X-ray photoelectron and voltammetry studies of the charged state of the metal atom in nickel(II) chelate complexes with ligands containing ... View Full Text


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Article Info

DATE

2005-05

AUTHORS

L. N. Mazalov, S. V. Trubina, I. M. Oglezneva, N. A. Kryuchkova, O. V. Tarasenko, V. L. Varand, T. E. Kokina, S. V. Larionov

ABSTRACT

X-ray photoelectron and voltammetry studies of the charged state of the metal atom in nickel(II) chelate complexes with ligands containing CS2− and PS2− groups and in heteroligand complexes on their basis were carried out. It is shown that the degree of formal oxidation of the nickel atom in the complexes corresponds to Ni(II). In the case of heteroligand complexes, addition of nitrogen heterocycles causes an increase in the electron density on the atoms of the coordination center. Theoretical data obtained in ab initio quantum chemical model calculations correlate with the experimental results. More... »

PAGES

542-545

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10947-006-0136-8

DOI

http://dx.doi.org/10.1007/s10947-006-0136-8

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1028222040


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