Unusual lability of intramolecular coordination bond O→Si N-(trifluorosilylmethyl)succinimide View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2005-03

AUTHORS

T. N. Aksamentova, M. G. Voronkov, O. M. Trofimova, N. N. Chipanina, Yu. I. Bolgova, N. F. Chernov, É. A. Zel’bst, V. K. Turchaninov

ABSTRACT

According to IR spectroscopy data and ab initio quantum chemical computations, a novel representative of intracomplex organosilicon compounds — N-(trifluorosilylmethyl)succinimide (I) possesses an anomalously high sensitivity to medium effects. Coordination bond O→Si of the compound I is strong in the solid phase and polar medium, and weak in its isolated molecules. Geometric parameters calculated for the molecule I in polar medium correspond to X-ray diffraction data. More... »

PAGES

248-252

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10947-006-0038-9

DOI

http://dx.doi.org/10.1007/s10947-006-0038-9

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1025405292


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