Crystal and molecular structure of copper(II) trans-bis-(2-(methylimino)-4-pentanonate) View Full Text


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Article Info

DATE

2004-07

AUTHORS

I. A. Baidina, P. A. Stabnikov, A. D. Vasiliev, S. A. Gromilov, I. K. Igumenov

ABSTRACT

Synthesis and X-ray diffraction study of trans-bis-(2-(methylimino)-4-pentanonato)Cu(II), which is methyl-substituted ketoiminate, is reported. Crystal data for CuN2O2C12H20: a = 7.374(1) Å, b = 9.171(1) Å, c = 10.823(2) Å; α = 96.51(1)°, β = 106.12(1)°, γ = 96.81(1)°, space group P, Z = 2, dcalc = 1.38 g/cm3, dexp = 1.37 g/cm3, R = 0.037. The structure is molecular and consists of isolated trans-complexes. The coordination polyhedron of the copper atom is intermediate between the square and tetrahedron; the average distances are Cu-O 1.91 Å and Cu-N 1.95 Å, the O-Cu-O and N-Cu-N trans bond angles are 145.5° and 150.3°, respectively. The O-Cu-N chelate angle is 94.6°. The calculated energies of van der Waals intermolecular interactions are compared with the thermogravimetric characteristics of the complex with ketoiminate and copper(II) ethylenediamine-bis-acetylacetonate. More... »

PAGES

671-677

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10947-005-0043-4

DOI

http://dx.doi.org/10.1007/s10947-005-0043-4

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1010471288


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