X-ray study of volatile Ni(II), Cu(II), and Pd(II) complexes of β-ketoimine pivalyltrifluoroacetone View Full Text


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Article Info

DATE

2004-07

AUTHORS

I. A. Baidina, G. I. Zharkova, N. V. Pervukhina, S. A. Gromilov, I. K. Igumenov

ABSTRACT

Synthesis of volatile complexes based on β-ketoimine pivalyltrifluoroacetone, C(CH3)3C(NH)CH2COCF3, is described. The general formula of the complexes is M(L)2, where M = Cu, Ni, Pd. Complexes of this kind with Ni and Pd were obtained for the first time. The Cu and Pd complexes were found to be isostructural. A comprehensive crystal-chemical study showed that all structures are molecular and built of trans-complexes. The central atom has a square plane environment. The average M-O and M-N distances are nearly equal in all compounds: 1.84 Å, 1.92 Å, and 1.98 Å for Ni, Cu, and Pd complexes, respectively; the mean values of the O-M-N chelate angles are 93.4°, 91.9°, and 92.7°, respectively. More... »

PAGES

678-687

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10947-005-0044-3

DOI

http://dx.doi.org/10.1007/s10947-005-0044-3

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1013992492


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