d23
32 N399889a896a14fe59094f7b36fb6c84a rdf:first sg:person.011472411755.16
33 rdf:rest N8327fad8f86b4ddaab743920b9b2db28
34 N3beeb840b2dd4025b53920048209583c schema:volumeNumber 46
35 rdf:type schema:PublicationVolume
36 N47f413c32b8b40f7be01c01c5ca31ffd rdf:first sg:person.014552033255.10
37 rdf:rest Nd592e45c852c44c18bbcc7a39c5fc0e0
38 N4e0007765bca41eeabe435d0e5ba4d23 rdf:first sg:person.013737450113.81
39 rdf:rest Nadc417520a5944b58bc03046019c18f0
40 N620ee4f5148b4805b3ecf42a2fec61ea schema:name Springer Nature - SN SciGraph project
41 rdf:type schema:Organization
42 N67fd70f25a1f4dd181e0092fae7cc023 schema:affiliation https://www.grid.ac/institutes/grid.425759.8
43 schema:familyName Tarasenko
44 schema:givenName O. V.
45 rdf:type schema:Person
46 N8327fad8f86b4ddaab743920b9b2db28 rdf:first sg:person.014374177255.13
47 rdf:rest N2efaaabc29fa418191675c46e7480c22
48 Nadc417520a5944b58bc03046019c18f0 rdf:first N67fd70f25a1f4dd181e0092fae7cc023
49 rdf:rest N47f413c32b8b40f7be01c01c5ca31ffd
50 Ncd3d4e60aec24909a585714ae8fa8180 schema:name readcube_id
51 schema:value 86715f8544ce691988dfe9ba10ad52de57b2acd4ed1add868c82e3c1b1836a1b
52 rdf:type schema:PropertyValue
53 Nd592e45c852c44c18bbcc7a39c5fc0e0 rdf:first sg:person.015417414261.66
54 rdf:rest Ned8b0a54e5184964a1e5a1f0183d3193
55 Ne7daf6cd48bc4db8ae72747a57a340e8 schema:name doi
56 schema:value 10.1007/s10947-006-0136-8
57 rdf:type schema:PropertyValue
58 Ned8b0a54e5184964a1e5a1f0183d3193 rdf:first sg:person.0651161213.61
59 rdf:rest rdf:nil
60 Nf26a97c1458743a1a07912961d8dfcb7 schema:name dimensions_id
61 schema:value pub.1028222040
62 rdf:type schema:PropertyValue
63 Nf9591b920bdb47e8bb181cff2b6a2ebe schema:issueNumber 3
64 rdf:type schema:PublicationIssue
65 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
66 schema:name Chemical Sciences
67 rdf:type schema:DefinedTerm
68 anzsrc-for:0307 schema:inDefinedTermSet anzsrc-for:
69 schema:name Theoretical and Computational Chemistry
70 rdf:type schema:DefinedTerm
71 sg:journal.1135923 schema:issn 0022-4766
72 2542-0976
73 schema:name Journal of Structural Chemistry
74 rdf:type schema:Periodical
75 sg:person.011472411755.16 schema:affiliation https://www.grid.ac/institutes/grid.425759.8
76 schema:familyName Mazalov
77 schema:givenName L. N.
78 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011472411755.16
79 rdf:type schema:Person
80 sg:person.012156420060.57 schema:affiliation https://www.grid.ac/institutes/grid.425759.8
81 schema:familyName Oglezneva
82 schema:givenName I. M.
83 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012156420060.57
84 rdf:type schema:Person
85 sg:person.013737450113.81 schema:affiliation https://www.grid.ac/institutes/grid.425759.8
86 schema:familyName Kryuchkova
87 schema:givenName N. A.
88 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013737450113.81
89 rdf:type schema:Person
90 sg:person.014374177255.13 schema:affiliation https://www.grid.ac/institutes/grid.425759.8
91 schema:familyName Trubina
92 schema:givenName S. V.
93 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014374177255.13
94 rdf:type schema:Person
95 sg:person.014552033255.10 schema:affiliation https://www.grid.ac/institutes/grid.425759.8
96 schema:familyName Varand
97 schema:givenName V. L.
98 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014552033255.10
99 rdf:type schema:Person
100 sg:person.015417414261.66 schema:affiliation https://www.grid.ac/institutes/grid.425759.8
101 schema:familyName Kokina
102 schema:givenName T. E.
103 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015417414261.66
104 rdf:type schema:Person
105 sg:person.0651161213.61 schema:affiliation https://www.grid.ac/institutes/grid.425759.8
106 schema:familyName Larionov
107 schema:givenName S. V.
108 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0651161213.61
109 rdf:type schema:Person
110 https://doi.org/10.1002/cvde.19960020302 schema:sameAs https://app.dimensions.ai/details/publication/pub.1014076895
111 rdf:type schema:CreativeWork
112 https://doi.org/10.1016/0022-0248(80)90098-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1038683443
113 rdf:type schema:CreativeWork
114 https://doi.org/10.1016/s0277-5387(99)00352-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1026972731
115 rdf:type schema:CreativeWork
116 https://www.grid.ac/institutes/grid.425759.8 schema:alternateName Nikolaev Institute of Inorganic Chemistry
117 schema:name A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk
118 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...